IP Library Granted Patent US 12,622,439
Granted Patent B2
US 12,622,439 · App. 17/452,711 · Granted May 12, 2026

Edible cellulosic casings and compositions, and methods of formation

Inventors: Owen J. McGarel (Naperville, IL); Myron D. Nicholson (Lemont, IL); Chris L. Williams (Knoxville, TN)
Assignee: Viskase Companies, Inc.
A22C13/00A22C2013/0096
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Quick Facts
Patent No.
US 12,622,439
App. No.
17/452,711
Granted
May 12, 2026
Kind
B2
Abstract

Edible cellulosic casings comprise cellulose and at least one modifier comprising at least one polysaccharide. The at least one modifier is substantially evenly distributed with the cellulose throughout a casing material of the edible cellulosic casing. A composition useful for an edible cellulosic casing comprises regenerated cellulose and at least one non-cellulose hydrophilic polysaccharide dispersed in the regenerated cellulose. The regenerated cellulose composes at least 50 wt. % of the composition. A method for forming an edible cellulosic casing comprises forming a cellulose solution and forming a modifier solution comprising at least one polysaccharide dissolved therein. The modifier and cellulose solutions are mixed to form a mixture from which the edible cellulosic casing is made. Edible cellulosic casings, as disclosed, may be consumed along with an encased foodstuff or other material for ingestion.

Claims (35)

1 . An edible cellulosic casing, comprising:

cellulose; and

at least one modifier comprising at least one non-cellulose hydrophilic polysaccharide, the at least one modifier substantially evenly distributed with the cellulose throughout a casing material of the edible cellulosic casing,

the casing material having a heterogeneous material structure in which the cellulose and the at least one modifier comprising the at least one non-cellulose hydrophilic polysaccharide provide distinguishable phases from one another in the heterogeneous material structure,

wherein the edible cellulosic casing comprises, by dry weight thereof:

the cellulose in a range from about 55 wt. % to about 75 wt. % of the edible cellulosic casing;

the at least one non-cellulose hydrophilic polysaccharide, of the at least one modifier, in a range from about 10 wt. % to about 35 wt. % of the edible cellulosic casing;

at least one peptide, of the at least one modifier, in a range from about 10 wt. % to about 35 wt. % of the edible cellulosic casing; and

at least one filler material in a range from about 0 wt. % to about 15 wt. % of the edible cellulosic casing; and

wherein the edible cellulosic casing is free of aldehydes, methylols, epoxides, and enzymes.

2 . The edible cellulosic casing of claim 1 , wherein the cellulose comprises regenerated cellulose.

3 . The edible cellulosic casing of claim 1 , wherein the at least one polysaccharide is selected from the group consisting of starch, starch acetate, chitin, chitosan, pectin, carrageenan, konjac, xanthan gum, alginic acid, and alginate.

4 . The edible cellulosic casing of claim 1 , wherein the at least one non-cellulose hydrophilic polysaccharide comprises carrageenan.

5 . The edible cellulosic casing of claim 1 , wherein the casing is in a seamless tube form or in a flat film form.

6 . The edible cellulosic casing of claim 1 , further comprising at least one adhesion promoter on a food-contact surface of the edible cellulosic casing.

7 . The edible cellulosic casing of claim 6 , wherein the at least one adhesion promoter comprises at least one peptide.

8 . The edible cellulosic casing of claim 6 , wherein the at least one adhesion promoter comprises at least one of starch or dextrin.

9 . The edible cellulosic casing of claim 1 , wherein the edible cellulosic casing is free of animal-derived components.

10 . A method for forming the edible cellulosic casing of claim 1 , the method comprising:

forming a solution comprising the cellulose;

forming a modifier solution comprising, dissolved in the modifier solution, the at least one non-cellulose hydrophilic polysaccharide and the at least one peptide;

mixing the modifier solution into the solution comprising the cellulose to form a mixture; and

forming the casing material of claim 1 from the mixture.

