Gas diffusion layer, membrane electrode assembly, fuel cell, and manufacturing method of gas diffusion layer
A gas diffusion layer includes: a conductive particle; and a fluororesin, and the fluororesin includes a first fiber having a first average fiber diameter and a second fiber having a second average fiber diameter different from the first average fiber diameter.
1. A gas diffusion layer, comprising:
a first fiber consisting of fluororesin having a first average fiber diameter;
a second fiber consisting of fluororesin having a second average fiber diameter different from the first average fiber diameter;
a conductive particle; and
a particulate fluororesin,
wherein the first average fiber diameter is 10 nm or more and 100 nm or less, and the second average fiber diameter is 0.5 μm or more and 50 μm or less.
2. The gas diffusion layer according to claim 1 , wherein a proportion of the second fiber consisting of fluororesin to an entirety of the first fiber consisting of fluororesin and the second fiber consisting of fluororesin is 10 mass % or more and 90 mass % or less.
3. The gas diffusion layer according to claim 1 , further comprising:
a conductive fiber.
4. The gas diffusion layer according to claim 1 , wherein an average particle diameter of the particulate fluororesin is 0.1 μm or more and 10 μm or less.
5. The gas diffusion layer according to claim 1 , wherein a proportion of the particulate fluororesin to an entirety of the first fiber consisting of fluororesin, the second fiber consisting of fluororesin, and the particulate fluororesin is 1 mass % or more and 50 mass % or less.
6. The gas diffusion layer according to claim 1 , wherein the gas diffusion layer has a porous structure including the conductive particle and the fluororesin.
7. The gas diffusion layer according to claim 1 , wherein a tensile fracture strength of the gas diffusion layer is 0.20 N/mm 2 or more.
8. The gas diffusion layer according to claim 1 , wherein the gas diffusion layer is a self-supporting film supported by the conductive particle and the fluororesin.
9. The gas diffusion layer according to claim 1 , wherein the fluororesin includes polytetrafluoroethylene (PTFE).
10. A membrane electrode assembly, comprising:
a gas diffusion layer, comprising
a first fiber consisting of fluororesin having a first average fiber diameter,
a second fiber consisting of fluororesin having a second average fiber diameter different from the first average fiber diameter, and
a conductive particle,
wherein the first average fiber diameter is 10 nm or more and 100 nm or less, and the second average fiber diameter is 0.5 μm or more and 50 μm or less;
a pair of electrodes; and
an electrolyte membrane.
11. A fuel cell, comprising:
a gas diffusion layer, comprising
a first fiber consisting of fluororesin having a first average fiber diameter,
a second fiber consisting of fluororesin having a second average fiber diameter different from the first average fiber diameter, and
a conductive particle,
wherein the first average fiber diameter is 10 nm or more and 100 nm or less, and the second average fiber diameter is 0.5 μm or more and 50 μm or less; and
a current collection plate.
12. A manufacturing method of a gas diffusion layer, the gas diffusion layer comprising:
a first fiber consisting of fluororesin having a first average fiber diameter;
a second fiber consisting of fluororesin having a second average fiber diameter different from the first average fiber diameter;
a conductive particle; and
a particulate fluororesin,
wherein the first average fiber diameter is 10 nm or more and 100 nm or less, and the second average fiber diameter is 0.5 μm or more and 50 μm or less,
the method comprising:
kneading the conductive particle, a first fluororesin having a first average particle diameter, and a second fluororesin having a second average particle diameter different from the first average particle diameter; and
rolling the kneaded material to fiberize the first fluororesin and the second fluororesin to form the first fiber and the second fiber, respectively.
13. The manufacturing method of a gas diffusion layer according to claim 12 , wherein the first average particle diameter is 0.1 μm or more and 0.5 μm or less, and
the second average particle diameter is 1 μm or more and 1000 μm or less.