Polarizing plate and optical display comprising the same
A polarizing plate and an optical display including the same are provided. A polarizing plate includes a polarizer; and a first retardation layer and a second retardation layer sequentially stacked on a lower surface of the polarizer, and the first retardation layer has a degree of biaxiality (NZ) of less than 0 at a wavelength of 550 nm and is a non-liquid crystal layer, and the second retardation layer has a degree of biaxiality (NZ) of greater than 1 at a wavelength of 550 nm.
1 . A polarizing plate comprising:
a polarizer; and a first retardation layer and a second retardation layer sequentially stacked on a first surface of the polarizer,
wherein the first retardation layer has a degree of biaxiality (NZ) of greater than or equal to −2 and less than 0 at a wavelength of 550 nm and is a non-liquid crystal layer, and the second retardation layer has a degree of biaxiality (NZ) of greater than 1 and less than or equal to 2 at a wavelength of 550 nm, and
wherein a laminate of the first retardation layer and the second retardation layer or a laminate comprising the first retardation layer and the second retardation layer is stacked on the first surface of the polarizer and has an out-of-plane retardation (Rth) of −80 nm to −20 nm at a wavelength of 550 nm.
2 . The polarizing plate according to claim 1 , wherein the first retardation layer has a greater absolute out-of-plane retardation (Rth) at a wavelength of 550 nm than the second retardation layer.
3 . The polarizing plate according to claim 1 , wherein the first retardation layer has an out-of-plane retardation (Rth) of −250 nm to −50 nm at a wavelength of 550 nm, and the second retardation layer has an out-of-plane retardation (Rth) of 40 nm to 150 nm at a wavelength of 550 nm.
4 . The polarizing plate according to claim 1 , wherein the first retardation layer has a greater absolute in-plane retardation (Re) at a wavelength of 550 nm than the second retardation layer.
5 . The polarizing plate according to claim 1 , wherein the first retardation layer has an in-plane retardation (Re) of 100 nm to 270 nm at a wavelength of 550 nm, and the second retardation layer has an in-plane retardation (Re) of 70 nm to 160 nm at a wavelength of 550 nm.
6 . The polarizing plate according to claim 1 , wherein the first retardation layer has negative (−) birefringence, and the second retardation layer has positive (+) birefringence.
7 . The polarizing plate according to claim 1 , wherein the first retardation layer has Rth/d of −50 nm/μm to −10 nm/μm, where Rth is an out-of-plane retardation (unit: nm) of the first retardation layer at a wavelength of 550 nm, and d is a thickness (unit: μm) of the first retardation layer.
8 . The polarizing plate according to claim 1 , wherein the first retardation layer exhibits positive dispersion, and the second retardation layer exhibits positive dispersion.
9 . The polarizing plate according to claim 1 , wherein the first retardation layer has a thickness of 15 μm or less, and the second retardation layer has a thickness of 10 μm or more.
10 . The polarizing plate according to claim 1 , wherein the first retardation layer comprises at least one selected from among a cellulose ester compound or a polymer thereof and an aromatic compound or a polymer thereof.
11 . The polarizing plate according to claim 10 , wherein the aromatic compound comprises a polystyrene compound comprising a moiety represented by the following Formula 2:
where is a linking site of an atom;
R 1 , R 2 , and R 3 are each independently a hydrogen atom, an alkyl group, a substituted alkyl group, or a halogen;
R is each independently a substituent group on a styrene ring; and
n is an integer of 0 to 5 indicating the number of substituent groups on the styrene ring.
12 . The polarizing plate according to claim 11 , wherein the moiety of Formula 2 comprises a halogen.
13 . The polarizing plate according to claim 1 , wherein the first retardation layer is directly formed on a first surface of the second retardation layer without an adhesive layer therebetween, the first surface of the second retardation layer facing the first surface of the polarizer.
14 . The polarizing plate according to claim 1 , wherein the second retardation layer is a non-liquid crystal layer.
15 . The polarizing plate according to claim 1 , wherein the polarizer has a slow axis tilted at an angle of +5° to +25° or at an angle of −25° to −5° with reference to a transmission axis of the polarizer, and the second retardation layer has a slow axis tilted at an angle of +50° to +80° or at an angle of −80° to −50° with reference to the transmission axis of the polarizer.
16 . The polarizing plate according to claim 1 , further comprising a protective layer on a second surface of the polarizer that faces away from the first surface.
17 . The polarizing plate according to claim 1 , further comprising a third retardation layer comprising a positive C layer having an out-of-plane retardation (Rth) of −300 nm to 0 nm at a wavelength of 550 nm.
18 . The polarizing plate according to claim 17 , wherein the third retardation layer is stacked between the polarizer and the first retardation layer or on a surface of the second retardation layer that faces away from the first retardation layer.
19 . The polarizing plate according to claim 1 , further comprising: a light absorbent-containing layer.
20 . The polarizing plate according to claim 19 , wherein the light absorbent-containing layer contains 0.001 wt % to 6 wt % of a light absorbent having a maximum absorption wavelength of 380 nm to 450 nm.
21 . The polarizing plate according to claim 19 , wherein the light absorbent-containing layer is on a first surface of a protective layer that is on a second surface of the polarizer that faces away from the first surface of the polarizer, between the polarizer and the protective layer, between the polarizer and the first retardation layer, between the first retardation layer and the second retardation layer, and/or on a surface of the second retardation layer that faces away from the first retardation layer.
22 . An optical display comprising the polarizing plate according to claim 1 .