SURFACE COATED ELECTRICALLY CONDUCTIVE ELASTOMERS

1 . An elastomeric material comprising a cross-linked polymeric matrix, wherein the cross-linked polymeric matrix comprises an adduct of an unsaturated precursor and a nucleophilic precursor, the adduct having Formula I:

wherein in Formula I:

p is any integer from 1 to 12;

Core 1 comprises one or more of a substituted alkyl moiety, and one or more linking groups selected from —C 1-10 alkyl-, —O—C 1-10 alkyl-, —C 1-10 alkenyl-, —O—C 1-10 alkenyl-, cycloalkenyl-, cycloalkenyl-, alkynyl-, alkynyl-, —C 1-10 aryl-, —O—C 1-10 aryl-, —O—, —S—, —C(O)—, —C(O)O—, —OC(O)—, —C(O)S—, —SC(O)—, —OC(O)O—, —N(R b )—, —C(O)N(R b )—, —N(R b )C(O)—, —OC(O)N(R b )—, —N(R b )C(O)O—, —SC(O)N(R b )—, —N(R b )C(O)S—, —N(R b )C(O)N(R b )—, —N(R b )C(NR b )N(R b )—, —N(R b )S(O) w —, —S(O) w N(R b )—, —S(O) w O—, —OS(O) w —, —OS(O) w O—, —O(O)P(OR b )O—, (O)P(O—) 3 , —O(S)P(OR b )O—, and (S)P(O—) 3 , wherein w is 1 or 2, and R b is independently hydrogen, optionally substituted alkyl, or optionally substituted aryl;

q is any integer from 1 to 12; and

Core 2 comprises one or more linking groups selected from —C 1-10 alkyl-, alkyl-, —C 1-10 alkenyl-, —O—C 1-10 alkenyl-, —C 1-10 cycloalkenyl-, —O—C 1-10 cycloalkenyl-, —C 1-10 alkynyl-, alkynyl-, —C 1-10 aryl-, aryl-, —O—, —S—, —C(O)—, —C(O)O—, —OC(O)—, —C(O)S—, —SC(O)—, —OC(O)O—, —N(R b )—, —C(O)N(R b )—, —N(R b )C(O)—, —OC(O)N(R b )—, —N(R b )C(O)O—, —SC(O)N(R b )—, —N(R b )C(O)S—, —N(R b )C(O)N(R b )—, —N(R b )C(NR b )N(R b )—, —N(R b )S(O) w —, —S(O) w N(R b )—, —S(O) w O—, —OS(O) w —, —OS(O) w O—, —O(O)P(OR b )O—, (O)P(O—) 3 , —O(S)P(OR b )O—, and (S)P(O—) 3 , wherein w is 1 or 2, and R b is independently hydrogen, optionally substituted alkyl, or optionally substituted aryl.

2 . The elastomeric material of claim 1 , wherein p is an integer from 2 to 12, an integer from 3 to 12, an integer from 3 to 5, or an integer from 3 to 6.

3 . The elastomeric material of claim 1 , wherein p is at least 2, at least 3, at least 4, at least 5, or at least 6.

4 . The elastomeric material of claim 1 , wherein p is 1, p is 2, p is 3, p is 4, p is 5, p is 6, p is 7, p is 8, p is 9, or p is 10.

5 . The elastomeric material of claim 1 , wherein q is an integer from 3 to 12, an integer from 3 to 5, or an integer from 3 to 6.

6 . The elastomeric material of claim 1 , wherein q is at least 2, at least 3, at least 4, at least 5, or at least 6.

7 . The elastomeric material of claim 1 , wherein q is 1, q is 2, q is 3, q is 4, q is 5, q is 6, q is 7, q is 8, q is 9, or q is 10.

8 . The elastomeric material of claim 1 , the adduct having Formula II:

wherein in Formula II:

R comprises one or more linking groups selected from —C 1-10 alkyl-, —O—C 1-10 alkyl-, —C 1-10 alkenyl-, —O—C 1-10 alkenyl-, —C 1-10 cycloalkenyl-, cycloalkenyl-, alkynyl-, alkynyl-, —C 1-10 aryl-, aryl-, —O—, —S—, —C(O)—, —C(O)O—, —OC(O)—, —C(O)S—, —SC(O)—, —OC(O)O—, —N(R b )—, —C(O)N(R b )—, —N(R b )C(O)—, —OC(O)N(R b )—, —N(R b )C(O)O—, —SC(O)N(R b )—, —N(R b )C(O)S—, —N(R b )C(O)N(R b )—, —N(R b )C(NR b )N(R b )—, —N(R b )S(O) w —, —S(O) w N(R b )—, —S(O) w O—, —OS(O) w —, —OS(O) w O—, —O(O)P(OR b )O—, (O)P(O—) 3 , —O(S)P(OR b )O—, and (S)P(O—) 3 , wherein w is 1 or 2, and R b is independently hydrogen, optionally substituted alkyl, or optionally substituted aryl.

