IP Library Granted Patent US 12,180,115
Granted Patent B1
US 12,180,115 · App. 17/466,066 · Granted Dec 31, 2024

Yellow soda-lime-silica glass

Inventors: Scott Cooper (Maumee, OH); Casey Townsend (Perrysburg, OH); Chase Davis (Tulsa, OK)
Assignee: Owens-Brockway Glass Container Inc.
C03C3/087C03B9/30C03B25/00C03C4/02Y10T428/131
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,180,115
App. No.
17/466,066
Granted
Dec 31, 2024
Kind
B1
Abstract

A soda-lime-silica glass that has a composition comprising 60-80 wt % SiO 2 ; 8-18 wt % Na 2 O; 5-15 wt % CaO; 0-3 wt % Al 2 O 3 ; 0.0010-0.050 wt % silver expressed as Ag 2 O; and 0.005-0.30 wt % bismuth expressed as Bi 2 O 3 is disclosed. Light-scattering silver colloids are dispersed throughout the soda-lime-silica glass to provide the glass with a yellow coloration. The soda-lime-silica glass may be in the form of a body that provides a shape of a container that defines an internal containment space. The body of such a container includes a base, a mouth that defines an opening to the internal containment space, and a wall that externs from the base to the mouth. A method of making a glass container that exhibits a yellow coloration is also disclosed.

Claims (22)

1. A glass container comprising:

a soda-lime-silica glass in the form of a body that provides a shape of the container and defines an internal containment space, the body of the container including a base, a mouth that defines an opening to the internal containment space, and a wall that extends from a perimeter of the base to the mouth, the soda-lime-silica glass having a composition that comprises 60-80 wt % SiO 2 ; 8-18 wt % Na 2 O; 5-15 wt % CaO; 0-3 wt % Al 2 O 3 ; 0.0010-0.050 wt % silver expressed as Ag 2 O; and 0.005-0.30 wt % bismuth expressed as Bi 2 O 3 ; and wherein light-scattering silver colloids are dispersed throughout the soda-lime-silica glass to provide the glass with a yellow coloration.

2. The glass container set forth in claim 1 , wherein the composition of the soda-lime-silica glass further comprises at least one of 0-0.4 wt % tin expressed as SnO; 0-0.15 wt % iron expressed as Fe 2 O 3 ; 0-0.2 wt % sulfur expressed as SO 3 ; or combinations thereof.

3. The glass container set forth in claim 2 , wherein the composition of the soda-lime-silica glass comprises at least one of 0.05-0.20 wt % tin expressed as SnO; 0.01-0.10 wt % iron expressed as Fe 2 O 3 ; 0.005-0.03 wt % sulfur expressed as SO 3 ; or combinations thereof.

4. The glass container set forth in claim 1 , wherein the composition of the soda-lime-silica glass comprises 0.0025-0.0050 wt % silver expressed as Ag 2 O and 0.01-0.16 wt % bismuth expressed as Bi 2 O 3 .

5. The glass container set forth in claim 4 , wherein the composition of the soda-lime-silica glass further comprises 0.05-0.20 wt % tin expressed as SnO; 0.01-0.10 wt % iron expressed as Fe 2 O 3 ; and 0.005-0.03 wt % sulfur expressed as SO 3 .

6. The glass container set forth in claim 1 , wherein the composition of the soda-lime-silica glass is free of cadmium and lead.

7. A glass container comprising:

a body of soda-lime-silica glass that provides a shape of the glass container about a central longitudinal axis and defines an internal containment space, the body of soda-lime-silica glass including a base, a mouth that defines an opening to the internal containment space, and a wall that extends from a perimeter of the base along the longitudinal axis of the container to the mouth; the body of soda-lime-silica glass having a composition comprising 60-80 wt % SiO 2 ; 8-18 wt % Na 2 O; 5-15 wt % CaO; 0-3 wt % Al 2 O 3 ; 0.0010-0.050 wt % silver expressed as Ag 2 O; and 0.005-0.30 wt % bismuth expressed as Bi 2 O 3 ; and wherein light-scattering silver colloids are dispersed throughout the body of soda-lime-silica glass to provide the glass with a yellow coloration.

8. The glass container set forth in claim 7 , wherein the composition of the body of soda-lime-silica glass further comprises at least one of 0-0.4 wt % tin expressed as SnO; 0-0.15 wt % iron expressed as Fe 2 O 3 ; 0-0.2 wt % sulfur expressed as SO 3 ; or combinations thereof.

9. The glass container set forth in claim 8 , wherein the composition of the body of soda-lime-silica glass comprises at least one of 0.05-0.20 wt % tin expressed as SnO; 0.01-0.10 wt % iron expressed as Fe 2 O 3 ; 0.005-0.03 wt % sulfur expressed as SO 3 ; or combinations thereof.

10. The glass container set forth in claim 7 , wherein the composition of the body of the soda-lime-silica glass comprises 0.0025-0.0050 wt % silver expressed as Ag 2 O and 0.01-0.16 wt % bismuth expressed as Bi 2 O 3 .

11. The glass container set forth in claim 10 , wherein the composition of the body of soda-lime-silica glass comprises 0.05-0.20 wt % tin expressed as SnO; 0.01-0.10 wt % iron expressed as Fe 2 O 3 ; and 0.005-0.03 wt % sulfur expressed as SO 3 .

12. The glass container set forth in claim 7 , wherein the composition of the body of soda-lime-silica glass is free from cadmium and lead.

13. A method of making a glass container, the method comprising the steps of:

producing a melt of soda-lime-silica glass having a composition comprising 60-80 wt % SiO 2 ; 8-18 wt % Na 2 O; 5-15 wt % CaO; 0-3 wt % Al 2 O 3 ; 0.0010-0.050 wt % silver expressed as Ag 2 O; and 0.005-0.30 wt % bismuth expressed as Bi 2 O 3 ;

forming a glass container from the melt of soda-lime-silica glass, the glass container including a body that provides a shape of the glass container and which is comprised of the soda-lime-silica glass, wherein light-scattering silver colloids are dispersed throughout the body to provide the glass with a yellow coloration, and wherein the body defines an internal containment space and includes a base, a mouth that defines an opening to the internal containment space, and a wall that extends from a perimeter of the base to the mouth;

annealing the glass container by heating the body of soda-lime-silica glass to a temperature above an annealing point of the soda-lime-silica glass followed by cooling the glass container to a temperature below the strain point of the soda-lime-silica glass.

14. The method set forth in claim 13 , further comprising:

striking the glass container, after annealing, by heating the body of soda-lime-silica glass to a temperature above the temperature reached during annealing for a period of time and then cooling the body of soda-lime-silica glass to intensify the yellow coloration provided by the glass.

15. The method as set forth in claim 14 , wherein, during striking, the body of the soda-lime-silica glass is heated to a temperature ranging from 575° C. to 670° C. for a period of time ranging from 15 minutes to 45 minutes.

16. The method set forth in claim 13 , wherein the composition of the soda-lime-silica glass comprises at least one of 0.05-0.20 wt % tin expressed as SnO; 0.01-0.10 wt % iron expressed as Fe 2 O 3 ; 0.005-0.03 wt % sulfur expressed as SO 3 ; or combinations thereof.

Assignments (2)
SECURITY INTEREST Recorded Sep 30, 2025
From: OWENS-BROCKWAY GLASS CONTAINER INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 072989/0286 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2023
From: COOPER, SCOTT; TOWNSEND, CASEY; DAVIS, CHASE
To: OWENS-BROCKWAY GLASS CONTAINER INC.
Reel/Frame 064296/0245 →