USE OF AN IONIC LIQUID AND ALCOHOL BLEND TO MODIFY THE RHEOLOGY OF POLYETHOXYLATED ALCOHOL SULFATES
In one embodiment, a polyethoxylated alcohol sulfate composition is provided which includes a polyethoxylated alcohol sulfate, such as sodium laureth ether sulfate (SLES), water, an ionic liquid, and an alcohol. The ionic liquid and the alcohol form a synergistic blend, enabling a significant reduction of the viscosity of the polyethoxylated alcohol sulfate composition. Also provided is an embodiment of a method for modifying the rheology of polyethoxylated alcohol sulfate by use of an ionic liquid and alcohol blend. Finally provided is an embodiment of a detergent composition which is prepared by use of the polyethoxylated alcohol sulfate composition described herein, in addition to other commonly known ingredients.
1 . A polyethoxylated alcohol sulfate blend consisting essentially of:
a polyethoxylated alcohol sulfate having Formula (I):
R′—O—(C2H4O)n-SO3M′ (I)
wherein R′ is a C8-C20 alkyl group, n is from 1 to 20, and M′ is a salt-forming cation, preferably, R′ is C10-C18 alkyl, n is from 1 to 15, and M′ is sodium, potassium, ammonium, alkylammonium, or alkanolammonium, an alcohol,
an ionic liquid, and
water;
wherein the polyethoxylated alcohol sulfate is present in an amount ranging from about 20% to about 80% by weight of the blend.
2 . The polyethoxylated alcohol sulfate blend of claim 1 , wherein the polyethoxylated alcohol sulfate is sodium laureth ether sulfate (SLES).
3 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein the ionic liquid and the alcohol have a weight ratio ranging from about 1:5 to about 5:1.
4 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein a combined weight of the polyethoxylated alcohol sulfate and water and the weight of the ionic liquid have a ratio ranging from about 20:1 to about 1:1.
5 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein a combined weight of the polyethoxylated alcohol sulfate and water and the weight of the alcohol have a ratio ranging from about 15:1 to about 5:1.
6 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein a combined weight of the polyethoxylated alcohol sulfate and water and a combined weight of the alcohol and the ionic liquid have a ratio ranging from about 15:1 to about 1:1.
7 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein the alcohol is selected from a group consisting of ethanol, isopropyl, propanol, butanol, pentanol, hexanol, heptanal, and octanol, and a mixture thereof; and wherein the ionic liquid is selected from a group consisting of trioctyl methyl amine dioctyl sulfosuccinate, triisooctyl methyl amine C12-C13 methyl branched dodecyl sulfate, tetraoctyl amine dodecyl sulfate, N-dodecyl-N,N-dimethyl-N-hydroxyammonium dodecyleethoxysulfate, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, tris(2-hydroxyethyl) methyl-ammonium methylsulfate, and a mixture thereof.
8 . The polyethoxylated alcohol sulfate blend according to claim 7 , wherein the ionic liquid is tris(2-hydroxyethyl) methyl-ammonium methylsulfate; and wherein the alcohol is ethanol.
9 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein the polyethoxylated alcohol sulfate and water have a weight ratio of 7:3.
10 . The polyethoxylated alcohol sulfate blend according to claim 1 , wherein the blend does include any component other than polyethoxylated alcohol sulfate, water, the alcohol, and the ionic liquid.
11 . A detergent composition comprising:
(a) at least one nonionic surfactant in an amount of about 10% to about 30% by weight of the detergent composition;
(b) the polyethoxylated alcohol sulfate blend of claim 1 in an amount of about 8% to about 28% by weight of the detergent composition;
(c) a non-aqueous solvent system in an amount of about 8% to about 40 by weight of the detergent composition; and
(d) water in an amount of about 8% to about 20% by weight of the detergent composition.
12 . The detergent composition according to claim 11 , wherein the ionic liquid and the alcohol have a weight ratio ranging from about 1:5 to about 5:1.
13 . The detergent composition according to claim 11 ,
wherein the alcohol is selected from a group consisting of ethanol, isopropyl, propanol, butanol, pentanol, hexanol, heptanal, and octanol, and a mixture thereof, and
wherein the ionic liquid is selected from a group consisting of trioctyl methyl amine dioctyl sulfosuccinate, triisooctyl methyl amine C12-C13 methyl branched dodecyl sulfate, tetraoctyl amine dodecyl sulfate, N-dodecyl-N,N-dimethyl-N-hydroxyammonium dodecyleethoxysulfate, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, tris(2-hydroxyethyl) methyl-ammonium methylsulfate, and a mixture thereof.
14 . The detergent composition according to claim 11 , wherein the ionic liquid is tris(2-hydroxyethyl) methyl-ammonium methylsulfate; and
wherein the alcohol is ethanol.
15 . The detergent composition according to claim 11 , further comprising a polyol, an enzyme, a fatty acid, a fragrance composition, a color care agent, a polymer dispersant agent, an anti-disposition agent, a softening agent, or a combination thereof.
16 . The detergent composition according to claim 11 , wherein the detergent composition is enclosed in a pouch made of a water-soluble polymer film.
17 . A process for lowering viscosity of polyethoxylated alcohol sulfate comprising the steps of: blending a polyethoxylated alcohol sulfate with water, an alcohol, and an ionic liquid;
wherein the polyethoxylated alcohol sulfate composition is in an amount ranging from about 20% to about 80% by weight of the total of the polyethoxylated alcohol sulfate composition;
wherein the polyethoxylated alcohol sulfate blend consists essentially of the polyethoxylated alcohol sulfate, water, the alcohol, and the ionic liquid;
wherein the ionic liquid and the alcohol have a weight ratio ranging from about 1:5 to about 5:1;
wherein the alcohol is selected from a group consisting of ethanol, isopropyl, propanol, butanol, pentanol, hexanol, heptanol, and octanol, and a mixture thereof; and
wherein the ionic liquid is selected from a group consisting of trioctyl methyl amine dioctyl sulfosuccinate, triisooctyl methyl amine C12-C13 methyl branched dodecyl sulfate, tetraoctyl amine dodecyl sulfate, N-dodecyl-N,N-dimethyl-N-hydroxyammonium dodecyleethoxysulfate, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, N-(dodecylamindopropyl)-N, N-dimethyl-N-carboxymethylammonium, hydroxyethyl) methyl-ammonium methylsulfate, and a mixture thereof.
18 . The process according to claim 17 , wherein the polyethoxylated alcohol sulfate and water are blended with the alcohol first before blended with the ionic liquid.
19 . The process according to claim 17 , wherein the ionic liquid and the alcohol are blended first before further blended with the polyethoxylated alcohol sulfate and water.
20 . The process according to claim 17 , wherein the polyethoxylated alcohol sulfate is SLES.