Method for grinding a hydraulic binder
Disclosed is a method for grinding a hydraulic binder, including: a) introducing:—a hydraulic binder, and—a composition B including at least one grinding aid B into the first chamber of a horizontal grinder including several chambers, including a first chamber and a last chamber, each chamber being separated from the adjacent chamber by a diaphragm, whereby a composition β including the hydraulic binder and composition B is obtained in the first chamber; and b) grinding composition β in the horizontal grinder, whereby composition β moves from the first chamber to the last chamber and a ground composition C is obtained at the outlet of the last chamber. At the grinding step, the method includes introducing into the last chamber a composition A including at least one grinding aid A including an aminoalcohol. Also disclosed is a corresponding grinding unit.
1. A method for grinding a hydraulic binder by providing a horizontal grinder, comprising:
a) introducing:
a hydraulic binder, and
a composition β comprising at least one grinding aid B′,
into a first chamber of the horizontal grinder comprising several chambers, including the first chamber and a last chamber, each chamber being separated from the adjacent chamber by a diaphragm,
whereby a composition β comprising the hydraulic binder and composition B is obtained in the first chamber,
b) grinding composition β in the horizontal grinder, whereby composition β moves from the first chamber to the last chamber and a ground composition C is obtained at an outlet of the last chamber,
wherein the grinding step comprises introducing into the last chamber a composition A comprising at least one grinding aid A′ comprising an aminoalcohol, composition A differing from composition β.
2. The method for grinding a hydraulic binder according to claim 1 , comprising after step b):
c) separating, by a separator, composition C ground into fines and separator rejects, where a mean size of the particles of the separator rejects is greater than that of the particles of the fines;
d) recovering the fines;
e) returning the separator rejects to the first chamber of the horizontal grinder.
3. The method for grinding a hydraulic binder according to claim 2 , wherein the horizontal grinder only has two chambers.
4. The method for grinding a hydraulic binder according to claim 1 , wherein the horizontal grinder only has two chambers.
5. The method for grinding a hydraulic binder according to claim 1 , wherein the hydraulic binder is cement.
6. The method for grinding a hydraulic binder according to claim 1 , wherein the grinding aid B′ comprises a polyol.
7. The method according to claim 6 , wherein the grinding aid B′ comprises a polyol selected from the group consisting of:
a diol,
a triol,
a tetraol,
and a mixture thereof.
8. The method according to claim 7 , wherein the diol is an alkylene glycol.
9. The method according to claim 8 , wherein the alkylene glycol has 1 to 20 carbon atoms.
10. The method according to claim 7 , wherein the grinding aid B′ comprises an alkylene glycol having 1 to 20 carbon atoms, or a mixture thereof.
11. The method according to claim 7 , wherein the polyol of grinding aid B′ is selected from among:
a diol selected from among 2-methyl-1,3-propanediol, monoethyleneglycol, diethyleneglycol, triethyleneglycol, tetraethyleneglycol, propylene glycol and a mixture thereof,
a triol, which is glycerol,
a tetraol, which is erythritol.
12. The method for grinding a hydraulic binder according to claim 1 , wherein grinding aid B′ comprises:
an aminoalcohol or one of the salts thereof, and
a carboxylic acid or salt thereof.
13. The method grinding a hydraulic binder according to claim 12 , wherein the aminoalcohol of the grinding aid B′ comprises:
from 2 to 8 carbon atoms, and/or
1, 2 or 3 alcohol functions.
14. The method for grinding a hydraulic binder according to claim 13 , wherein the aminoalcohol of the grinding aid B′ is N-methyldiethanolamine (MDEA), diisopropanolamine (DIPA), triisopropanolamine (TIPA), triethanolamine (TEA), ethanol-diisopropanolamine (EDIPA), diethanolisopropanolamine (DEIPA) or a mixture thereof.
15. The method for grinding a hydraulic binder according to claim 1 , wherein the aminoalcohol of grinding aid A′ comprises:
from 2 to 8 carbon atoms, and/or
1, 2 or 3 alcohol functions.
16. The method for grinding a hydraulic binder according to claim 1 , wherein composition A is injected into the last chamber;
either at the diaphragm separating the last chamber from the adjacent chamber,
or into the enclosure of the last chamber,
or at the outlet of the last chamber.
17. The method for grinding a hydraulic binder according to claim 1 , wherein the hydraulic binder is cement comprising mineral additions.
18. The method for grinding a hydraulic binder according to claim 1 , wherein grinding aid B′ comprises an aminoalcohol or one of the salts thereof.