Compositions for increasing nitrogen sources life span in plant growth mediums and methods of making
The present invention relates to compositions for increasing a nitrogen source life span in plant growth mediums as well as methods of making these compositions. The invention also relates to compositions and methods of reacting a nitrogen source with one or more nitrification inhibitors using standard equipment for producing nitrogen sourced particles.
1. A method of making a solid fertilizer composition wherein the solid fertilizer composition comprises a) urea granules and/or urea prills and b) a liquid solution wherein said liquid solution comprises i) one or more biodegradable polymeric and/or oligomeric nitrification inhibitors (BPONIs) and ii) a NOSDS (Non-aqueous Organic Solvent Delivery System) wherein said one or more biodegradable polymeric and/or oligomeric nitrification inhibitors (BPONI) are selected from the group consisting of:
wherein R 43 and R 44 , R 45 and R 46 are one or more members independently selected from the group consisting of: H, and —CH 2 OH,
wherein R 47 , R 48 , R 49 R 50 , R 51 and R 52 are one or more members independently selected from the group consisting of: H, and —CH 2 OH,
wherein R 53 , R 54 , R 55 , R 56 , R 57 , R 58 , R 59 and R 60 are one or more members independently selected from the group consisting of: H and —CH 2 OH, and
wherein R 61 , R 62 , R 63 , R 64 , R 65 , R 66 , R 67 and R 68 are one or more members independently selected from the group consisting of: H and —CH 2 OH, and x=2-20,
wherein the method comprises coating said urea granules and/or urea prills with the liquid solution at a temperature range between 20-80° C., and wherein said one or more BPONIs do not react with said urea granules and/or urea prills.
2. The method of claim 1 , wherein the fertilizer composition further comprises one or more biologically active agents selected from the group consisting of a) one or more urease inhibitors, b) one or more nitrification inhibitors, c) one or more pesticides, d) one or more herbicides, e) one or more fungicides, and f) one or more insecticides.
3. The method of claim 2 , wherein said one or more urease inhibitors comprise N-(n-butyl)thiophosphoric triamide (NBPT).
4. The method of claim 3 , wherein said NBPT is applied in a solution onto a surface of urea.
5. The method of claim 1 , wherein the solid fertilizer composition further comprises one or more members selected from the group consisting of:
a. a colorant that does not contain water and/or an alcohol,
b. one or more members selected from the group consisting of fragrances, scents and masking agents,
c. one or more surfactants selected from the group consisting of i) nonionic, ii) anionic, iii) cationic, iv) zwitterionic, and v) amphoteric surfactants,
d. one or more buffering agents,
e. one or more flow modifiers, and
f. one or more catalysts.
6. The method of claim 5 , wherein said one or more flow modifiers comprise silicas.
7. The method of claim 5 , wherein said one or more flow modifiers comprise hydrophobized silicas.
8. The method of claim 1 , wherein the liquid solution further comprises one or more members selected from the group consisting of a) dicyandiamide and b) one or more additional biodegradable polymeric and/or oligomeric nitrification inhibitors wherein said one or more additional biodegradable polymeric and/or oligomeric nitrification inhibitors comprise one or more dimethylene ether functionalities.
9. The method of claim 8 , wherein the one or more additional biodegradable polymeric and/or oligomeric nitrification inhibitors comprise the structure:
wherein
xx=1-9,
yy=0-8,
R 69 is one or more members selected from the group consisting of: H and CH 2 OH,
E is selected from the group consisting of CH 2 and CH 2 OH,
R 70 is one or more members selected from the group consisting of H and CH 2 OH.
10. The method of claim 1 , wherein the solid fertilizer composition is made by one or more processes selected from the group consisting of a) an urea rotating drum granulation, b) an urea fluidized bed granulation and c) an urea prilling tower process, wherein the liquid solution is coated onto the urea granules and/or urea prills and wherein a temperature of application of said liquid solution onto the urea granules and/or urea prills is low enough to prevent reaction of the one or more BPONIs with urea.
