Sealant material composition
Provided is a sealant material composition that can ensure good sealing properties while suppressing a flow of a sealant during travel and that can provide such performance in a well-balanced, compatible manner. As a sealant material composition constituting a sealant layer ( 10 ) disposed in an inner surface of a pneumatic tire, a sealant material composition in which a proportion (A) of toluene insoluble occupying the sealant material composition is from 30 mass % to 60 mass % is used, or a sealant material composition in which a ratio (d1/d2) of measured specific gravity (d1) of the sealant material composition measured by an underwater replacement method to calculated specific gravity (d2) of the sealant material composition calculated from specific gravity and a blended amount of each raw material in the sealant material composition is from 0.7 to 0.9 is used.
1. A pneumatic tire comprising a sealant material composition constituting a sealant layer disposed in an inner surface of the pneumatic tire, a proportion A of toluene insoluble occupying the sealant material composition represented by Formula (1) being from 30 mass % to 60 mass %:
A =( W 2/ W 1)×100 (1)
(where W2 is mass (unit: g) of toluene insoluble remaining after immersion of the sealant material composition in toluene for one week, and W1 is initial mass (unit: g) obtained before immersion of the sealant material composition in toluene),
the sealant layer includes one or more cavities formed therein,
wherein from 0.1 parts by mass to 40 parts by mass of a crosslinking agent is blended per 100 parts by mass of a rubber component;
wherein from 1 part by mass to 40 parts by mass of an organic peroxide and more than 0 parts by mass and less than 1 part by mass of a crosslinking aid are blended per 100 parts by mass of the rubber component;
wherein from 70 parts by mass to 400 parts by mass of a liquid polymer is blended per 100 parts by mass of the rubber component; and
wherein the liquid polymer is paraffin oil.
2. The pneumatic tire according to claim 1 , wherein the proportion A of the toluene insoluble occupying the sealant material composition is from 35 mass % to 50 mass %.
3. The pneumatic tire according to claim 1 , wherein assuming that specific gravity of the sealant material composition measured by an underwater replacement method is measured specific gravity d1, and specific gravity of the sealant material composition calculated from specific gravity and a blended amount of each raw material in the sealant material composition is calculated specific gravity d2, a ratio d1/d2 of the measured specific gravity d1 to the calculated specific gravity d2 is from 0.7 to 0.9.
4. The pneumatic tire according to claim 3 , wherein the calculated specific gravity d2 is 1.0 or less.
5. The pneumatic tire according to claim 1 , wherein the crosslinking agent comprises a sulfur component.
6. The pneumatic tire according to claim 1 , wherein the rubber component comprises butyl rubber, and a blended amount of the butyl rubber per 100 mass % of the rubber component is 10 mass % or more.
7. The pneumatic tire according to claim 6 , wherein the butyl rubber comprises chlorinated butyl rubber, and a blended amount of the chlorinated butyl rubber per 100 mass % of the rubber component is 5 mass % or more.
8. The pneumatic tire according to claim 1 , wherein molecular weight of the paraffin oil is 800 or more.