Polyamide resin composition and method for producing same
The present invention provides a polyamide resin composition containing (A) a crystalline polyamide resin containing a polycapramide resin as a main component, (B) a semi-aromatic amorphous polyamide resin, and (C) an inorganic reinforcing material, wherein the polyamide resin composition contains, as the (C), (C-1) a glass fiber, (C-2) a wollastonite having a needle shape, and (C-3) an inorganic reinforcing material of a plate-like crystal; a mass ratio of the (B) to (A) satisfies 0.35≤(B)/(A)≤0.80; when a total content of the (A), (B), and (C) is 100 parts by mass, a content (parts) of each component satisfies 30≤(A)+(B)≤55; 10≤(B)≤23; 20≤(C-1)≤40; 8≤(C-2)≤25; 8≤(C-3)≤25; 45≤(C-1)+(C-2)+(C-3)≤70; and an amount of a carboxyl group in the polyamide resin composition is less than 120 meq/kg. The resin composition provides a molded article having excellent strength and rigidity, excellent surface appearance of the molded article, and further excellent weather resistance, even in continuous molding of the composition over a long period of time at a high cylinder temperature.
1. A polyamide resin composition containing (A) a crystalline polyamide resin containing a polycapramide resin as a main component, (B) a semi-aromatic amorphous polyamide resin, and (C) an inorganic reinforcing material, wherein
the polyamide resin composition contains, as the (C) inorganic reinforcing material, (C-1) a glass fiber, (C-2) a wollastonite having a needle shape, and (C-3) an inorganic reinforcing material of a plate-like crystal;
a mass ratio of the (B) to (A) satisfies 0.35≤(B)/(A)≤0.80;
when a total content of the (A), (B), and (C) is 100 parts by mass, a content of each component satisfies the following relationship,
30 parts by mass≤( A )+( B )≤55 parts by mass
10 parts by mass≤( B )≤23 parts by mass
20 parts by mass≤( C -1)≤40 parts by mass
8 parts by mass≤( C -2)≤25 parts by mass
8 parts by mass≤( C -3)≤25 parts by mass
45 parts by mass≤( C -1)+( C -2)+( C -3)≤70 parts by mass; and
an amount of a carboxyl group in the polyamide resin composition is less than 120 meq/kg.
2. The polyamide resin composition according to claim 1 , wherein a temperature-decreasing crystallization temperature of the polyamide resin composition as measured by differential scanning calorimetry (DSC) satisfies the following relationship:
180° C.≤( TC 2-1)≤185° C.
( TC 2-1)−( TC 2-2)≤5° C.
((TC2-1) represents a temperature-decreasing crystallization temperature of the polyamide resin composition at a retention time of 0 minute, and (TC2-2) represents a temperature-decreasing crystallization temperature of the polyamide resin composition which has been retained at 280° C. for 20 minutes).
3. The polyamide resin composition according to claim 1 , further containing (D) a master batch of carbon black and (E) a copper compound, wherein when a total content of the (A), (B), and (C) is 100 parts by mass, a content of the (D) is 1 to 5 parts by mass, and a content of the (E) is 0.001 to 0.1 part by mass.
4. A method for producing the polyamide resin composition according to claim 3 , the method including mixing, in advance, the (A) crystalline polyamide resin containing a polycapramide resin as a main component, the (B) semi-aromatic amorphous polyamide resin, the (D) master batch of carbon black, and a dispersion of the (E) copper compound, feeding the mixture to a hopper part of an extruder, and feeding the (C) inorganic reinforcing material by a side feeding method.