9 . The elastomeric material of claim 8 , wherein the adduct is obtained by a Michael addition reaction between an urethane acrylate oligomer and a thiol comprising compound.

10 . The elastomeric material of claim 9 , wherein the urethane acrylate oligomer comprises a compound of formula:

11 . The elastomeric material of claim 9 , wherein the urethane acrylate oligomer comprises a compound of formula:

wherein R 0 can be any (hetero)hydrocarbyl groups, including aliphatic and aromatic groups; R′ 0 can be any (hetero)hydrocarbyl groups, including aliphatic and aromatic groups; n can be 2, 3, 4, 5, 6, >6.

12 . The elastomeric material of claim 9 , wherein the urethane acrylate oligomer comprises a compound of formula:

wherein R 1 comprises or consists of a hydrocarbyl group, which is carrying n —NH— groups; R 2 or R 3 each independently comprises or consists of substituents which are identical or different and interchangeable in their position, and can be chosen in some embodiments from H, alkyl or hydroxyalkyl, where alkyl can be C 1 to C 3 alkyl; m can be 0, 1, or any integer>1; R 4 comprises or consists of, an alkylene radical, cycloalkylene radical or arylene radical, which can be substituted, in particular by CH 3 , Et, CH 3 —(CH 2 ) n (where n>1), H, OH, OMe, OEt, OiPr, F, Cl, Br, I, Ph, NO 2 , SO 3 , SO 2 Me, iPr, t-Bu, sec-Bu, Et, acetyl, SH, SMe, carboxyl, aldehyde, amide, nitrile, ester, SO 2 NH 3 , NH 2 , NMe 2 , NMeH, C 2 H 2 , at any position where on the molecule could be substituted to one of the above functional groups can be considered or a combination there of; R 5 comprises or consists of, alkylene radical, cycloalkylene radical or arylene radical, which can be substituted, in particular by CH 3 , Et, CH 3 —(CH 2 )n (where n>1), H, OH, OMe, OEt, OiPr, F, Cl, Br, I, Ph, NO 2 , SO 3 , SO 2 Me, iPr, t-Bu, sec-Bu, Et, acetyl, SH, SMe, carboxyl, aldehyde, amide, nitrile, ester, SO 2 NH 3 , NH 2 , NMe 2 , NMeH, C 2 H 2 , at any position where on the molecule could be substituted to one of the above functional groups can be considered or a combination there of; n can be 2 to 6, or >6.

13 . The elastomeric material of claim 9 , wherein the thiol comprising compound comprises a multifunctional thiol represented by the formula R 8 —(SH) n , where n is 2 to 6, or >6, R 8 includes any (hetero)hydrocarbyl groups, including aliphatic and aromatic monothiols and polythiols; R 4 may optionally further include one or more functional groups including hydroxyl, acid, ester, cyano, urea, urethane and ether groups.

14 . The elastomeric material of claim 9 , wherein the thiol comprising compound comprises a multifunctional thiol represented by the formula:

wherein R 9 comprises or consists of, hydrocarbyl of valence n in polyol compound, carrying n hydroxyl groups; R 10 comprises or consists of, H or methyl group; n can be 2 to 4; m can be 0, 1, or any integer>1.

15 . The elastomeric material of claim 9 , wherein the Michael addition reaction comprises the use of a base catalyst comprising a tertiary amine comprising a 5- or 6-membered aliphatic nitrogen heterocycle, which can be selected from 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), 1, 8-diazabicyclo[5.4.0]undec-7ene (DBU) and 1,4-diazabicyclo[2/2/2]octane (DABCO) in an amount of 0.005-0.3 wt %, based on the total weight of the composition, or 1-(2-hydroxyethyl)pyrrolidine, 1-(2-hydroxyethyl)pyrrolidone, 1-(2-hydroxyethyl)piperidine, 1-ethylpiperazine, 1-(2-hydroxyethyl)piperazine, 1,4-bis-(2-hydroxyethyl)piperazine, 1-methylimidazole and 4-(2-hydroxyethyl)morpholine.

16 . The elastomeric material of claim 1 , further comprising an inorganic filler selected from a carbon based material and a metal.

17 . The elastomeric material of claim 1 , further comprising an inorganic filler selected from graphite, aluminum, copper, silver, gold, and nickel coated gold.

18 . The elastomeric material of claim 1 , further comprising a coating, wherein the coating comprises one or more of PEDOT:PSS, a sulfonated tetrafluoroethylene based fluoropolymer-copolymer, and/or a polymer binder.

19 . The elastomeric material of claim 18 , wherein the coating comprises a polymer binder, wherein the polymer binder comprises a thermoplastic polymer or cross-linked polymeric matrix.

20 . An electrode comprising the elastomeric material of claim 1 .