Organic electroluminescent compound and organic electroluminescent device comprising the same
The present disclosure relates to an organic electroluminescent compound, and an organic electroluminescent device comprising the same. It is possible to provide an organic electroluminescent device which can be deposited at a low deposition temperature and/or in which clogging is reduced.
1. An organic electroluminescent compound represented by the following formula 1:
wherein
X 1 to X 12 each independently represent N or CR 1 ;
T 1 to T 4 each independently represent N or CR 2 ;
Y 1 to Y 3 each independently represent N or CR 3 , in which at least one of Y 1 to Y 3 is N;
L 1 represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene; and
Ar 1 , Ar 2 , and R 1 to R 3 each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino, a substituted or unsubstituted mono- or di-(C6-C30)arylamino, or a substituted or unsubstituted (C1-C30)alkyl(C6-C30)arylamino; or may be linked to an adjacent substituent to form a ring(s), where if a plurality of R 1 to R 3 is present, each of R 1 , each of R 2 , and each of R 3 may be the same or different.
2. The organic electroluminescent compound according to claim 1 , wherein substituents of the substituted (C1-C30)alkyl, the substituted (C6-C30)aryl(ene), the substituted (3- to 30-membered)heteroaryl(ene), the substituted (C3-C30)cycloalkyl, the substituted (C1-C30)alkoxy, the substituted tri(C1-C30)alkylsilyl, the substituted di(C1-C30)alkyl(C6-C30)arylsilyl, the substituted (C1-C30)alkyldi(C6-C30)arylsilyl, the substituted tri(C6-C30)arylsilyl, the substituted mono- or di-(C1-C30)alkylamino, the substituted mono- or di-(C6-C30)arylamino, and the substituted (C1-C30)alkyl(C6-C30)arylamino in L 1 , Ar 1 , Ar 2 , and R 1 to R 3 each independently are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a hydroxyl; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkoxy; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C3-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (5- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s); a (C6-C30)aryl unsubstituted or substituted with a (5- to 30-membered)heteroaryl(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; an amino; a mono- or di-(C1-C30)alkylamino; a mono- or di-(C6-C30)arylamino unsubstituted or substituted with a (C1-C30)alkyl(s); a (C1-C30)alkyl(C6-C30)arylamino; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl.
3. The organic electroluminescent compound according to claim 1 , wherein formula 1 is represented by the following formula 2 or formula 3:
wherein
a and b each independently represent an integer of 1 to 6, in which, if a and b are an integer of 2 or more, each of R 2 may be the same or different;
Y′ represents CR 4 R 5 , O, or S;
R 4 and R 5 each independently represent a substituted or unsubstituted (C1-C30)alkyl, or a substituted or unsubstituted (C6-C30)aryl; and
X 1 to X 12 , Y 1 to Y 3 , L 1 , Ar 1 , and Ar 2 are as defined in claim 1 .
4. The organic electroluminescent compound according to claim 1 , wherein
X 1 to X 12 each independently represent N or CR 1 ;
T 1 to T 4 each independently represent N or CR 2 ;
Y 1 to Y 3 each independently represent N or CR 3 , in which at least one of Y 1 to Y 3 is N;
L 1 represents a single bond, a substituted or unsubstituted (C6-C12)arylene, or a substituted or unsubstituted (5- to 15-membered)heteroarylene;
Ar 1 and Ar 2 each independently represent a substituted or unsubstituted (C6-C18)aryl, or a substituted or unsubstituted (5- to 15-membered)heteroaryl; and
R 1 to R 3 each independently represent hydrogen, a substituted or unsubstituted (C6-C12)aryl, or a substituted or unsubstituted (5- to 15-membered)heteroaryl; or may be linked to an adjacent substituent to form a ring(s).
5. The organic electroluminescent compound according to claim 1 , wherein
X 1 to X 12 each independently represent CR 1 ;
T 1 to T 4 each independently represent N or CR 2 ;
Y 1 to Y 3 each independently represent N or CR 3 , in which at least one of Y 1 to Y 3 is N;
L 1 represents a single bond, an unsubstituted (C6-C12)arylene, or an unsubstituted (5- to 15-membered)heteroarylene;
Ar 1 and Ar 2 each independently represent a (C6-C18)aryl unsubstituted or substituted with one or more deuterium, or an unsubstituted (5- to 15-membered)heteroaryl; and
R 1 to R 3 each independently represent hydrogen, an unsubstituted (C6-C12)aryl, or an unsubstituted (5- to 15-membered)heteroaryl; or may be linked to an adjacent substituent to form a ring(s).
6. The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the following:
7. An organic electroluminescent material comprising the organic electroluminescent compound according to claim 1 .
8. An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
9. An organic electroluminescent device according to claim 8 , wherein the organic electroluminescent compound is comprised in a light-emitting layer.