11 . The method of claim 10 , wherein:

forming the solution comprising the cellulose comprises forming a viscose solution comprising the cellulose;

forming the casing material comprises:

exposing the mixture to at least one acid to form a casing composition comprising a regenerated cellulose derived from the cellulose of the viscose solution; and

the method further comprises:

extruding the casing composition to form a seamless tube casing comprising the casing material; and

shirring the seamless tube casing while applying at least one adhesion promoter on a food-contact surface of the seamless tube casing.

12 . The method of claim 10 , wherein:

forming the solution comprising the cellulose comprises dissolving natural cellulose in at least one of N-methyl-morpholine-N-oxide (NMMO), an ionic liquid (IL), or a deep eutectic solvent (DES); and

the method further comprises extruding the mixture to form an edible casing comprising the casing material, the cellulose of the casing material being derived from the natural cellulose.

13 . The edible cellulosic casing of claim 1 , wherein the at least one peptide in the range from about 10 wt. % to about 35 wt. % of the edible cellulosic casing comprises at least one oligopeptide in the range from about 10 wt. % to about 35 wt. % of the edible cellulosic casing.

14 . The edible cellulosic casing of claim 1 , wherein the heterogeneous material structure comprises cellulose-rich regions and modifier-rich regions that are microscopically distinguishable from one another.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 22, 2026
From: VISKASE COMPANIES, INC.
To: VISKASE COMPANIES, LLC
Reel/Frame 074437/0908 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 28, 2021
From: MCGAREL, OWEN J.; NICHOLSON, MYRON D.; WILLIAMS, CHRIS L.
To: VISKASE COMPANIES, INC.
Reel/Frame 057954/0365 →
Continuity (2)
Provisional Application 63108134 · Oct 30, 2020
Related Publication 20220132871A1 · May 5, 2022
References Cited (95)
US 2179181A · Charles et al. · 1939 [cited by applicant]
US 3427168A · Turbak et al. · 1969 [cited by applicant]
US 3447939A · Johnson · 1969 [cited by applicant]
US 3682661A · Turbak · 1972 [cited by applicant]
US 4145532A · Franks et al. · 1979 [cited by applicant]
US 4426228A · Brandner et al. · 1984 [cited by applicant]
US 4994285A · Hisano et al. · 1991 [cited by applicant]
US 5096754A · Hammer et al. · 1992 [cited by applicant]
US 5277857A · Nicholson et al. · 1994 [cited by applicant]
US 5451364A · Ducharme et al. · 1995 [cited by applicant]
US H1592H · Nicholson · 1996 [cited by applicant]
US 5597587A · Nicholson et al. · 1997 [cited by applicant]
US 5658524A · Portnoy et al. · 1997 [cited by applicant]
US 5702783A · Nicholson et al. · 1997 [cited by applicant]
US 5744251A · Ducharme et al. · 1998 [cited by applicant]
US 5811162A · Hammer et al. · 1998 [cited by applicant]
US 5820934A · Basfeld · 1998 [cited by applicant]
US 5942167A · Edmund · 1999 [cited by applicant]
US 5962053A · Frederick · 1999 [cited by applicant]
US 6033618A · Gord et al. · 2000 [cited by applicant]
US 6279737B1 · Long et al. · 2001 [cited by applicant]
US 6395356B1 · Wielockx et al. · 2002 [cited by applicant]
US 6547999B1 · Ducharme et al. · 2003 [cited by applicant]
US 6558719B1 · Blumenberg et al. · 2003 [cited by applicant]
US 6565796B1 · McGarel et al. · 2003 [cited by applicant]
US 6730340B1 · Macquarrie et al. · 2004 [cited by applicant]
US 7108907B1 · Yamane et al. · 2006 [cited by applicant]
US 7655165B2 · Weibel · 2010 [cited by applicant]
