Method for manufacturing non-aqueous-electrolyte secondary cell, and voltage detection method
The purpose of the present invention is to shorten the manufacturing time in a method for manufacturing a non-aqueous-electrolyte secondary cell. In the method for manufacturing a non-aqueous-electrolyte secondary cell according to one embodiment of the present invention, during initial charging/discharging of a non-aqueous-electrolyte secondary cell comprising a negative electrode that includes a negative-electrode active material, a positive electrode that includes a Li—Ni composite oxide represented by the general formula Li a Ni x M (1-x) O 2 (where 0<a≤1.2, 0.6≤x<1, and M is at least one element selected from Co, Mn, and Al) as a positive-electrode active material, and a non-aqueous electrolyte, charging is performed so that the positive electrode potential based on lithium is 4.1-4.25 V in an open circuit state after charging.
1. A method for manufacturing a non-aqueous electrolyte secondary battery, the method comprising:
carrying out, in initial charging and discharging for the non-aqueous electrolyte secondary battery, charging so that a positive electrode potential in terms of a lithium reference in an open circuit state after charging becomes 4.1 to 4.25 V, the state of charge of the battery is between 75 and 95% and an amount of volume expansion of a positive electrode active material and a negative electrode active material is 100%;
the non-aqueous electrolyte secondary battery comprising:
a negative electrode including the negative electrode active material;
a positive electrode including, as the positive electrode active material, a Li—Ni-based composite oxide represented by a general formula Li a Ni x M (1-x) O 2 , wherein 0<a≤1.2, 0.6≤x<1, and M is at least one element selected from the group consisting of Co, Mn, and Al; and
a non-aqueous electrolyte.
2. The method for manufacturing a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the negative electrode active material includes graphite and a silicon compound, and
a content of the silicon compound is more than 0% by mass and 20% by mass or less based on a total mass of the negative electrode active material.
3. The method for manufacturing a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the Li—Ni-based composite oxide is represented by a general formula Li a Ni x Co y Al z O 2 , wherein 0<a≤1.2, 0.8≤x<1, 0<y<0.1, 0<z<0.1, and x+y+z=1.
4. A method for voltage inspection for a non-aqueous electrolyte secondary battery, the method comprising:
carrying out, in initial charging and discharging for the non-aqueous electrolyte secondary battery, charging so that a positive electrode potential in terms of a lithium reference in an open circuit state after charging becomes 4.1 to 4.25 V, the state of charge of the battery is between 75 and 95% and an amount of volume expansion of a positive electrode active material and a negative electrode active material is 100%; and
subsequently measuring a voltage of the non-aqueous electrolyte secondary battery;
the non-aqueous electrolyte secondary battery comprising:
a negative electrode including the negative electrode active material;
a positive electrode including, as the positive electrode active material, a Li—Ni-based composite oxide represented by a general formula Li a Ni x M (1-x) O 2 , wherein 0<a≤1.2, 0.6≤x<1, and M is at least one element selected from the group consisting of Co, Mn, and Al; and
a non-aqueous electrolyte.