Pigment mixture
The present invention relates to a pigment mixture based on spherical particles having a defined particle-size distribution, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, in cosmetic formulations, as tracer, as filler and for the preparation of pigment preparations and dry preparations.
1 . A pigment mixture consisting of components A and B:
component A consists of spherical base particles having a particle-size distribution D 90 of 0.5-15 μm and coating layers, wherein the coating layers consist of a TiO 2 layer, a SiO 2 layer, and optionally an outer protective layer, wherein said spherical base particles are completely covered on their surface firstly with the TiO 2 layer and subsequently with the SiO 2 layer,
and
component B consists of spherical base particles having a particle-size distribution D 90 of 0.5-15 μm and coating layers, wherein the coating layers consist of a TiO 2 layer, an iron oxide layer or with a layer of a mixture of TiO 2 and iron oxide, and optionally an outer protective layer, said spherical base particles are completely covered on their surface firstly with the TiO 2 layer and subsequently with the iron oxide layer or with the layer of the mixture of TiO 2 and iron oxide.
2 . The pigment mixture according to claim 1 , wherein the spherical base particles of component A and component B are magnesium silicate, aluminum silicate, alkali-metal aluminum silicates, alkaline-earth metal aluminum silicates, SiO 2 spheres, glass beads, hollow glass beads, nylon, aluminum oxide beads, polymeric beads comprising ethylene-acrylic acid copolymers, ethylene-methacrylate copolymers, HDI-trimethylol hexyl lactone copolymers, nylon, polyacrylates, polymethyl methacrylate copolymers, polyethylene, polymethylsilsesquioxanes or mixtures thereof.
3 . The pigment mixture according to claim 1 , wherein the spherical base particles of component A and/or the spherical base particles of component B are SiO 2 .
4 . The pigment mixture according to claim 1 , wherein the spherical base particles of component A and the spherical base particles of component B each consist of SiO 2 .
5 . The pigment mixture according to claim 1 , wherein, in component B, the iron oxide of the iron oxide layer or of the layer of the mixture of TiO 2 and iron oxide is Fe 2 O 3 .
6 . The pigment mixture according to claim 1 , wherein, in component A, the TiO 2 of the TiO 2 layer is TiO 2 in anatase modification.
7 . The pigment mixture according to claim 1 , wherein the TiO 2 layer of component A has a layer thickness of 10-500 nm.
8 . The pigment mixture according to claim 1 , wherein the SiO 2 layer of component A has a layer thickness of 10-500 nm.
9 . The pigment mixture according to claim 1 , wherein, in component B, the TiO 2 of the TiO 2 layer is TiO 2 in anatase modification.
10 . The pigment mixture according to claim 1 , wherein the TiO 2 layer of component B has a layer thickness of 50-400 nm.
11 . The pigment mixture according to claim 1 , wherein, in component B, the coating layers consist of the TiO 2 layer, the iron oxide layer, and optionally the outer protective layer, and the iron oxide layer of component B has a layer thickness of 5-300 nm.
12 . The pigment mixture according to claim 1 , wherein, in component B, the coating layers consist of the TiO 2 layer, the layer of the mixture of TiO 2 and iron oxide, and optionally the outer protective layer, and the layer of the mixture of TiO 2 and iron oxide of component B has a layer thickness of 55-700 nm.
13 . The pigment mixture according to claim 1 , wherein components A and B are mixed in a weight ratio of 99:1 to 90:10.
14 . The pigment mixture according to claim 1 , wherein component A and/or component B includes the outer protective layer for increasing light, temperature or weather stability compared to pigment without said layer.
15 . The pigment mixture according to claim 1 , wherein the spherical base particles of both component A and component B have a D 90 value of 4-15 μm.
16 . The pigment mixture according to claim 1 , wherein the spherical base particles of both component A and component B are having a D 90 value of 4-8 μm.
17 . In paints, coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, in cosmetic formulations, tracers, fillers or dry preparations comprising a pigment, the improvement wherein the pigment comprises a pigment of claim 1 .
18 . A formulation comprising the pigment mixture according to claim 1 , and at least one absorbent, astringent, antimicrobial substance, antioxidant, antiperspirant, antifoaming agent, antidandruff active compound, antistatic, binder, biological additive, bleach, chelating agent, deodorizer, emollient, emulsifier, emulsion stabilizers, dye, humectant, film former, filler, fragrance, flavor, insect repellent, preservative, anticorrosion agent, cosmetic oil, solvent, oxidant, vegetable constituent, buffer substance, reducing agent, surfactant, propellant gas, opacifier, UV filter, UV absorber, denaturing agent, viscosity regulator, perfume or vitamin.
19 . A process for the preparation of the pigment mixture according to claim 1 , comprising covering the spherical base particles of components A and B with the coating layers by wet-chemical coating or by a CVD or PVD process, and component A and component B are subsequently mixed with one another.
20 . The process according to claim 19 , further comprising, after mixing component A and component B with one another, subjecting the mixture to calcination at a temperature of between 250 and 1100° C.
21 . The process according to claim 19 , further comprising, after mixing component A and component B with one another, subjecting the mixture to calcination at a temperature of between 35° and 900° C.