US 7854976B2 · Hammer et al. · 2010 [cited by applicant]
US 8728561B2 · MacQuarrie · 2014 [cited by applicant]
US 20040146668A1 · Gord et al. · 2004 [cited by applicant]
US 20040166209A1 · Gord et al. · 2004 [cited by applicant]
US 20050181020A1 · Reg · 2005 [cited by applicant]
US 20060004193A1 · Muller et al. · 2006 [cited by applicant]
US 20060153953A1 · Gord et al. · 2006 [cited by applicant]
US 20080233246A1 · Hammer et al. · 2008 [cited by applicant]
US 20090280221A1 · MacQuarrie · 2009 [cited by applicant]
US 20120321752A1 · Van De Nieuwelaar et al. · 2012 [cited by applicant]
US 20170042167A1 · MacQuarrie · 2017 [cited by applicant]
US 20170055558A1 · Ziemes et al. · 2017 [cited by applicant]
US 20190313655A1 · Nicholson et al. · 2019 [cited by applicant]
EP 2482668A1 · 2012 [cited by applicant]
WO 2004058862A1 · 2004 [cited by applicant]
WO 2011038479A1 · 2011 [cited by applicant]
European Communication pursuant to Article 94(3) EPC for European Application No. 21204611.4, dated Jul. 30, 2024, 4 pages. [cited by applicant]
Canadian Requisition by the Examiner for Canadian Application No. 3134985, dated Jan. 21, 2023, 5 pages. [cited by applicant]
Alanís-Lopez, et al., “Extrusion and Characterization of Thermoplastic Starch Sheets from “Macho” Banana”, Journal of Food Science, vol. 76, No. 6, (Apr. 2011), pp. E465-E471. [cited by applicant]
Ascona Foods Group “Products” retrieved from https://www.asconafoods.com/products, retrieved on (Sep. 29, 2020), 3 pages. [cited by applicant]
Belyamani et al., “Production and characterization of sodium caseinate edible films made by blown-film extrusion”, Journal of Food Engineering, vol. 121, (2014) Accepted Aug. 9, 2013, pp. 39-47. [cited by applicant]
Boyle et al., “Are All Meat Casings Edible?,” Department of Animal Sciences and Industry, Kansas State University, (Jan. 1995), 1 page. [cited by applicant]
Cha et al., “Evaluation of Processes to Enhance Grain and Meat Coproducts”, Journal of Food Process Engineering, vol. 23, Issue 5, (Jan. 30, 2007), pp. 353-371 (Abstract only). [cited by applicant]
Chunfang et al., “Effects of Extruding Technological Parameters on in Vitro Protein Digestibility of Flaxseed”, Transactions of the Chinese Society, (Accessed Oct. 25, 2021) 1 page. [cited by applicant]
Crowe et al., “Twin-Screw Extrusion Texturization of Extruded-Expelled Soybean Flour”, Jaocs, vol. 78, No. 8, (Jul. 2001), pp. 781-786. [cited by applicant]
Day et al., “Functionality of Protein-Fortified Extrudates”, Comprehensive Reviews in Food Science and Food Safety, vol. 12, (May 2013), pp. 546-564. [cited by applicant]
European Extended Search Report and Opinion for European Application No. 21204611.4, dated Mar. 24, 2022, 5 pages. [cited by applicant]
Glencross et al., “A comparison of the effect of diet extrusion or screw-press pelleting on the digestibility of grain protein products when fed to rainbow trout ( [cited by applicant]
Guha et al., “Twin-screw Extrusion of Rice Flour Without a Die: Effect of Barrel Temperature and Screw Speed on Extrusion and Extrudate Characteristics”, Journal of Food Engineering, vol. 32, (Apr. 1997), pp. 251-267. [cited by applicant]
Hermanutz et al., “Processing of Cellulose Using Ionic Liquids”, Macromol. Mater. Eng., vol. 304, (Feb. 2019), pp. 1800450, 1-8. [cited by applicant]
Hernandez-Izquierdo et al., “Thermal Transitions and Extrusion of Glycerol-Plasticized Whey Protein Mixtures”, Journal of Food Science, vol. 73, No. 4, (Feb. 2008), pp. E169-E175. [cited by applicant]
