Organic electroluminescent compound and organic electroluminescent device comprising the same
The present disclosure relates to an organic electroluminescent compound, and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound according to the present disclosure in a light-emitting layer, it is possible to produce an organic electroluminescent device having an improved driving voltage, luminous efficiency and/or lifetime properties.
1 . An organic electroluminescent compound represented by following formula 1-1:
Ar represents a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30) aryl, or a substituted or unsubstituted (3- to 30-membered) heteroaryl;
L represents a single bond, a substituted or unsubstituted (C6-C30) arylene, or a substituted or unsubstituted (3- to 30-membered) heteroarylene;
R 1 , R 2 , R 3 , and R 4 , each independently, represent hydrogen, deuterium, a cyano, a (C1-C30)alkyl, a (C2-C30)alkenyl, a (C2-C30)alkynyl, a (C3-C30) cycloalkyl; a (C3-C30)cycloalkenyl, a (3- to 7-membered)heterocycloalkyl, a (C6-C30)aryloxy, a (C6-C30)arylthio, a (C6-C30)aryl, a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, a (C1-C30)alkyl(C6-C30)aryl, or -L 1 (Ar 1 ) a,
with the proviso that at least one of R 1 , R 2 , R 3 , and R 4 represents -L1 (Ar 1 )a; and
L 1 represents a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
Ar 1 , each independently, is represented by any one of the following formulas 1-11 to 1-20:
in formulas 1-11, X represents O, or S;
in formula 1-12, formula 1-16, and formula 1-20, X represents O, S, or N(Ra);
in formula 1-13, formula 1-14, formula 1-15, and formula 1-18, X represents O, S, or N(Ra) and Y represents O, S, N(Ra), or C(Rb)(Rc);
in formula 1-19, Y represents O, S, N(Ra), or C(Rb)(Rc);
n represents an integer of 0 or 1; and
R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 , R 28 , R 29 , R 30 , R 31 , R 32 , R 33 , R 34 , R 35 , R 36 , R 37 , R 38 , R 39 , R 40 , R 41 , R 42 , R 43 , R 44 , R 45 , R 46 , R 47 , R 48 , R 49 , R 50 , R 51 , R 52 , R 53 , R 54 , R 55 , R 56 , R 57 , R 58 , R 59 , R 60 , R 61 , R 62 , R 63 , R 64 , R 65 , R 66 , R 67 , R 68 , R 69 , R 70 , R 71 , R 72 , R 73 , R 74 , R 75 , R 76 , R 77 , R 78 , R 79 , R 80 , R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 , R 88 , R 89 , R 90 , R 91 , R 92 , R 93 , R 94 , R 95 , R 96 , R 97 , Ra, Rb, and Rc, each independently, represent a position linked to -L 1 , or represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl, in which each of two R 30 , each of two R 35 may be the same or different
wherein the substituent(s) of the substituted alkyl, the substituted aryl, the substituted arylene, the substituted heteroaryl, and the substituted heteroarylene, each independently, are at least one selected from the group consisting of deuterium; a halogen; a cyano; a carboxyl; a nitro; a phosphineoxide; a (C1-C30)alkyl; a halo(C1-C30)alkyl; a (C2-C30)alkenyl; a (C2-C30)alkynyl; a (C1-C30)alkylthio; a (C3-C30)cycloalkyl; a (C6-C30)cycloalkenyl; a (3- to 7-membered)heterocycloalkyl; a (C6-C30)aryloxy; a (C6-C30)arylthio; a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl(s); a (C6-C30)aryl unsubstituted or substituted with a (3- to 30-membered)heteroaryl(s); a tri(C1-C30)alkylsilyl; a tri(C6-C30)arylsilyl; a di(C1-C30)alkyl(C6-C30)arylsilyl; a (C1-C30)alkyldi(C6-C30)arylsilyl; a (C1-C30)alkylcarbonyl; a (C1-C30)alkoxycarbonyl; a (C6-C30)arylcarbonyl; a (C6-C30)arylphosphine; a di(C6-C30)arylboronyl; a di(C1-C30)alkylboronyl; a (C1-C30)alkyl(C6-C30)arylboronyl; a (C6-C30)aryl(C1-C30)alkyl; and a (C1-C30)alkyl(C6-C30)aryl; and
a represents an integer of 1 or 2, where if a is an integer of 2, each of Ar 1 may be the same or different; and
with the proviso that when R 1 and R 4 represent -L 1 (Ar 1 )a, L 1 represents a single bond, Ar 1 is represented by formula 1-11, and a represents an integer of 1, then neither R 21 nor R 28 is a position linked to -L 1 .
2 . An electroluminescent compound selected from the following compounds:
3 . An organic electroluminescent material, wherein the organic electroluminescent material comprises at least one the organic electroluminescent compound according to claim 1 .
4 . An organic electroluminescent material, wherein the organic electroluminescent material comprises at least one organic electroluminescent compound according to claim 2 .