Water soluble PAA-based polymer blends as binders for Si dominant anodes
Systems and methods utilizing water soluble (aqueous) PAA-based polymer binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a pyrolyzed water soluble PAA-based polymer blend, wherein the water soluble PAA-based polymer blend comprises PAA and one or more additional water-soluble polymer components. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
1. A battery electrode, the electrode comprising:
an electrode coating layer on a current collector, the electrode coating layer formed from silicon and a water soluble polyacrylic acid (PAA) based polymer blend, wherein said water soluble PAA-based polymer blend comprises PAA and one or more additional water-soluble polymer components; and wherein the wt % of the PAA is from about 10 wt % to about 15 wt %; and wherein said water soluble PAA-based polymer blend comprises a PAA reacted with a phenolic resin in a ratio of phenolic:PAA of about 1:1 to about 1:5.
2. The electrode according to claim 1 , wherein one or more of said one or more additional water-soluble polymer components comprises a polymer containing one or more functional groups selected from the group consisting of —OH, NH—, NH 2 , and —COOH.
3. The electrode according to claim 1 , wherein said water soluble PAA-based polymer blend is a tertiary system comprising PAA, phenolic resin and a third water-soluble polymer component.
4. The electrode according to claim 1 , wherein the electrode coating layer further comprises conductive additives.
5. The electrode according to claim 1 , wherein the current collector comprises one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer.
6. The electrode according to claim 1 , wherein the electrode coating layer comprises more than 70% silicon.
7. The electrode according to claim 1 , wherein the electrode is in electrical and physical contact with an electrolyte, the electrolyte comprising a liquid, solid, or gel.
8. The electrode according to claim 1 , wherein the battery electrode is in a lithium ion battery.
9. A method of forming an electrode, the method comprising:
creating an electrode coating layer from an electrode slurry comprising an aqueous solution of a water soluble PAA-based polymer blend and Si powder;
fabricating a battery electrode by coating the slurry on a current collector; and
pyrolyzing said electrode coating layer;
wherein said water soluble PAA-based polymer blend comprises PAA and one or more additional water-soluble polymer components; and
wherein the wt % of the PAA is from about 10 wt % to about 15 wt %; and wherein said water soluble PAA-based polymer blend comprises a PAA reacted with a phenolic resin in a ratio of phenolic:PAA of about 1:1 to about 1:5.
10. The method of claim 9 , wherein one or more of said one or more additional water-soluble polymer components comprises a polymer containing one or more functional groups selected from the group consisting of —OH, NH—, NH 2 , and —COOH.
11. The method of claim 9 , wherein said water soluble PAA-based polymer blend is a tertiary system comprising PAA, phenolic resin and a third water-soluble polymer component.
12. The method according to claim 9 , wherein the electrode coating layer further comprises conductive additives.
13. The method according to claim 9 , wherein the current collector comprises one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer.
14. The method according to claim 9 , wherein the electrode coating layer comprises more than 70% silicon.
15. The method according to claim 9 , wherein the electrode is in electrical and physical contact with an electrolyte, the electrolyte comprising a liquid, solid, or gel.
16. A battery, the battery comprising:
a cathode, a separator, an electrolyte, and an anode, the anode comprising an electrode coating layer on a current collector, the electrode coating layer formed from silicon and a pyrolyzed water soluble PAA-based polymer blend, wherein said water soluble PAA-based polymer blend comprises PAA and one or more one or more additional water-soluble polymer components; and wherein the wt % of the PAA is from about 10 wt % to about 15 wt %; and wherein said water soluble PAA-based polymer blend comprises a PAA reacted with a phenolic resin in a ratio of phenolic:PAA of about 1:1 to about 1:5.
17. The battery of claim 16 , wherein said water soluble PAA-based polymer blend is a tertiary system comprising PAA, phenolic resin and a third water-soluble polymer component.