IP Library Granted Patent US 11,981,986
Granted Patent B2
US 11,981,986 · App. 17/421,933 · Granted May 14, 2024

7XXX-series aluminium alloy product

Inventors: Achim Bürger (Rheinland-Pfalz, DE); Sunil Khosla (Nottingham, GB); Christian Gerhard Krechel (Koblenz, DE); Sabine Maria Spangel (Rheinland-Pfalz, DE); Philippe Meyer (Koblenz, DE)
Assignee: NOVELIS KOBLENZ GMBH
C22F1/053C22C21/10
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Quick Facts
Patent No.
US 11,981,986
App. No.
17/421,933
Granted
May 14, 2024
Kind
B2
Abstract

The invention relates to a wrought 7xxx-series aluminium alloy product having a composition comprising, in wt. %, Zn 6.40 to 7.50, Mg 2.15 to 2.75, Cu 1.20 to 2.00, and wherein Cu+Mg<4.50, and wherein Mg<2.5+5/3(Cu−1.2), Fe up to 0.25, Si up to 0.25, and optionally one or more elements selected from the group consisting of: (Zr up to 0.3, Cr up to 0.3, Mn up to 0.45, Ti up to 0.25, Sc up to 0.5, Ag up to 0.5), the balance being aluminium and impurities, and having been aged to achieve a conventional tensile yield strength (in MPa) measured in the L-direction measured at quarter thickness of more than 485−0.12*(t−100) MPa (t being the thickness of the product in mm); a minimum life without failure due to stress corrosion cracking (SCC) measured in accordance with ASTM G47-98 of at least 30 days at a short transverse (ST) stress level of 170 MPa; and a minimum K max-dev value without crack deviation due to crack propagation testing in standard atmosphere at room temperature in accordance with ASTM E647-13e01 in L-S direction on CT samples of at least 40 MPa√m on average.

Claims (48)

1. A wrought 7xxx-series aluminium alloy product having a composition comprising, in wt. %,

Zn 6.50 to 7.20,

Mg 2.30 to 2.60,

Cu 1.30 to 1.80,

and wherein Cu+Mg<4.50, and wherein Mg<2.5+5/3(Cu−1.2),

Fe up to 0.25,

Si up to 0.25,

and optionally one or more elements selected from the group consisting of:

Zr up to 0.3,

Cr up to 0.3,

Mn up to 0.45,

Ti up to 0.25,

Sc up to 0.5,

Ag up to 0.5,

the balance being aluminium and impurities,

and wherein said product is aged to achieve:

a conventional tensile yield strength (in MPa) measured in the L-direction measured at quarter thickness of more than 485−0.12*(t−100) MPa (t being the thickness of the product in mm);

a minimum life without failure due to stress corrosion cracking (SCC) measured in accordance with ASTM G47-98 of at least 30 days at a short transverse (ST) stress level of 170 MPa; and

a minimum K max-dev value without crack deviation due to crack propagation testing in standard atmosphere at room temperature in accordance with ASTM E647-13e01 in L-S direction on CT samples of at least 40 MPa√m on average, testing in a load controlled fatigue test and crack deviation defined as a crack deviating more than 20° from the intended fracture plane.

2. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the Zn-content is at least 6.60%.

3. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the Zn-content is maximum 7.10%.

4. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein

Zn 6.75 to 7.10,

Mg 2.35 to 2.55,

Cu 1.35 to 1.75.

5. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein

Zn 6.75 to 7.10,

Mg 2.45 to 2.55,

Cu 1.35 to 1.75.

6. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a Zr-content in a range of 0.03% to 0.25%.

7. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a Cr-content in a range of 0.04% to 0.3%.

8. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a Cr-content of up to 0.05%.

9. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a Mn-content in a range of 0.05% to 0.4%.

10. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a Mn content of up to 0.05%.

11. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a sum of Mn+Cr up to 0.05%.

12. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product has a thickness of at least 12.7 mm.

13. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product is an aerospace product.

14. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product is in a T7 condition.

15. The wrought 7xxx-series aluminium alloy product according to claim 14 , wherein the product is in a T7 condition selected from the group consisting of T73, T74, T76, T77, and T79.

16. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the product has a thickness of at least 25.4 mm.

17. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product is in the form of a rolled, extruded or forged product.

18. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the product is in the form of a rolled product.

19. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein said product is aged to achieve one or more of:

a conventional tensile yield strength (in MPa) measured in the L-direction measured at quarter thickness of more than 500−0.12*(t−100) MPa (t being the thickness of the product in mm);

a minimum K max-dev value without crack deviation due to crack propagation testing in standard atmosphere at room temperature in accordance with ASTM E647-13e01 in L-S direction on CT samples of at least 50 MPa√m on average, testing in a load controlled fatigue test and crack deviation defined as a crack deviating more than 20° from the intended fracture plane;

a minimum life without failure due to stress corrosion cracking (SCC) measured in accordance with ASTM G47-98 of at least 30 days, at a short transverse (ST) stress level of 205 MPa.

20. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the wrought product is an aircraft structural part.

21. The wrought 7xxx-series aluminium alloy product according to claim 1 , wherein the wrought product is an aircraft structural part selected from the group of a wing spar, wing rib, wing skin, floor beam, and fuselage frame.

Assignments (6)
RELEASE OF SECURITY INTEREST AT REEL/FRAME 58711/0922 Recorded Mar 13, 2025
From: STANDARD CHARTERED BANK
To: NOVELIS INC.; NOVELIS KOBLENZ GMBH
Reel/Frame 070502/0231 →
SECURITY INTEREST Recorded Mar 11, 2025
From: NOVELIS DEUTSCHLAND GMBH; NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: CITIBANK, N.A.
Reel/Frame 070481/0417 →
CHANGE OF NAME Recorded Aug 10, 2022
From: ALERIS ROLLED PRODUCTS GERMANY GMBH
To: NOVELIS KOBLENZ GMBH
Reel/Frame 061419/0936 →
SECURITY INTEREST Recorded Jan 20, 2022
From: NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: STANDARD CHARTERED BANK
Reel/Frame 058711/0922 →
SECURITY INTEREST Recorded Jan 20, 2022
From: NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 058711/0952 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 9, 2021
From: BÜRGER, ACHIM; KHOSLA, SUNIL; KRECHEL, CHRISTIAN GERHARD; SPANGEL, SABINE MARIA; MEYER, PHILIPPE
To: ALERIS ROLLED PRODUCTS GERMANY GMBH
Reel/Frame 056806/0767 →