Cathode active material for lithium secondary battery and lithium secondary battery including the same
A cathode active material for a lithium secondary battery according to an embodiment of the present invention includes a lithium composite oxide particle that contains lithium and transition metals including an excess amount of nickel. The lithium composite oxide particle satisfies a predetermined XRD peak area relation. A lithium secondary battery using the cathode active material and providing improved stability and durability is provided.
1. A cathode active material for a lithium secondary battery comprising a lithium composite oxide particle that contains lithium and transition metals including nickel,
wherein a molar ratio of nickel in the transition metals contained in the lithium composite oxide particle is 0.5 or more,
wherein the lithium composite oxide particle satisfies Equation 1 and Equation 2:
1.0≤ A (003)/ A (104)≤1.5 [Equation 1]
wherein, in Equation 1, A(003) is an area of a peak corresponding to a (003) plane in an X-ray diffraction (XRD) analysis graph, and A(104) is an area of a peak corresponding to a (104) plane in the XRD analysis graph,
7.0≤ A (104)/ A (105) [Equation 2]
wherein, in Equation 2, A(104) is the area of the peak corresponding to the (104) plane in the XRD analysis graph, and A(105) is an area of a peak corresponding to a (105) plane in the XRD analysis graph.
2. The cathode active material for a lithium secondary battery of claim 1 , wherein the lithium composite oxide particle has a single particle shape.
3. The cathode active material for a lithium secondary battery of claim 2 , wherein the lithium composite oxide particle having the single particle shape has a particle diameter from 3 μm to 12 μm.
4. The cathode active material for a lithium secondary battery of claim 1 , wherein a spacing between (003) planes of the lithium composite oxide particle is from 100 nm to 210 nm.
5. The cathode active material for a lithium secondary battery of claim 1 , wherein a full width at half maximum (FWHM) corresponding to the (003) plane in the XRD analysis graph of the lithium composite oxide particle is from 0.066° to 0.072°.
6. The cathode active material for a lithium secondary battery of claim 1 , wherein a full width at half maximum (FWHM) corresponding to the (104) plane in the XRD analysis graph of the lithium composite oxide particle is from of 0.08° to 0.108°.
7. The cathode active material for a lithium secondary battery of claim 1 , wherein A(003)/A(104) of the lithium composite oxide particle is from 1.1 to 1.4.
8. The cathode active material for a lithium secondary battery of claim 1 , wherein A(104)/A(105) of the lithium composite oxide particle is from 7.0 to 8.5.
9. The cathode active material for a lithium secondary battery of claim 1 , wherein a reduction ratio of a specific surface area of the lithium composite oxide particle by a pressure from 2.5 tons to 3.5 tons is from 10% to 30%.
10. The cathode active material for a lithium secondary battery of claim 1 , wherein the transition metals of the lithium composite oxide particle further include cobalt and manganese.
11. The cathode active material for a lithium secondary battery of claim 1 , wherein the lithium composite oxide particle are represented by Chemical Formula 1:
Li x Ni a M 1-a O y [Chemical Formula 1]
wherein, in Chemical Formula 1, M is at least one of Al, Zr, Ti, Cr, B, Mg, Co, Mn, Ba, Si, Y, W and Sr, 0.9≤x≤1.2, 1.9≤y≤2.1 and 0.5≤a≤1.
12. A lithium secondary battery, comprising:
a cathode comprising the cathode active material for a lithium secondary battery of claim 1 ; and an anode facing the cathode.
13. The lithium secondary battery of claim 12 , wherein a reversible capacity increases by 2% to 10% as a charging voltage increases by 0.1V based on 4.3V.