Spunbonded non-woven fabric, sanitary material, and method of manufacturing spunbonded non-woven fabric
A spunbonded non-woven fabric includes a fiber including a propylene homopolymer having a melting point of 140° C. or more, a polyethylene having a density of from 0.941 g/cm 3 to 0.970 g/cm 3 , and at least one polymer selected from the group consisting of a polymer represented in (I) and a polymer represented in (II). In the spunbonded non-woven fabric, the fiber includes a sea-island structure, and the percentage of an island phase having a diameter of from 0.12 μm to less than 0.63 μm with respect to an island phase in a cross section orthogonal to the axis direction of the fiber on a number basis is 30% or more. (I) represents a random copolymer of propylene and at least one selected from ethylene or an α-olefin having a carbon number of from 4 to 20. (II) represents a propylene homopolymer with a melting point of less than 120° C.
1. A spunbonded non-woven fabric, comprising a fiber comprising: a propylene homopolymer having a melting point of 140° C. or more; a polyethylene having a density of from 0.941 g/cm3 to 0.970 g/cm3; and at least one polymer selected from the group consisting of a polymer specified in the following (I) and a polymer specified in the following (II),
wherein the fiber comprises a sea-island structure, and a percentage of an island phase having a diameter of from 0.12 μm to less than 0.63 μm with respect to an entire island phase in a cross section orthogonal to an axis direction of the fiber on a number basis is 30% or more:
(I) a random copolymer of propylene and at least one selected from ethylene or an α-olefin having a carbon number of from 4 to 20, and
(II) a propylene homopolymer with a melting point of less than 120° C., satisfying the following (a) to (f):
(a) [mmmm]=from 20% by mol to 60% by mol,
(b) [rrrr]/(1−[mmmm])≤0.1,
(c) [rmrm]>2.5% by mol,
(d) [mm]×[rr]/[mr] 2 ≤2.0,
(e) weight-average molecular weight (Mw)=from 10,000 to 200,000, and
(f) molecular weight distribution (Mw/Mn)<4,
wherein, in (a) to (d), [mmmm] represents a meso-pentad fraction, [rrrr] represents a racemic pentad fraction, [rmrm] represents a racemic meso-racemic meso-pentad fraction, each of [mm], [rr], and [mr] represents a triad fraction, and Mn represents a number-average molecular weight.
2. The spunbonded non-woven fabric according to claim 1 , wherein a percentage of an island phase having a diameter of 0.63 μm or more on a number basis is 10% or less.
3. The spunbonded non-woven fabric according to claim 1 , wherein a percentage of an island phase having a diameter of less than 0.12 μm on a number basis is 70% or less.
4. The spunbonded non-woven fabric according to claim 1 , wherein a content of the polyethylene is from 1.0% by mass to 15.0% by mass with respect to a total amount of the fiber.
5. The spunbonded non-woven fabric according to claim 1 , wherein a content of at least one polymer selected from the group consisting of the polymer specified in (I) and the polymer specified in (II) is from 5.0% by mass to 30.0% by mass with respect to a total amount of the fiber.
6. The spunbonded non-woven fabric according to claim 1 , wherein a content of the propylene homopolymer having a melting point of 140° C. or more is from 55.0% by mass to 90.0% by mass with respect to a total amount of the fiber.
7. The spunbonded non-woven fabric according to claim 1 , wherein the fiber comprises a fatty acid amide having a carbon number of from 15 to 22, and a content of the fatty acid amide having a carbon number of from 15 to 22 is from 0.1% by mass to 5.0% by mass with respect to a total amount of the fiber.
8. The spunbonded non-woven fabric according to claim 1 , wherein the polymer specified in (I) is a random copolymer comprising at least a constitutional unit derived from propylene and a constitutional unit derived from ethylene.
9. A sanitary material, comprising the spunbonded non-woven fabric according to claim 1 .
10. A method of manufacturing a spunbonded non-woven fabric, the method comprising extruding a composition comprising: a propylene homopolymer having a melting point of 140° C. or more; a polyethylene having a density of from 0.941 g/cm 3 to 0.970 g/cm 3 ; and at least one polymer selected from a group consisting of a polymer specified in the following (I) and a polymer specified in the following (II) such that an amount of the composition extruded from an extruding machine A and an extruding machine B is 85:15 to 55:45 (extruding machine A: extruding machine B) on a mass basis:
(I) a random copolymer of propylene and at least one selected from ethylene or an α-olefin having a carbon number of from 4 to 20, and
(II) a propylene homopolymer with a melting point of less than 120° C., satisfying the following (a) to (f),
(a) [mmmm]=from 20% by mol to 60% by mol,
(b) [rrrr]/(1−[mmmm])≤0.1,
(c) [rmrm]>2.5% by mol,
(d) [mm]×[rr]/[mr] 2 ≤2.0,
(e) weight-average molecular weight (Mw)=from 10,000 to 200,000, and
(f) molecular weight distribution (Mw/Mn)<4,
wherein in (a) to (d), [mmmm] represents a meso-pentad fraction, [rrrr] represents a racemic pentad fraction, [rmrm] represents a racemic meso-racemic meso-pentad fraction, each of [mm], [rr], and [mr] represents a triad fraction, and Mn represents a number-average molecular weight.
11. The method of manufacturing a spunbonded non-woven fabric according to claim 10 , wherein a bore A of the extruding machine A is larger than a bore B of the extruding machine B.