Method of manufacturing a piezoelectric thin film
Disclosed is a method for manufacturing a piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film, comprising: forming a stress control layer comprised of a Group III nitride on a silicon substrate by chemical vapor deposition (CVD); and depositing a piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film on the stress control layer, the thin film being deposited by PVD at 0.3 Tm (Tm is melting temperature of a piezoelectric thin film material) or higher. Further, a method for manufacturing a device in conjunction with piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin films is provided.
1. A method for manufacturing a piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film, comprising:
forming a sacrificial layer on a sapphire substrate for film synthesis; and
growing a piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film on the sacrificial layer,
wherein the method further comprises forming a first semiconductor layer of Al y Ga 1-y N (0.5≤y≤1) before growing the piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film, and
wherein the sacrificial layer has an AI content of less than 50%, and an energy band gap of the sacrificial layer is smaller than that of the piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film.
2. The method of claim 1 , wherein the first semiconductor layer is formed at 1000° C. or higher, prior to forming the sacrificial layer.
3. The method of claim 1 , wherein the first semiconductor layer is formed by PVD under an oxygen atmosphere, after forming the sacrificial layer.
4. The method of claim 1 , further comprising: forming a second semiconductor layer between the sacrificial layer and the piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film, with the second semiconductor layer having an AI content greater than the sacrificial layer and less than the piezoelectric Al x Ga 1-x N (0.5≤x≤1) thin film.