IP Library Granted Patent US 11,753,338
Granted Patent B2
US 11,753,338 · App. 17/436,310 · Granted Sep 12, 2023

Methods and systems for controlling carbon burn out

Inventors: Rafic Y. Minkara (Kennesaw, GA); Joseph W. Cochran (Palm Harbor, FL)
Assignee: EM RESOURCES LLC
C04B18/08C04B20/04F23G5/08C04B2111/1093F23G2209/12F23G2209/30
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Quick Facts
Patent No.
US 11,753,338
App. No.
17/436,310
Granted
Sep 12, 2023
Kind
B2
Abstract

Systems and methods for beneficiating a recovered fly ash material and/or recovering fly ash from an impound site are described. The method may include thermally treating a first portion of a recovered fly ash material to form a thermally treated fly ash having a first temperature of at least 1000° F., and contacting the thermally treated fly ash with a second portion of the recovered fly ash material to cool the thermally treated fly ash to a second temperature of less than or equal to 500° F. and form a fly ash product. The fly ash product may have a carbon content less than 8% by weight, based on the total dry weight of the fly ash product.

Claims (31)

1. A method for beneficiating a recovered fly ash material, the method comprising:

thermally treating a first portion of the recovered fly ash material to form a thermally treated fly ash having a first temperature of at least 1000° F.; and

contacting the thermally treated fly ash with a second portion of the recovered fly ash material to cool the thermally treated fly ash to a second temperature of less than or equal to 500° F. and form a fly ash product;

wherein the fly ash product has a carbon content less than or equal to 8% by weight, based on the total dry weight of the fly ash product.

2. The method of claim 1 , wherein the contacting comprises mixing the thermally treated fly ash with the second portion of the recovered fly ash material in a ribbon mixer or rotating drum.

3. The method of claim 1 , wherein a temperature difference between the first portion of the recovered fly ash material and the second portion of the recovered fly ash material is at least 20° F.

4. The method of claim 1 , wherein the recovered fly ash material is obtained from an impound site, the method further comprising separating the recovered fly ash material into the first portion and the second portion, wherein the first portion comprises wet fly ash and the second portion comprises an aqueous solution.

5. The method of claim 4 , wherein the aqueous solution comprises at least one trace metal contaminant.

6. The method of claim 4 , wherein the first portion of the recovered fly ash material is thermally treated in a combustion chamber, and the method further comprises introducing at least a portion of the aqueous solution into the combustion chamber before, after, or during thermal treatment of the first portion of the recovered fly ash material.

7. The method of claim 6 , wherein the aqueous solution comprises a liquid portion that at least partially vaporizes in the combustion chamber, and a solid portion that is present in the fly ash product.

8. The method of claim 1 , wherein the carbon content of the thermally treated fly ash is less than or equal to 6% by weight, based on the total dry weight of the thermally treated fly ash.

9. The method of claim 1 , wherein the carbon content of the first portion of the recovered fly ash material is greater than or equal to 10% by weight, based on the total dry weight of the first portion of the recovered fly ash material.

10. A method for recovering fly ash from an impound site, the method comprising:

separating a recovered fly ash material obtained from the impound site into an aqueous component and a wet fly ash component;

thermally treating a first portion of the wet fly ash component in a carbon burn out system to form a thermally treated fly ash; and

controlling a temperature of the carbon burn out system with at least a portion of the aqueous component.

11. The method of claim 10 , further comprising mixing the thermally treated fly ash and a second portion of the wet fly ash component to form an ash product;

wherein the thermally treated fly ash has a lower carbon content than the recovered fly ash material, and the ash product has a carbon content less than or equal to 6% by weight, based on the total dry weight of the ash product.

12. The method of claim 11 , wherein the ash product exits from the carbon burnout system having a temperature at least 300° F. cooler than a temperature of the thermally treated fly ash.

13. The method of claim 11 , wherein mixing the thermally treated fly ash and the second portion of the wet fly ash component releases a gas, and the method further comprises passing the gas through a scrubber.

14. The method of claim 10 , wherein the first portion of the wet fly ash component is thermally treated in a combustion chamber of the carbon burn out system, and a temperature of the combustion chamber is maintained at 1200° F.±100° F.

15. The method of claim 10 , wherein controlling the temperature of the carbon burn out system includes introducing the aqueous component into the combustion chamber.

16. The method of claim 10 , wherein the recovered fly ash has a carbon content less than or equal to 8% by weight, based on the total dry weight of the recovered fly ash, the method further comprising mixing the wet fly ash component with an auxiliary fuel prior to thermally treating the first portion of the wet fly ash component.

17. A carbon burn out system for recovering fly ash, the carbon burn out system comprising:

a combustion chamber for thermally treating fly ash;

a mixing chamber in communication with, and downstream from, the combustion chamber; and

a source of recovered fly ash material for controlling a temperature of the carbon burn out system, at least a portion of the recovered fly ash material being in communication with (a) an inlet of the combustion chamber, and (b) an inlet of the mixing chamber.

18. The system of claim 17 , wherein the portion of the recovered fly ash material in communication with the combustion chamber and the mixing chamber comprises an aqueous solution.

19. The system of claim 17 , wherein the portion of the recovered fly ash material in communication with the combustion chamber and the mixing chamber comprises wet recovered fly ash having a carbon content of at least 8% by weight, relative to the total dry weight of the wet recovered fly ash.

20. The system of claim 17 , wherein one or both of the combustion chamber and the mixing chamber does not include a cooling jacket.

21. The system of claim 17 , further comprising a scrubber in communication with, and downstream from, the mixing chamber.

Assignments (9)
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 67963/0364 Recorded Sep 16, 2025
From: MIZUHO BANK, LTD., AS AGENT
To: EM RESOURCES LLC
Reel/Frame 072872/0638 →
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 70696/0397 Recorded Sep 15, 2025
From: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
To: EM RESOURCES LLC
Reel/Frame 072910/0155 →
SECURITY INTEREST Recorded Apr 1, 2025
From: EM RESOURCES LLC
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 070696/0397 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 066256/0596 Recorded Feb 12, 2025
From: UMB BANK, N.A.
To: EM RESOURCES LLC
Reel/Frame 070191/0456 →
PATENT SECURITY AGREEMENT Recorded Jun 28, 2024
From: EM RESOURCES LLC
To: MIZUHO BANK, LTD.
Reel/Frame 067963/0364 →
RELEASE OF SECURITY INTEREST Recorded Jun 20, 2024
From: MUFG BANK, LTD
To: EM RESOURCES LLC (FORMERLY KNOWN AS BORAL RESOURCES LLC)
Reel/Frame 067799/0395 →
SECURITY INTEREST Recorded Jan 26, 2024
From: EM RESOURCES LLC
To: MUFG BANK, LTD., AS AGENT
Reel/Frame 066256/0465 →
SECURITY INTEREST Recorded Jan 26, 2024
From: EM RESOURCES LLC
To: UMB BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066256/0596 →
CHANGE OF NAME Recorded Mar 23, 2022
From: BORAL RESOURCES LLC
To: EM RESOURCES LLC
Reel/Frame 059482/0239 →