Thermal interface materials based on two-part polyurethanes
Disclosed herein are thermal interface materials based on two-part polyurethane resins comprising a polyurethane resin and a thermally conductive filler dispersed throughout the polyurethane resin, wherein the polyurethane resin is formed from two parts comprising: a first part comprising a triol, and a second part comprising an isocyanate-functionalized component, wherein at least one of the first part and the second part comprises a thermally conductive filler material.
1 . A composition comprising a polyurethane resin and a thermally conductive filler, wherein the polyurethane resin is formed from two parts comprising:
a first part comprising a triol and a first thermally conductive filler; and
a second part comprising an isocyanate-functionalized component and a second thermally conductive filler,
wherein:
the first thermally conductive filler is present in the first part in an amount of from 35 wt. % to 95 wt. %, based on the total weight of the first part,
the second thermally conductive filler is present in the second part in an amount of from 85 wt. % to 95 wt. %, based on the total weight of the second part,
the molar ratio of NCO groups to OH groups in the composition is less than 1.3, and
the first thermally conductive filler and the second thermally conductive filler are dispersed throughout the polyurethane resin.
2 . The composition of claim 1 , wherein the triol is selected from the group consisting of polypropylene glycol triol, poly(trimethylene) glycol triol, poly(tetramethylene ether) glycol triol, 2-methyl-1,3-propanediol adipate triol, and any combination thereof.
3 . The composition of claim 1 , wherein the triol has a number average molecular weight of from about 200 to about 5000 g/mol.
4 . The composition of claim 1 , wherein the first part further comprises a diol.
5 . The composition of claim 4 , wherein the diol has a number average molecular weight of from about 200 g/mol to about 5000 g/mol.
6 . The composition of claim 1 , wherein the triol is present in the first part in an amount of from about 29 wt. % to about 100 wt. %, based on the total weight of the first part.
7 . The composition of claim 1 , wherein the isocyanate-functionalized component is a difunctional aliphatic isocyanate component.
8 . The composition of claim 1 , wherein the isocyanate-functionalized component comprises a pendant group with a number average molecular weight greater than about 100 g/mol.
9 . The composition of claim 8 , wherein the pendant group is selected from the group consisting of a polyether, a linear or branched alkyl, an ester, a polyester, and any combination thereof.
10 . The composition of claim 1 , wherein each of the first part and the second part has a number average molecular weight of less than about 5000 g/mol.
11 . The composition of claim 1 , wherein the composition further comprises a catalyst selected from the group consisting of an amine catalyst, a metal catalyst based on Sn, Zn, Bi, Zr, V, Ti, or Zn, a Bi based complex, and any combination thereof.
12 . The composition of claim 1 , wherein the first part and/or the second part further comprises a component selected from the group consisting of an antioxidant blend, a pigment, a defoamer, a phase change material, a rheology modifier, a plasticizer, a moisture scavenger, and any combination thereof.
13 . The composition of claim 1 , wherein the second part further comprises a component selected from the group consisting of a moisture scavenger, wherein the moisture scavenger is selected from the group consisting of oxazolidine, p-toluenesulfonyl isocyanate, vinyl oxy silane, and any combination thereof.
14 . The composition of claim 1 , wherein the first thermally conductive filler and/or the second thermally conductive filler is selected from the group consisting of aluminum oxide, boron nitride, aluminum nitride, magnesium oxide, zinc oxide, and any combination thereof.
15 . The composition of claim 1 , wherein the first thermally conductive filler and the second thermally conductive filler are the same thermally conductive filler.
16 . A composition comprising a polyurethane resin and a thermally conductive filler, wherein the polyurethane resin is formed from two parts comprising:
a first part comprising a triol and a first thermally conductive filler; and
a second part comprising an isocyanate-functionalized component and a second thermally conductive filler,
wherein:
the first thermally conductive filler is present in the first part in an amount of from 85 wt. % to 95 wt. %, based on the total weight of the first part,
the second thermally conductive filler is present in the second part in an amount of from 85 wt. % to 95 wt. %, based on the total weight of the second part,
the molar ratio of NCO groups to OH groups in the composition is less than 1.3, and
the first thermally conductive filler and the second thermally conductive filler are dispersed throughout the polyurethane resin.
17 . A cured reaction product comprising the composition of claim 1 .
18 . The cured reaction product of claim 17 , wherein the cured reaction product has a Shore OO hardness of less than about 90, when measured according to ASTM D2240.
19 . A thermal interface material comprising the composition of claim 1 .
20 . An electronic device comprising a heat source, a heat sink, and the composition of claim 1 disposed between the heat source and the heat sink.
21 . The electronic device of claim 20 , wherein no air is disposed between the heat source and the heat sink.