IP Library Granted Patent US 11,898,058
Granted Patent B2
US 11,898,058 · App. 17/377,912 · Granted Feb 13, 2024

Fluorine compounds

Inventor: Reiner Friedrich (Seeheim-Jugenheim, DE)
Assignee: Merck Patent GmbH
C09D5/00C07C69/653C07C319/12C07C323/12C07F7/1804C09D4/00
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Quick Facts
Patent No.
US 11,898,058
App. No.
17/377,912
Granted
Feb 13, 2024
Kind
B2
Abstract

The present invention relates to novel compounds containing fluorinated end groups and to the use thereof in, for example, dirt-repellent coatings.

Claims (18)

1. A compound of formulae Ib, Id, Ie, Ig or Ih:

where

Rf=a perfluorinated alkyl group, optionally containing heteroatoms,

R 1 ═H or C 1 -C 4 -alkyl,

R″═C 1 -C 4 -alkyl, and R″″═H or an alkyl group.

2. The compound according to claim 1 , wherein Rf is selected from CF 3 —(CF 2 ) 0-3 —O—, CF 3 —(CF 2 ) 0-3 —O—, CF 3 —(CF 2 ) 0-3 —O—(CF 2 ) 1-3 —, CF 3 —(CF 2 ) 0-3 —O—(CF 2 ) 1-3 —O—, CF 3 —(CF 2 ) 0-3 —O—(CF 2 ) 1-3 —O—CF 2 —, CF 3 —(CF 2 ) 0-3 —O—(CF 2 —O—) 1-8 — and CF 3 —(CF 2 ) 0-3 —O—(CF 2 —O) 1-8 —CF 2 —.

3. The compound according to claim 1 , wherein R f is selected from CF 3 —(CF 2 ) 1-2 —, CF 3 —(CF 2 ) 1-2 —O—, CF 3 —O—(CF 2 ) 1-3 —, CF 3 —O—(CF 2 ) 1-2 —O—, CF 3 —(CF 2 ) 1-2 —O—CF 2 —, CF 3 —O—(CF 2 ) 1-2 —O—CF 2 —, CF 3 —O—(CF 2 —O—) 1-8 — and CF 3 —O—(CF 2 —O—) 1-8 —CF 2 —.

4. The compound according to claim 1 , wherein R″ is C 1 - or C 2 -alkyl.

5. The compound according to claim 1 , wherein the compound is of formula (Ib)

6. The compound according to claim 1 , wherein Rf is CF 3 —(CF 2 ) 1-2 —, CF 3 —(CF 2 ) 1-2 —O—, CF 3 —O—(CF 2 ) 1-3 — or CF 3 —O—(CF 2 ) 1-2 —O—.

7. The compound according to claim 1 , wherein the compound is of formula (Id)

8. The compound according to claim 1 , wherein the compound is of formula (Ie)

9. The compound according to claim 1 , wherein the compound is of formula (Ig)

10. The compound according to claim 1 , wherein the compound is of formula (Ih)

11. The compound according to claim 1 , wherein the compound is selected from the following compounds:

12. A method of providing a dirt-repellent surface to a substrate comprising applying to said substrate at least one compound according to claim 1 .

13. A composition comprising at least one compound according to claim 1 and a support which is suitable for the respective application and optionally further additives.

14. A coated article having a coating produced using at least one compound according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2025
From: MERCK PATENT GMBH
To: SUSONITY COMMERCIAL GMBH
Reel/Frame 072287/0400 →
Priority Claims (1)
EP 14004337 · Dec 19, 2014 · regional
Continuity (2)
Division 15536671
Related Publication 20210340383A1 · Nov 4, 2021