IP Library Granted Patent US 11,618,846
Granted Patent B2
US 11,618,846 · App. 17/391,947 · Granted Apr 4, 2023

Polymer matrix particles for inhibiting scale formation in oil and gas wells

Inventors: Anthony D. Duong (Columbus, OH); Ramanathan S. Lalgudi (Columbus, OH); Phillip N. Denen (Columbus, OH)
Assignee: Battelle Memorial Institute
C09K8/528E21B37/06
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Quick Facts
Patent No.
US 11,618,846
App. No.
17/391,947
Granted
Apr 4, 2023
Kind
B2
Abstract

Polymer matrix particles useful for inhibiting scale formation in oil and gas wells are described. The insoluble, porous, crosslinked polymer matrix includes a polymer backbone and ionic functional groups covalently bonded to the backbone, the ionic functional groups being capable of selectively attracting and binding salt scale-forming ions when in contact with a liquid containing such ions.

Claims (11)

1. A coated substrate, consisting essentially of:

a coating disposed on an interior wellbore surface of a tubing, drill pipe, or casing of a wellbore; or on an interior wellbore surface of a collection of pipes and valves on top of a wellbore; wherein the coating comprises:

a continuous oil phase suitable for forming a coating on an interior surface of a well; and

polymer matrix particles dispersed in the continuous oil phase for inhibiting scale formation, each particle comprising a water-insoluble, porous, crosslinked polymer matrix, the polymer matrix comprising a polymer backbone and ionic functional groups covalently bonded to the backbone, the ionic functional groups comprising quaternary ammonium groups being capable of selectively attracting and binding salt scale-forming ions when in contact with a liquid containing such ions.

2. The coated substrate of claim 1 wherein the quaternary ammonium groups comprise tetrabutylammonium groups.

3. The coated substrate of claim 1 disposed in a brine comprising sodium chloride.

4. The coated substrate of claim 1 disposed in an oil or gas well.

5. The coating of claim 1 wherein the continuous phase comprises vegetable oil.

6. The coating of claim 1 wherein the coating is disposed in contact with the interior surface of a tubing, drillpipe, or casing of a wellbore; and further comprises a corrosion inhibitor.

7. The coating of claim 1 , wherein the polymer backbone of the polymer matrix is selected from the group consisting of polyacrylates, polyurethanes, polyesters and polystyrenes.

8. The coating of claim 1 , wherein the polymer matrix has a polyacrylate backbone.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2021
From: DUONG, ANTHONY D.; LALGUDI, RAMANATHAN S.; DENEN, PHILLIP N.
To: BATTELLE MEMORIAL INSTITUTE
Reel/Frame 057833/0704 →
Continuity (3)
Division 15686583 · Aug 25, 2017
Provisional Application 62381839 · Aug 31, 2016
Related Publication 20210363406A1 · Nov 25, 2021