IP Library Granted Patent US 11,667,818
Granted Patent B2
US 11,667,818 · App. 17/342,648 · Granted Jun 6, 2023

Ethylene-(meth)acrylic acid copolymer and water-dispersive composition including the same

Inventors: Doh Yeon Park (Daejeon, KR); Ju Eun Jung (Daejeon, KR); Soo Young Hwang (Daejeon, KR); Sang Ha Son (Daejeon, KR); Byoung Kyu Kwak (Daejeon, KR); Hai Jin Shin (Daejeon, KR)
Assignees: SK Innovation Co., Ltd.; SK Geo Centric Co., Ltd.
C09J123/0876C08F210/02C08F220/06C08F2500/33C08F2500/34C08F2800/20C08L33/02
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Quick Facts
Patent No.
US 11,667,818
App. No.
17/342,648
Granted
Jun 6, 2023
Kind
B2
Abstract

An ethylene-(meth)acrylic acid copolymer has a portion having a melting temperature of 94° C. or higher. A content of the portion having the melting temperature of 94° C. or higher measured by a Successive Self-nucleation and Annealing (SSA) analysis is 1.5% or less. A water-dispersive composition includes the ethylene (meth)acrylic acid copolymer, a neutralizing agent and an aqueous medium.

Claims (16)

1. An ethylene-(meth)acrylic acid copolymer, wherein a content of a portion having a melting temperature of 94° C. or higher measured by a Successive Self-nucleation and Annealing (SSA) analysis is 1.5% or less.

2. The ethylene-(meth)acrylic acid copolymer of claim 1 , wherein a melt flow index (MFI) measured at 190° C. and 2.16 kg is in a range from 200 g/10 min to 1,500 g/10 min.

3. The ethylene-(meth)acrylic acid copolymer of claim 1 , wherein a content of (meth)acrylic acid is in a range from 15 wt % to 30 wt %, and a content of ethylene is in a range from 70 wt % to 85 wt %.

4. The ethylene-(meth)acrylic acid copolymer of claim 1 , wherein a crystallization temperature measured by a differential scanning calorimetry (DSC) analysis is from 50° C. to 60° C.

5. The ethylene-(meth)acrylic acid copolymer of claim 1 , wherein a melting temperature measured by a differential scanning calorimetry (DSC) analysis is from 60° C. to 90° C.

6. A water-dispersive composition, comprising:

an ethylene-(meth)acrylic acid copolymer, wherein a content of a portion having a melting temperature of 94° C. or higher measured by a Successive Self-nucleation and Annealing (SSA) analysis is 1.5% or less;

a neutralizing agent; and

an aqueous dispersion medium.

7. The water-dispersive composition of claim 6 , wherein a solid content of the composition is in a range from 20% to 50%.

8. The water-dispersive composition of claim 6 , wherein a transmittance to a light having a wavelength of 600 nm is 50% or more.

9. The water-dispersive composition of claim 6 , wherein a viscosity of the composition at 25° C. is in a range from 100 cP to 10,000 cP.

10. The water-dispersive composition of claim 6 , wherein the ethylene-(meth)acrylic acid copolymer has a melt flow index (MFI) in a range from 200 g/10 min to 1,500 g/10 min measured at 190° C. and 2.16 kg.

11. The water-dispersive composition of claim 6 , wherein a degree of neutralization of acid groups included in the ethylene-(meth)acrylic acid copolymer is in a range from 25% to 50%.

12. The water-dispersive composition of claim 6 , wherein the neutralizing agent includes at least one selected from the group consisting of NH 4 OH, an organic amine, KOH, NaOH, CsOH or LiOH.

13. The water-dispersive composition of claim 6 , further comprising a polyolefin-based polymer.

Assignments (2)
CHANGE OF NAME Recorded Sep 2, 2022
From: SK GLOBAL CHEMICAL CO., LTD
To: SK GEO CENTRIC CO., LTD.
Reel/Frame 061371/0332 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 9, 2021
From: PARK, DOH YEON; JUNG, JU EUN; HWANG, SOO YOUNG; SON, SANG HA; KWAK, BYOUNG KYU; SHIN, HAI JIN
To: SK INNOVATION CO., LTD.; SK GLOBAL CHEMICAL CO., LTD.
Reel/Frame 056482/0107 →
Priority Claims (2)
KR 10-2020-0071714 · Jun 12, 2020 · national
KR 10-2020-0102269 · Aug 14, 2020 · national
Continuity (1)
Related Publication 20210388243A1 · Dec 16, 2021