Electrode for secondary battery
An electrode for a secondary battery includes a current collector, a first electrode mixture layer disposed on at least one surface of the current collector and including carboxymethyl cellulose and styrene butadiene rubber, and a second electrode mixture layer disposed on the first electrode mixture layer and including carboxymethyl cellulose. A weight average molecular weight of the carboxymethyl cellulose included in the first electrode mixture layer is less than a weight average molecular weight of the carboxymethyl cellulose included in the second electrode mixture layer. Adhesion between the electrode current collector and the active material and cohesion between the active materials may be improved, and the resistance within the electrode may be reduced, thereby significantly increasing the capacity and lifespan characteristics of a battery.
1. An electrode for a secondary battery comprising:
a current collector;
a first electrode mixture layer disposed on at least one surface of the current collector and including carboxymethyl cellulose and styrene butadiene rubber,
wherein the styrene butadiene rubber included in the first electrode mixture layer comprises 40 to 90 mol % of a butadiene monomer based on a total content of a monomer; and
a second electrode mixture layer disposed on the first electrode mixture layer and including carboxymethyl cellulose, wherein a weight average molecular weight of the carboxymethyl cellulose included in the first electrode mixture layer is less than a weight average molecular weight of the carboxymethyl cellulose included in the second electrode mixture layer,
wherein the second electrode mixture layer further comprises styrene butadiene rubber, a weight of the styrene butadiene rubber included in the second electrode mixture layer is equal to or less than a weight of styrene butadiene rubber included in the first electrode mixture layer, and the styrene butadiene rubber included in the second electrode mixture layer comprises 5 to 35 mol % of a butadiene monomer based on a total content of a monomer.
2. The electrode for a secondary battery of claim 1 , wherein the weight average molecular weight of the carboxymethyl cellulose included in the first electrode mixture layer is 40×10 4 to 300×10 4 .
3. The electrode for a secondary battery of claim 1 , wherein the weight average molecular weight of the carboxymethyl cellulose included in the second electrode mixture layer is 350×10 4 to 600×10 4 .
4. The electrode for a secondary battery of claim 1 , wherein the first electrode mixture layer comprises 0.6 to 2.0 weight % of carboxymethyl cellulose and 2.0 to 5.0 weight % of styrene butadiene rubber based on a total weight of the first electrode mixture layer.
5. The electrode for a secondary battery of claim 1 , wherein the second electrode mixture layer comprises 0.6 to 2.0 weight % of carboxymethyl cellulose and 2.0 weight % or less of styrene butadiene rubber based on a total weight of the second electrode mixture layer.
6. The electrode for a secondary battery of claim 1 , wherein a thickness of the first electrode mixture layer is 10 to 40 μm.
7. The electrode for a secondary battery of claim 1 , wherein a thickness of the second electrode mixture layer is 10 to 100 μm.
8. The electrode for a secondary battery of claim 1 , wherein the electrode is a negative electrode.
9. A secondary battery having the electrode according to claim 1 as a positive electrode or a negative electrode.
10. The secondary battery of claim 9 , wherein the electrode is a negative electrode.