Separating device for separating volatile compounds from a polymer reaction mixture
The current application is related to a process for separating volatile compounds from a reaction mixture comprising a polymer and said volatile compounds, comprising the steps of passing the reaction mixture through the inlet into the gravimetric vessel of the gravimetric separator of a separating device according to the present invention, withdrawing a first polymer-rich stream comprising mainly polymer through the first outlet of the gravimetric vessel, withdrawing a first polymer-lean stream comprising mainly volatile compounds through the second outlet of the gravimetric vessel, passing at least a part of the polymer-lean stream as a second polymer-lean stream through the first inlet into the flash vessel of the flash separator of the separating device according to the present invention, withdrawing a liquid stream through the first outlet of the flash vessel, and withdrawing a gaseous stream through the second outlet of the flash vessel.
1. A process for separating volatile compounds from a reaction mixture ( 9 ) comprising a polymer and said volatile compounds using a separating device comprising:
a gravimetric separator, having a gravimetric vessel ( 1 ), an inlet ( 2 ) for feeding the polymer reaction mixture ( 9 ), a first outlet ( 3 ) located in the lower part of the gravimetric vessel ( 1 ) for withdrawing a first polymer-rich stream ( 10 ), and a second outlet ( 4 ) located in the upper part of the gravimetric vessel ( 1 ) for withdrawing a first polymer-lean stream ( 11 ); and
a flash separator having a flash vessel ( 5 ), a first inlet ( 6 ) for feeding a second polymer-lean stream ( 12 ) split from the first polymer-lean stream ( 11 ), a first outlet ( 7 ) located at the lower part of the flash vessel ( 5 ) for withdrawing a liquid stream ( 14 ), and a second outlet ( 8 ) located at the upper part of the flash vessel ( 5 ) for withdrawing a gaseous stream ( 13 ), wherein the flash separator further comprises a second inlet ( 18 ) for feeding a second polymer-rich stream ( 19 ) from the first polymer rich stream ( 10 ), wherein the first outlet ( 3 ) of the gravimetric vessel ( 1 ) is fluidly connected to the second inlet ( 18 ) of the flash vessel ( 5 )
wherein the second outlet ( 4 ) of the separator vessel ( 1 ) is fluidly connected to the first inlet ( 6 ) of the flash vessel ( 5 );
the process comprising the steps of:
passing the reaction mixture ( 9 ) through the inlet ( 2 ) into the gravimetric vessel ( 1 ) of the gravimetric separator of the separating device,
withdrawing a first polymer-rich stream ( 10 ) comprising mainly polymer through the first outlet ( 3 ) of the gravimetric vessel ( 1 ),
passing at least a part of the first polymer-rich stream ( 10 ) as the second polymer-rich stream ( 19 ) through the second inlet ( 18 ) into the flash vessel ( 5 ),
withdrawing a first polymer-lean stream ( 11 ) comprising mainly volatile compounds through the second outlet ( 4 ) of the gravimetric vessel ( 1 ),
passing at least a part of the polymer-lean stream ( 11 ) as a second polymer-lean stream ( 12 ) through the first inlet ( 6 ) into the flash vessel ( 5 ) of the flash separator of the separating device,
withdrawing a liquid stream ( 14 ) through the first outlet ( 7 ) of the flash vessel ( 5 ), and
withdrawing a gaseous stream ( 13 ) through the second outlet ( 8 ) of the flash vessel ( 5 ).
2. The process according to claim 1 , wherein the second polymer-rich stream ( 19 ) is fed via the second inlet ( 18 ) between a liquid level ( 27 ) present in the flash vessel ( 5 ) and the first inlet ( 6 ) of the flash vessel ( 5 ), wherein the liquid level ( 27 ) is the boundary between a gaseous phase and a liquid phase present in the flash vessel ( 5 ).
3. The process according to claim 1 , wherein the third polymer-lean stream ( 16 ) and the gaseous stream ( 13 ) are combined to form a volatile compounds stream ( 17 ).
4. The process according to claim 2 , wherein the third polymer-rich stream ( 15 ) and the liquid stream ( 14 ) are combined to form the polymer stream ( 20 ).
5. The process according to claim 1 , wherein the second polymer-lean stream ( 12 ) is heated by a second heater ( 23 ) to the temperature as provided in the flash vessel ( 5 ).
6. The process according to claim 1 comprising the step of reducing the pressure of the second polymer-lean stream ( 12 ) before introduction into the flash separator.
7. The process according to claim 1 wherein the pressure within the flash separator is from 0 to 500 barg.
8. The process according to claim 1 wherein the temperature within the flash separator is from 100 to 400° C.
9. The process according to claim 1 wherein the pressure within the gravimetric separator is from 0 to 500 barg.
10. The process according to claim 1 wherein the temperature within the gravimetric separator is from 100 to 400° C.