IP Library Granted Patent US 12,116,456
Granted Patent B2
US 12,116,456 · App. 17/484,644 · Granted Oct 15, 2024

Fluoropolyether group containing compound

Inventors: Tsuneo Yamashita (Osaka, JP); Hisashi Mitsuhashi (Osaka, JP); Takeshi Maehira (Osaka, JP); Yoshimi Motonari (Osaka, JP)
Assignee: DAIKIN INDUSTRIES, LTD.
C08G65/336
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Quick Facts
Patent No.
US 12,116,456
App. No.
17/484,644
Granted
Oct 15, 2024
Kind
B2
Abstract

A fluoropolyether group-containing compound of the following formula (1) or (2): R F1 —X—R Si   (1) R Si —X—R F2 —X—R Si   (2) wherein R F1 , R Si and R F2 are as defined herein.

Claims (49)

1. A fluoropolyether group-containing compound of the following formula (1) or (2):

R F1 —X—R Si   (1)

R Si —X—R F2 —X—R Si   (2)

wherein

R F1 is Rf 1 —R F —O q —;

R F2 is —Rf 2 p —R F —O q —;

Rf 1 is a C 1-16 alkyl group optionally substituted with one or more fluorine atoms;

Rf 2 is a C 1-6 alkylene group optionally substituted with one or more fluorine atoms;

R F is each independently at each occurrence a group represented by formula:

—(OC 6 F 12 ) a —(OC 5 F 10 ) b —(OC 4 F 8 ) c —(OC 3 R Fa 6 ) d —(OC 2 F 4 ) e —(OCF 2 ) f —;

a, b, c, d, e, and f are each independently an integer of 0 to 200, the sum of a, b, c, d, e, and f is one or more, and the occurrence order of the respective repeating units enclosed in parentheses provided with a, b, c, d, e, or f is not limited in the formula;

R Fa is each independently at each occurrence a hydrogen atom, a fluorine atom, or a chlorine atom;

p is 0 or 1;

q is independently 0 or 1;

X is a group represented by the following formula:

R X1 is each independently at each occurrence a C 1-6 alkylene group;

R X2 is each independently at each occurrence a C 1-6 alkylene group optionally substituted with a C 1-6 alkyl group or cyclic alkyl group optionally containing one or more nitrogen atoms, oxygen atoms, sulfur atoms, or silicon atoms, or with a perfluoroalkyl group;

R y is each independently at each occurrence a hydrogen atom, a C 1-6 alkyl group, or a phenyl group;

X 11 is each independently at each occurrence a single bond, an oxygen atom, or a divalent organic group;

R Si is each independently at each occurrence represented by the following formula (S1):

—CR d1 k2 R e1 12 R f1 m2   (S1);

R d1 is each independently at each occurrence —Z 2 —CR 31 p2 R 32 q2 R 33 r2 ;

Z 2 is each independently at each occurrence a single bond, an oxygen atom, or a divalent organic group;

R 31 is each independently at each occurrence —Z 2′ —CR 32′ q2′ R 33′ r2′ ;

Z 2′ is each independently at each occurrence a single bond, an oxygen atom, or a divalent organic group;

R 32′ is each independently at each occurrence —Z 3 —SiR 34 n2 R 35 3-n2 ;

R 33′ is each independently at each occurrence a hydrogen atom, a hydroxyl group, or a monovalent organic group;

q2′ is each independently at each occurrence an integer of 0 to 3;

r2′ is each independently at each occurrence an integer of 0 to 3;

Z 3 is each independently at each occurrence a single bond, an oxygen atom, or a divalent organic group;

R 34 is each independently at each occurrence a hydroxyl group or a hydrolyzable group;

R 35 is each independently at each occurrence a hydrogen atom or a monovalent organic group;

n2 is each independently at each occurrence an integer of 1 to 3;

R 32 is each independently at each occurrence —Z 3 —SiR 34 n2 R 35 3-n2 ;

R 33 is each independently at each occurrence a hydrogen atom, a hydroxyl group, or a monovalent organic group;

p2 is each independently at each occurrence an integer of 0 to 3;

q2 is each independently at each occurrence an integer of 0 to 3;

r2 is each independently at each occurrence an integer of 0 to 3;

R e1 is each independently at each occurrence —Z 3 —SiR 34 n2 R 35 3-n2 ;

R f1 is each independently at each occurrence a hydrogen atom, a hydroxyl group, or a monovalent organic group;

k2 is each independently at each occurrence an integer of 0 to 2;

l2 is each independently at each occurrence an integer of 1 to 3; and

m2 is each independently at each occurrence an integer of 0 to 2.

2. The fluoropolyether group-containing compound according to claim 1 , wherein X 11 is a divalent organic group.

3. The fluoropolyether group-containing compound according to claim 1 , wherein X 11 is a C 1-6 alkylene group.

4. The fluoropolyether group-containing compound according to claim 1 , wherein n2 is 2 or 3.

5. The fluoropolyether group-containing compound according to claim 1 , wherein k2 is 0 and 12 is 3.

6. The fluoropolyether group-containing compound according to claim 1 , wherein R y is a hydrogen atom or a C 1-6 alkyl group.

7. The fluoropolyether group-containing compound according to claim 1 , wherein R Fa is a fluorine atom.

Assignments (2)
CHANGE OF ADDRESS Recorded Jan 11, 2023
From: DAIKIN INDUSTRIES LTD.
To: DAIKIN INDUSTRIES LTD.
Reel/Frame 062355/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 24, 2021
From: YAMASHITA, TSUNEO; MITSUHASHI, HISASHI; MAEHIRA, TAKESHI; MOTONARI, YOSHIMI
To: DAIKIN INDUSTRIES, LTD.
Reel/Frame 057594/0351 →
Priority Claims (1)
JP 2019-066346 · Mar 29, 2019 · national
Continuity (2)
Continuation PCTJP2020013752 · Mar 26, 2020
Related Publication 20220017694A1 · Jan 20, 2022