Polyamide-based film, preparation method thereof, and cover window and display device comprising same
The embodiments relate to a polyamide-based film excellent in optical properties such as transmittance, haze, and yellow index and mechanical properties such as modulus and thickness uniformity, to a process for preparing the same, and to a cover window and a display device comprising the same. The polyamide-based film comprises a polyamide-based polymer and has an XRD pattern comprising a first peak whose highest point is located in a section where 2θ is 14° to 16°.
1. A polyamide-based film, which comprises a polyamide-based polymer and comprises an XRD pattern including a first peak on an XRD graph, wherein the highest point of the first peak is located in a section where 2θ is 14° to 16°,
wherein the polyamide-based polymer comprises an amide repeat unit derived from the polymerization of a diamine compound and a dicarbonyl compound, and wherein the dicarbonyl compound comprises a first dicarbonyl compound and a second dicarbonyl compound, and the molar ratio of the first dicarbonyl compound to the second dicarbonyl compound is 25:75 to 79:21.
2. The polyamide-based film of claim 1 , wherein a distance between crystal planes corresponding to the first peak is 5.4 Å to 6.3 Å.
3. The polyamide-based film of claim 1 , wherein the polyamide-based polymer comprises a plurality of crystal forms having different distances between crystal planes, and the ratio of the crystal form having a distance between crystal planes of 5.4 Å to 6.3 Å among the plurality of crystal forms is the highest.
4. The polyamide-based film of claim 1 , wherein the XRD pattern further comprises a second peak in a section where 2θ is 20° to 25°, and the ratio (P a /P b ) of a maximum value (P a ) of the first peak to a maximum value (P b ) of the second peak is 1.03 to 1.15.
5. The polyamide-based film of claim 1 ,
wherein an angle between two carbonyl groups contained in the first dicarbonyl compound is greater than an angle between two carbonyl groups contained in the second dicarbonyl compound.
6. The polyamide-based film of claim 1 , which, based on a thickness of the film of 50 μm, has a modulus of 5 GPa or more, a transmittance of 80% or more, a haze of 1% or less, a yellow index of 3 or less, and a thickness deviation of 4 μm or less.
7. A cover window for a display device, which comprises the polyamide-based film of claim 1 ; and a functional layer.
8. A display device, which comprises a display unit; and a cover window disposed on the display unit, wherein the cover window comprises the polyamide-based film of claim 1 , and a functional layer.
9. A preparation method of the polyamide-based film of claim 1 , which comprises polymerizing a diamine compound and a dicarbonyl compound in an organic solvent to prepare a solution comprising a polyamide-based polymer; casting the polymer solution to prepare a gel sheet; and thermally treating the gel sheet,
wherein a step of preparing the solution comprising the polyamide-based polymer is carried out at a temperature of −10° C. to 25° C.,
the preparation method further comprising adjusting the viscosity of the solution to 200,000 cps to 350,000 cps after the step of preparing the solution comprising the polyamide-based polymer, and
the preparation method further comprising aging the solution comprising the polyamide-based polymer at −10° C. to 10° C.