Biobased material for consumer goods packaging
A biodegradable polymeric composition for food contact applications is disclosed. This polymeric composition includes at least (1) from about 5 weight percent to about 95 weight percent poly(hydroxyalkanoates); (2) from about 5 weight percent to about 95 weight percent of at least one biodegradable polymer selected from the group consisting of poly(butylene succinate), poly(butylene succinate-co-adipate), poly(butylene adipate-co-terephthalate, poly(caprolactone), poly(lactic acid), cellulose esters (such as cellulose acetate) thermoplastic starch, and mixtures thereof; and (3) from about 0.1 weight percent to about 5 weight percent of a nucleating agent.
1. A biodegradable polymeric composition comprising: (1) from about 5 weight percent to about 95 weight percent poly(hydroxyalkanoates); (2) from about 5 weight percent to about 95 weight percent of at least one biodegradable polymer selected from the group consisting of poly(butylene succinate), poly(butylene succinate-co-adipate), poly(butylene adipate-co-terephthalate, poly(caprolactone), poly(lactic acid), cellulose esters, thermoplastic starch, and mixtures thereof; and (3) from about 0.1 weight percent to about 5 weight percent of a nucleating agent,
wherein the poly(hydroxyalkanoates) comprise a mixture of a first copolymer and a second copolymer,
wherein the first copolymer consists of from about 90 to about 99.9 mole percent monomer residues of 3-hydroxybutyrate and from about 0.1 to about 10 mole percent monomer residues of a second 3-hydroxyalkanoate having from 5 to 12 carbon atoms,
wherein the second copolymer consists of at least 70 mole percent monomer residues of 3-hydroxybutyrate and monomer residues of the second 3-hydroxyalkanoate having from 5 to 12 carbon atoms in an amount which is at least 6 mole percent less than the amount of the second 3-hydroxyalkanoate in the first polymer, and
wherein the poly(hydroxyalkanoates) and the at least one biodegradable polymer are transesterified with one another.
2. The polymeric composition of claim 1 , wherein the composition comprises from about 35 weight percent to about 90 weight percent poly(hydroxyalkanoates).
3. The polymeric composition of claim 1 , wherein the composition comprises from about 30 weight percent to about 90 weight percent poly(butylene succinate).
4. The polymeric composition of claim 1 , wherein the composition comprises from about 30 weight percent to about 90 weight percent poly(butylene succinate-co-adipate).
5. The polymeric composition of claim 1 , wherein the composition comprises from about 10 weight percent to about 70 weight percent poly(lactic acid).
6. The polymeric composition of claim 1 , wherein the composition comprises from about 30 weight percent to about 90 weight percent cellulose esters.
7. The polymeric composition of claim 1 , wherein the nucleating agent is selected from the group consisting of erythritols, pentaerythritol, dipentaerythritols, artificial sweeteners, stearates, polysaccharides, sorbitols, mannitols, inositols, polyester waxes, nanoclays, behenamide, erucamide, stearamide, oleamide, poly(hydroxybutyrate), thymine, cyanuric acid, cytosine, adenine, uracil, guanine, boron nitride and mixtures thereof.
8. The polymeric composition of claim 1 , wherein the composition further comprises up to about 15 weight percent of a plasticizer selected from the group consisting of sebacates, citrates, fatty esters of adipic, succinic, and glucaric acids, lactates, alkyl diesters, citrates, alkyl methyl esters, dibenzoates, propylene carbonate, caprolactone diols having a number average molecular weight from 200-10,000 g/mol, poly(ethylene glycols) having a number average molecular weight of 400-10,000 g/mol, esters of vegetable oils, long chain alkyl acids, adipates, glycerol, isosorbide derivatives or mixtures thereof, polymeric plasticizers, poly(hydroxyalkanoates) copolymers comprising at least 18 mole percent monomer residues of hydroxyalkanoates other than hydroxybutyrate, and mixtures thereof.
9. The polymeric composition of claim 8 , wherein the composition comprises from about 5 weight percent to about 15 weight percent of the plasticizer.
10. The polymeric composition of claim 1 , wherein the composition further comprises up to about 50 weight percent of a filler selected from the group consisting of calcium carbonate, talc, nano clays, nanocellulose, hemp fibers, kaolin, carbon black, wollastonite, glass fibers, carbon fibers, graphite fibers, mica, silica, dolomite, barium sulfate, magnetite, halloysite, zinc oxide, titanium dioxide, montmorillonite, feldspar, asbestos, boron, steel, carbon nanotubes, cellulose fibers, flax, cotton, starch, polysaccharides, aluminum hydroxide, magnesium hydroxide, modified starches, chitins and chitosans, alginates, gluten, zein, casein, collagen, gelatin, polysaccharides, guar gum, xanthan gum, succinoglycan, natural rubbers; rosinic acid, lignins, natural fibers, jute, kenaf, hemp, ground nut shells, wood flour, and mixtures thereof.
11. The polymeric composition of claim 10 , wherein the composition comprises from about 5 weight percent to about 40 weight percent of the filler.
12. The polymeric composition of claim 1 , wherein the composition further comprises up to about 20 weight percent of an impact modifier selected from the group consisting of acrylic-based resins and emulsions, isosorbide derivatives, natural rubbers, aliphatic polyesters, or mixtures thereof.
13. The polymeric composition of claim 12 , wherein the composition comprises from about 5 weight percent to about 15 weight percent of the impact modifier.
14. The polymeric composition of claim 1 , wherein the composition further comprises up to 50 weight percent of one or more additives selected from the group consisting of poly(vinyl alcohols), poly(vinyl acetate), poly(vinyl laurate), poly(ethylene vinyl acetate), poly(glycolic acid), furandicarboxylic acid-based polyesters, cellulose, nanocellulose, glucans, and mixtures thereof.
15. The polymeric composition of claim 1 , wherein the poly(hydroxyalkanoates) have a weight average molecular weight from about 50,000 Daltons to about 7.5 million Daltons.
16. The polymeric composition of claim 1 , wherein the poly(hydroxyalkanoates) and the at least one biodegradable polymer are reactively extruded with one another.
17. A product package for a consumer goods product, wherein the product package comprises at least one biodegradable package portion which comprises the polymeric composition of claim 1 .
18. The product package of claim 17 , wherein the at least biodegradable package portion is formed by a method selected from the group consisting of injection molding, compression molding, thermoforming, cast and blown film formation, extrusion coating, extrusion blow molding, injection stretch blow molding, and extrusion profiling.