Processes for producing lithium compounds using reverse osmosis
Provided are methods of extracting lithium from a lithium containing solution, as well as the resulting compositions. The method includes supplying a lithium containing solution to a lithium capture step, the lithium capture step being operable to capture lithium from the lithium salt containing solution. The method further includes recovering lithium from the lithium capture step to produce a lithium rich stream. In especially preferred methods, the lithium capture step is performed to increase the lithium to sodium ratio above at least 1:1. Optionally, the lithium rich stream can be purified to remove divalent ions and borate ions. The lithium rich stream is then concentrated by supplying the lithium rich stream to a reverse osmosis step to produce a concentrated lithium rich stream.
1 . A method of extracting lithium from a lithium containing solution, the method comprising:
processing a lithium containing solution in a lithium capture step, wherein the lithium capture step includes:
contacting the lithium containing solution with a sorbent material to capture lithium;
stripping the sorbent material to produce an eluate;
recycling at least a portion of the eluate back to the sorbent material, wherein the portion of the eluate comprises lithium;
recovering lithium from the eluate after the recycling step to produce a lithium rich stream; and
concentrating the lithium rich stream by processing the lithium rich stream in a reverse osmosis step to produce a concentrated lithium rich stream.
2 . The method of claim 1 , wherein the lithium rich stream comprises divalent ions and borate ions.
3 . The method of claim 2 , further comprising purifying the lithium rich stream to remove divalent ions and borate ions.
4 . The method of claim 1 , wherein the portion of the eluate has a higher lithium to sodium ratio as compared to the lithium containing solution.
5 . The method of claim 1 , wherein the reverse osmosis step is a cascade reverse osmosis system.
6 . The method of claim 1 , further comprising a purification step for decreasing the concentration of at least one of calcium, magnesium, manganese, or zinc in the lithium rich stream after the lithium capture step, the purification step comprising:
contacting the lithium rich stream with a base or a carbonate such that at least a portion of the calcium, magnesium, manganese, or zinc precipitates as a solid carbonate salt; and
separating the solid carbonate salt from a purified lithium rich stream, wherein the purified lithium rich stream has a lower concentration of at least one of calcium, magnesium, manganese, or zinc.
7 . The method of claim 1 , further comprising a purification step for decreasing the concentration of at least one of calcium, magnesium, manganese, or zinc in the lithium rich stream after the lithium capture step, the purification step comprising:
contacting the lithium rich stream with a base and/or a carbonate wherein at least a portion of the calcium, magnesium, manganese, or zinc precipitates as a solid carbonate salt;
separating the solid carbonate salt from a purified lithium rich stream; and
treating the lithium containing solution with an ion selective media to further remove trace concentrations of divalent ions and boron;
wherein the purified lithium rich stream has a lower concentration of at least one of calcium, magnesium, manganese, zinc, or boron.
8 . The method of claim 1 , wherein the lithium capture step selectively isolates lithium and allows other cations present in the lithium containing solution not to be co-extracted.
9 . The method of claim 1 , wherein the lithium capture step comprises the step of contacting the lithium containing solution with a lithium sorbent material for capturing lithium until the lithium sorbent material is saturated with lithium to produce a saturated lithium sorbent material.
10 . The method of claim 9 , wherein the lithium capture step comprises stripping the saturated lithium sorbent material with water to produce the lithium rich stream.
11 . The method of claim 9 , wherein the lithium sorbent material is an intercalated lithium sorbent.
12 . The method of claim 9 , wherein during the step of contacting the lithium sorbent material and the lithium containing solution, a temperature of the lithium containing solution is maintained above 70° C.