IP Library Granted Patent US 11,667,657
Granted Patent B2
US 11,667,657 · App. 17/402,905 · Granted Jun 6, 2023

Diphosphites based on cis-butene-1,4-diol

Inventors: Robert Franke (Marl, DE); Detlef Selent (Rostock, DE); Armin Börner (Rostock, DE); Anna Chiara Sale (Recklinghausen, DE)
Assignee: EVONIK OPERATIONS GMBH
C07F9/65746B01J31/185B01J2531/004B01J2531/821B01J2531/822B01J2531/827B01J2531/845
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,667,657
App. No.
17/402,905
Granted
Jun 6, 2023
Kind
B2
Abstract

New diphosphites based on cis-butene-1,4-diol.

Claims (29)

1. A compound having structure (I) or (II):

where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are selected from: —H, —(C 1 -C 12 ) alkyl or —O—(C 1 -C 12 ) alkyl,

and the radicals R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are not all simultaneously — t Bu.

2. The compound according to claim 1 ,

where R 1 , R 4 , R 5 and R 8 are selected from: —H or —(C 1 -C 12 ) alkyl.

3. The compound according to claim 1 ,

where the radicals R 1 , R 4 , R 5 and R 8 are not all simultaneously — t Bu.

4. The compound according to claim 1 ,

where the radicals R 1 , R 4 , R 5 and R 8 are not — t Bu.

5. The compound according to claim 1 ,

where at least one of the radicals R 1 , R 4 , R 5 and R 8 is —H.

6. The compound according to claim 1 ,

where R 2 , R 3 , R 6 and R 7 are selected from: —H or —O—(C 1 -C 12 ) alkyl.

7. The compound according to claim 1 ,

where at least one of the radicals R 2 , R 3 , R 6 and R 7 is —H.

8. The compound according to claim 1 ,

where the compound has the structure (I).

9. The compound according to claim 1 ,

where the compound has the structure (I):

10. The compound according to claim 1 ,

where the compound has the structure (II).

11. The compound according to claim 1 ,

where the compound has the structure (2):

12. A ligand-metal complex comprising the compound according to claim 1 and a metal selected from: Rh. Ru, Co or Ir.

13. A process comprising the process steps of:

a) initially charging an olefin,

b) adding a compound according to claim 1 and a substance containing a metal selected from: Rh, Ru, Co or Ir,

c) feeding in H 2 and CO, and

d) heating the reaction mixture from steps a) to c), with conversion of the olefin to an aldehyde.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2024
From: EVONIK OPERATIONS GMBH
To: EVONIK OXENO GMBH & CO. KG
Reel/Frame 066242/0585 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2022
From: FRANKE, ROBERT; SELENT, DETLEF; BÖRNER, ARMIN; SALE, ANNA CHIARA
To: EVONIK OPERATIONS GMBH
Reel/Frame 061205/0095 →