Heat shrinkable film and method for reproducing polyester container using same
The embodiments relate to a heat shrinkable film and a process for regenerating a polyester container using the same. The heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds, a melting point of 190° C. or higher as measured by differential scanning calorimetry, and a peak temperature (Tp) of 95° C. to 115° C. as measured in the endothermic and exothermic curve (heat flow) by differential scanning calorimetry. It not only solves the environmental problem by improving the recyclability of the polyester container, but also is capable of enhancing the yield and productivity.
1. A heat shrinkable film, which comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component, and
which has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds,
a melting point of 190° C. or higher as measured by differential scanning calorimetry, and
a peak temperature (Tp) of 95° C. to 115° C. as measured in the endothermic and exothermic curve (heat flow) by differential scanning calorimetry.
2. The heat shrinkable film of claim 1 , which has a clumping fraction of 8% or less.
3. The heat shrinkable film of claim 1 , which has a crystallization temperature that is not measured or is 70° C. to 95° C. by differential scanning calorimetry.
4. The polyester film of claim 1 , which has a heat of crystallization at the crystallization temperature that is not measured or is 0.01 to 50 J/g.
5. The heat shrinkable film of claim 1 , wherein the diol component is at least one selected from the group consisting of ethylene glycol, diethylene glycol, neopentyl glycol, and cyclohexanedimethanol.
6. The heat shrinkable film of claim 1 , wherein the copolymerized polyester resin comprises neopentyl glycol in an amount of 5 to 35% by mole based on the total number of moles of the diol component.
7. The heat shrinkable film of claim 1 , which has a heat shrinkage rate of 5% to 55% in the main shrinkage direction upon thermal treatment at a temperature of 70° C. for 10 seconds,
wherein the rate of increase in the heat shrinkage rate in the main shrinkage direction in the temperature range of 0.35×Tm° C. to 0.40×Tm° C. is 2.5%/° C. to 4.0%/° C., and
the rate of increase in the heat shrinkage rate in the main shrinkage direction in the temperature range of 0.45×Tm° C. to 0.50×Tm° C. is 0.1%/° C. to 1.0%/° C.
8. A process for regenerating a polyester container, which comprises:
preparing a polyester container provided with the heat shrinkable film according to claim 1 ;
crushing the container provided with the heat shrinkable film to obtain flakes; and
thermally treating the flakes to produce regenerated polyester chips,
the flakes comprise first flakes obtained by crushing the container and second flakes obtained by crushing the heat shrinkable film.
9. The process for regenerating a polyester container of claim 1 , wherein when the flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes 120 minutes, the clumping fraction is 8% or less.