Hernandez-Izquierdo et al., “Thermal Transitions and Heat-Sealing of Glycerol-Plasticized Whey Protein Films”, Packaging Technology and Science, vol. 22, Issue 5, (Jan. 20, 2009), pp. 255-260. [cited by applicant]
Hernandez-Izquierdo, V.M., “Thermal Transitions, Extrusion, and Heat-sealing of Whey Protein Edible Films”, Dissertation preview, submitted in partial satisfaction of the requirements for the degree of Doctor of Philoso… [cited by applicant]
Ibanoglu et al., “In Vitro Protein Digestiblity and Content of Thiamin and Riboflavin in Extruded Tarhana, a Traditional Turkish Cereal Food”, Food Chemistry, vol. 58, Issue 1-2, (Jan.-Feb. 1997), pp. 141-144 (Abstract … [cited by applicant]
Indian Patent News, Innogel AG Receives Patent for Tough_Elastic Material Based on Starch, (May 25, 2011), available at https://www.proquest.com/docveiw/868381888/57597A1984F94130PQ/1, 2 pages. [cited by applicant]
JetNet , “Nutrafilm carrageenan film for Meat and Poultry Packaging”, (Sep. 29, 2020), (available at https://www.jetnetcorp.com/nutrafilm.html, 1 page. [cited by applicant]
Jing et al., “Effects of twin-screw extrusion on soluble dietary fibre and physicochemical properties of soybean residue”, Food Chemistry, vol. 138, (2013) Accepted Dec. 2, 2012, pp. 884-889. [cited by applicant]
Kong et al., “Development, Characterization and Stability Study of Value-Aded Extruded Salmon Snacks”, Electronic Theses and Dissertations, (Date of Award -Dec. 2008), 2 pages. [cited by applicant]
Krishna et al., “Development of fish gelatin edible films using extrusion and compression molding”, Journal of Food Engineering, vol. 108, (2012), pp. 337-344. [cited by applicant]
Li et al., “Evaluation of the prebiotic GroBiotic (Registered)—A and brewers yeast as dietary supplements for sub-adult hybrid striped bass (Morone chrysops*M. saxatilis) challenged in situ with [cited by applicant]
Li et al., “Extrusion processing and characterization of edible starch films with different amylose contents”, Journal of Food Engineering, vol. 106, (Apr. 2011), pp. 95-101. [cited by applicant]
Liang et al., “Extrusion Cooking of Rapeseed Meal for Feeding Value Improvement”, Applied Engineering in Agriculture, vol. 18, No. 3, (2002), pp. 325-330. [cited by applicant]
Liu et al., “A Preliminary Study on Antimicrobial Edible Films from Pectin and Other Food Hydrocolloids by Extrusion Method”, Journal of Natural Fibers, vol. 5, No. 4, (Nov. 2008), pp. 366-382. [cited by applicant]
Luo et al., “Effect of Extrusion Cooking on in Vitro Digestibility of low Value Aquatic Protein”, 2011 International Conference on Remote Sensing, Environment and Transportation Engineering, (2011), 2 pages. [cited by applicant]
Mohd et al., “Dissolution of Cellulose in Ionic Liquid: A Review”, AIP Conference Proceedings, 1809, (Published online Feb. 24, 2017), 020035-1-020035-13. [cited by applicant]
Murphy et al., “Chemical composition and physical properties of extruded snacks containing crab-processing by-product”, Journal of the Science of Food and Agriculture, vol. 83, (May 2003), pp. 1163-1167. [cited by applicant]
Nicholson et al., “Fllexibie nonwoven composites for food packaging”, Reprinted from Toppi Journal, vol. 74, No. 5, May 1991, pp. 227-231. [cited by applicant]
Norajit et al., “Preparation and Properties of Antibacterial Alginate Films Incorporating Extruded White Ginseng Extract”, Journal of Food Processing and Preservation, vol. 35, Issue 4, (Dec. 9, 2010), pp. 387-393. [cited by applicant]
Pastor-Cavada et al., “Effects of the addition of wild legumes ( [cited by applicant]
