IP Library Granted Patent US 12,258,459
Granted Patent B2
US 12,258,459 · App. 17/471,660 · Granted Mar 25, 2025

HydroFluoro olefin propellant in a polyurethane foam composition

Inventors: Andrew P. Shinko (Uniontown, OH); Anthony J. Taylor (Medina, OH)
Assignee: ICP CONSTRUCTION, INC.
C08J9/143C08G18/163C08G18/1816C08G18/225C08G18/246C08G18/3206C08G18/4018C08G18/4213C08G18/4812C08G18/4825C08G18/4829C08J9/146C08J9/228C08K3/08C08K5/053C08L75/04C08G18/18C08G2110/005C08G2110/0058C08J2203/162C08J2207/04C08J2475/06C08J2475/08C08K2003/0825C08L2203/14C08L2205/03
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Quick Facts
Patent No.
US 12,258,459
App. No.
17/471,660
Granted
Mar 25, 2025
Kind
B2
Abstract

A process and composition is described for the inclusion of polyether polyols in concentrations greater than 10% loading on the B-side formulation with a catalyst package less than 1% loading on the B-side formulation. In one specific example, the use of glycerin as a fluorine ion scavenger is utilized to improve performance of the polyurethane systems through a twelve-month shelf life.

Claims (15)

1. A two component low pressure polyurethane foam comprising:

an A-side comprising:

at least one diisocyanate, and

an HFO propellant; and

a B-side comprising:

approximately 30-50% by weight of the B-side of at least one polyester polyol;

approximately 35% or greater by weight of the B-side of at least one polyether polyol;

approximately 1-15% by weight of the B-side of a triol that comprises glycerin as a fluoride ion scavenger;

an amine catalyst;

a catalyst that includes an organotin catalyst; and

an HFO propellant; and

a catalytic decay ratio (gel) is <1.5;

a catalytic decay ratio (tack-free) is <1.5; and

water in an amount of less than 1% by weight of the B-side prior to inclusion of the HFO propellant at the B-side.

2. The polyurethane foam of claim 1 wherein the HFO propellant is 1,3,3,3-tetrafluoropropene.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 3, 2025
From: SHINKO, ANDREW P.; TAYLOR, ANTHONY J.
To: ICP ADHESIVES AND SEALANTS, INC.
Reel/Frame 069731/0795 →
MERGER Recorded Nov 14, 2022
From: ICP ADHESIVES AND SEALANTS, INC
To: ICP MERGER OPCO, LLC
Reel/Frame 061761/0252 →
MERGER Recorded Nov 14, 2022
From: ICP MERGER OPCO, LLC; ICP MERGER HOLDCO, LLC
To: ICP CONSTRUCTION, INC.
Reel/Frame 061761/0296 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 10, 2021
From: SHINKO, ANDREW P.; TAYLOR, ANTHONY J.
To: ICP ADHESIVES AND SEALANTS, INC.
Reel/Frame 057445/0153 →