Diphosphites based on cis-butene-1,4-diol
New diphosphites based on cis-butene-1,4-diol.
1. A compound having structure (I) or (II):
where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are selected from: —H, —(C 1 -C 12 ) alkyl or —O—(C 1 -C 12 ) alkyl,
and the radicals R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are not all simultaneously — t Bu.
2. The compound according to claim 1 ,
where R 1 , R 4 , R 5 and R 8 are selected from: —H or —(C 1 -C 12 ) alkyl.
3. The compound according to claim 1 ,
where the radicals R 1 , R 4 , R 5 and R 8 are not all simultaneously — t Bu.
4. The compound according to claim 1 ,
where the radicals R 1 , R 4 , R 5 and R 8 are not — t Bu.
5. The compound according to claim 1 ,
where at least one of the radicals R 1 , R 4 , R 5 and R 8 is —H.
6. The compound according to claim 1 ,
where R 2 , R 3 , R 6 and R 7 are selected from: —H or —O—(C 1 -C 12 ) alkyl.
7. The compound according to claim 1 ,
where at least one of the radicals R 2 , R 3 , R 6 and R 7 is —H.
8. The compound according to claim 1 ,
where the compound has the structure (I).
9. The compound according to claim 1 ,
where the compound has the structure (I):
10. The compound according to claim 1 ,
where the compound has the structure (II).
11. The compound according to claim 1 ,
where the compound has the structure (2):
12. A ligand-metal complex comprising the compound according to claim 1 and a metal selected from: Rh. Ru, Co or Ir.
13. A process comprising the process steps of:
a) initially charging an olefin,
b) adding a compound according to claim 1 and a substance containing a metal selected from: Rh, Ru, Co or Ir,
c) feeding in H 2 and CO, and
d) heating the reaction mixture from steps a) to c), with conversion of the olefin to an aldehyde.