ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
The present disclosure relates to an organic electroluminescent compound represented by formula 1 and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound of the present disclosure, it is possible to provide an organic electroluminescent device having long lifetime and/or high luminous efficiency properties.
1 . An organic electroluminescent compound represented by the following formula 1:
wherein
X represents O or S;
R 1 to R 4 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted silyl, or a substituted or unsubstituted amino; or may be linked to an adjacent substituent(s) to form a ring(s); and
at least one group of group R 5 and R 6 , group R 6 and R 7 , and group R 7 and R 8 are fused to the following formula 2 to form a ring(s):
wherein
R 5 to R 8 , which do not form a ring, each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted silyl, or a substituted or unsubstituted amino;
R 9 to R 12 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted silyl, or a substituted or unsubstituted amino, or *-L-ETU; with the proviso that at least one of R 9 to R 12 represents *-L-ETU;
L represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene; and
ETU represents a substituted or unsubstituted triazinyl, a substituted or unsubstituted quinazolinyl, a substituted or unsubstituted quinoxalinyl, a substituted or unsubstituted benzoquinoxalinyl, a substituted or unsubstituted dibenzoquinoxalinyl, a substituted or unsubstituted benzoquinazolinyl, a substituted or unsubstituted dibenzoquinazolinyl, a substituted or unsubstituted benzofuropyrazinyl, a substituted or unsubstituted benzothiopyrazinyl, a substituted or unsubstituted benzofuropyrimidinyl, or a substituted or unsubstituted benzothiopyrimidinyl.
2 . The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted alkyl, the substituted aryl(ene), the substituted heteroaryl(ene), the substituted silyl, the substituted amino, the substituted triazinyl, the substituted quinazolinyl, the substituted quinoxalinyl, the substituted benzoquinoxalinyl, the substituted dibenzoquinoxalinyl, the substituted benzoquinazolinyl, the substituted dibenzoquinazolinyl, the substituted benzofuropyrazinyl, the substituted benzothiopyrazinyl, the substituted benzofuropyrimidinyl and the substituted benzothiopyrimidinyl, each independently, are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl, a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s); a (C6-C30)aryl unsubstituted or substituted with a (3- to 30-membered)heteroaryl(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl;
a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C6-C30)arylamino unsubstituted or substituted with a (C1-C30)alkyl(s); a (C1-C30)alkyl(C6-C30)arylamino; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl, a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.
3 . The organic electroluminescent compound according to claim 1 , wherein the formula 1 is represented by any one of the following formulas 1-1 to 1-3:
wherein
R 5 to R 12 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted silyl, or a substituted or unsubstituted amino; and
R 1 to R 4 , L, ETU and X are as defined in claim 1 .
4 . The organic electroluminescent compound according to claim 1 , wherein ETU is represented by any one of the following:
wherein
R, each independently, represents hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted silyl, or a substituted or unsubstituted amino.
5 . The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is any one selected from the group consisting of the following compounds:
6 . An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
7 . An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
8 . The organic electroluminescent device according to claim 7 , wherein the organic electroluminescent compound is comprised in at least one of a light-emitting layer and an electron transport zone.