Reiser et al., “VEMAG cc215 Alginate Sausage Line”, Accessed May 22, 2018, (available at http://www.reiser.com/sausage-alginate-cc215.php, 1 page. [cited by applicant]
Santillán-Moreno et al., “Physicochemical Characterization of Extruded Blends of Corn Starch-Whey Protein Concentrate-Agave tequilana Fiber”, Food Bioprocess Technol., vol. 4, (2011) Accepted Jun. 9, 2009, pp. 797-808. [cited by applicant]
Shrestha et al., “Enzyme resistance and structural organization in extruded high amylose maize starch”, Carbohydrate Polymers, vol. 80, (2010) Accepted Dec. 3, 2009, pp. 699-710. [cited by applicant]
Simelane et al., “Mechanical Properties of Whey Protein Isolate Based Edible Films as Affected by Meat Processing Conditions and Optimization of These Properties”, Department of Food Science and Human Nutrition, 2003, 2… [cited by applicant]
Singla, “Effect of Processing on Pinhão Seeds and Extrudability of Pinhão Flour,” Thesis, Graduate School-New Brunswick, Rutgers, (Jan. 2011), available at https://rucore.libraries.rutgers.edu/rutgers-lib/31172/PDF/1/ (… [cited by applicant]
Sothornvit et al., “Tensile properties of compression-molded whey protein sheets: Determination of molding condition and glycerol-content effects and comparison with solution-cast films”, Journal of Food Engineering, vo… [cited by applicant]
Stojceska et al., “Cauliflower by-products as a new source of dietary fibre, antioxidants and proteins in cereal based ready-to-eat expanded snacks”, Journal of Food Engineering, vol. 87, (Jan. 2008), pp. 554-563. [cited by applicant]
Su et al., “Extrusion Processing of Starch Film”, International Journal of Food Engineering, vol. 5, Issue 1, (Mar. 2009), 15 pages. [cited by applicant]
Ture et al., “Antimicrobial compression-moulded wheat gluten films containing potassium sorbate”, Food Research International, vol. 45, (2012) Accepted Oct. 11, 2011, pp. 109-115. [cited by applicant]
Vodovotz et al., “Quantification and Characterization of Volatiles Evolved during Extrusion of Rice and Soy Flours”, Biotechnol. Prog., vol. 16, (Feb. 2000) pp. 299-301. [cited by applicant]
Waramboi et al., “Influence of extrusion on expansion, functional and digestibility properties of whole sweetpotato flour”, LWT—Food Science and Technology, vol. 59, (Jun. 2014), pp. 1136-1145. [cited by applicant]
Willberg-Keyrilainen et al., “Production of cellulose carbamate using urea-based deep eutectic solvents”, Cellulose, (Aug. 2017), 11 pages. [cited by applicant]
Wirjosentono et al., “Oil Palm Fruit Bunch Filled Polypropylene Composites”, International Journal of Polymeric Materials, vol. 53, No. 4, (Apr. 2004), pp. 295-306. [cited by applicant]
Yagci et al., “Effect of Incorporation of Various Food By-products on Some Nutritional Properties of Rice-based Extruded Foods”, Food Science and Technology International OnlineFirst, (Dec. 2009), pp. 0001-0011. [cited by applicant]
Yong et al., “Weighing up whey fortification of foods: Implications for kinetics of starch digestion and estimated glycemic index of model high-protein-low-carbohydrate food systems”, Carbohydrate Polymers, vol. 84, (20… [cited by applicant]
Zhang et al., “Alkali combined extrusion pretreatment of corn stover to enhance enzyme saccharification”, Industrial Crops and Products, vol. 37, (2012) Accepted Dec. 4, 2011, pp. 352-357. [cited by applicant]
European Communication pursuant to Rule 114(2) EPC for European Application No. 21204611.4, dated Oct. 20, 2023, 63 pages. [cited by applicant]
European Communication pursuant to Rule 114(2) EPC for European Application No. 21204611.4, dated Feb. 27, 2025, 9 pages. [cited by applicant]