Method For Bonding Three-Dimensional Articles Made By Additive Manufacturing

1 ) A method of bonding a substrate comprising a three-dimensional printed article to another substrate, the method comprising the steps of:

(a) providing a substrate comprising a three-dimensional printed article; wherein said three-dimensional printed article is formed by photocuring a photocurable composition comprising:

(i) a photopolymerizable component,

(ii) a photoinitiator, and

(iii) a transition metal;

(b) applying a redox curable composition to at least one of said substrates; and

(c) mating together the two substrates for a time sufficient for cure of the redox curable composition to take place.

2 ) The method of bonding according to claim 1 , wherein the redox curable composition comprises a (meth)acrylate adhesive composition.

3 ) The method of bonding according to claim 1 , wherein the redox curable composition comprises an anaerobically curable composition.

4 ) The method of bonding according to claim 1 , wherein the transition metal is selected from copper, iron, vanadium, cobalt, chromium, silver, manganese and combinations thereof.

5 ) The method of bonding according to claim 1 , wherein the transition metal is present in the form of a salt.

6 ) The method of bonding according to claim 1 , wherein the transition metal is present in the photocurable composition in a mass fraction amount of from about 30 ppm to about 1000 ppm.

7 ) The method of bonding according to claim 6 , wherein the transition metal is present in the photocurable composition in a mass fraction amount of from about 50 ppm to about 750 ppm.

8 ) The method of bonding according to claim 1 , wherein the photocurable composition further comprises an amine component.

9 ) The method of bonding according to claim 8 , wherein the amine component comprises a trialkyl amine.

10 ) The method of bonding according to claim 8 , wherein the amine component is present in a mass fraction amount of from about 20 ppm to about 1000 ppm.

11 ) The method of bonding according to claim 1 , wherein the photopolymerizable component comprises one or more (meth)acrylate monomer components.

12 ) The method of bonding according to claim 11 , wherein the (meth)acrylate monomer has the formula: H2C═CGCO2R1, wherein G may be hydrogen, halogen or alkyl groups having from 1 to about 4 carbon atoms, and R1 may be selected from alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkaryl, aralkyl or aryl groups having from 1 to about 16 carbon atoms, any of which may be optionally substituted or interrupted as the case may be with silane, silicon, oxygen, halogen, carbonyl, hydroxyl, ester, carboxylic acid, urea, urethane, polyurethane, carbonate, amine, amide, sulfur, sulfonate, and sulfone.

13 ) The method of bonding according to claim 1 , wherein the time sufficient for cure of the redox curable composition is 15 minutes or less.

14 ) A photocurable composition comprising:

(i) a photopolymerizable component,

(ii) a photoinitiator,

(iii) a transition metal; and

(iv) an amine;

wherein the transition metal is present in a mass fraction amount of from about 30 ppm to about 1000 ppm based on the total mass of the photocurable composition; and wherein the amine is present in a mass fraction amount of from about 15 ppm to about 1000 ppm based on the total mass of the photocurable composition.

14 . photocurable composition according to claim 14 , wherein the amine is a trialkyl amine having the formula R3N, where each R is a C1-C12 alkyl group.

15 . photocurable composition according to claim 15 , wherein the trialkyl amine is selected from the group consisting of triethylamine, tripropylamine, tributylamine, tripentylamine, and trihexylamine.