11. The method of claim 10 , wherein the temperature of application of said liquid solution as a coating on the urea granules and/or urea prills is ≤70° C.
12. The method of claim 1 , wherein the liquid solution further comprises one or more biologically active agents selected from the group consisting of a) one or urease inhibitors, b) one or more nitrification inhibitors, c) one or more pesticides, d) one or more herbicides, e) one or more fungicides, and f) one or more insecticides.
13. The method of claim 12 , wherein the one or more urease inhibitors comprise N-(n-butyl)thiophosphoric triamide (NBPT).
14. The method of claim 1 , wherein said NOSDS comprises one or more solvents selected from the group consisting of a) one or more aprotic solvents and b) one or more protic solvents,
wherein the one or more aprotic solvents are selected from the group consisting of:
i) dimethyl sulfoxide (DMSO),
ii) dialkyl, diaryl, or alkylaryl sulfoxide(s) having the formula:
R 9 S(O) x R 10 ,
wherein R 9 and R 10 are each independently a C 1-6 alkylene group, an aryl group, or C 1-3 alkylenearyl group or R 9 and R 10 together with the sulfur to which they are attached form a 4 to 8 membered ring wherein R 9 and R 10 together are a C 1-6 alkylene group which optionally contains one or more atoms selected from the group consisting of O, S, Se, Te, N, and P in the ring and x is 1 or 2,
iii) one or more alkylene carbonates selected from the group consisting of ethylene carbonate, propylene carbonate and butylene carbonate, iv) one or more alkyl pyrrolidones selected from the group consisting of 1-Methyl-2-pyrrolidone and butyl pyrrolidone, v) one or more organo phosphorous liquids selected from the group consisting of hexamethylphosphoramide, vi) one or more trialkylphosphates selected from the group represented by the formula:
wherein:
R 22 is alkyl radical —C 1 H 3 to —C 6 H 13
R 23 is alkyl radical —C 1 H 3 to —C 6 H 13
R 24 is alkyl radical —C 1 H 3 to —C 6 H 13
vii) 1,2-dimethyloxyethane, viii) 2-methoxyethyl ether and ix) cyclohexylpyrrolidone, and
wherein the one or more protic solvents are selected from the group consisting of: i) an alcohol from the family of C 1-10 alkanols, ii) one or more polyols selected from the group consisting of trimethylol propane, trimethylol ethane, pentaerythritol, sorbitol, sorbitan, glucose, fructose, galactose, and glycerin, iii) poly(C 1-10 alkylene) glycols, iv) one or more alkylene glycols selected from the group consisting of ethylene glycol, 1,3 propylene glycol, 1,2 propylene glycol, and butylene glycol, v) isopropylidene glycerol vi) one or more alkylene glycol alkyl ethers represented by the structure:
where R 1 is: CH 3 , C 2 H 5 , C 3 H 7 or C 4 H 9
where R 2 is: H or
where R 3 is: H or CH 3
where R 4 is H and/or CH 3
and f is an integer between 1 and 15
vii) one or more alkyl lactates from the group consisting of ethyl lactate, propyl lactate and butyl lactate, viii) one or more alkanolamines represented by the structure:
where R 5 is: C 2 H 4 OR 8 or C 3 H 6 OH
where R 6 is: H, C 2 H 4 OR 8 or C 3 H 6 OH
where R 7 is: H, C 2 H 4 OR 8 or C 3 H 6 OH
where R 8 is: (C 2 H 4 O) g H
and g is an integer between 1-10, and
ix) glycerol carbonate.
15. The method of claim 1 , wherein the liquid solution further comprises one or more members selected from the group consisting of:
a. a colorant that does not contain water and/or an alcohol,
b. one or more members selected from the group consisting of fragrances scents and masking agents,
c. one or more surfactants selected from the group consisting of i) nonionic, ii) anionic, iii) cationic, iv) zwitterionic, and v)amphoteric surfactants,
d. one or more buffering agents, and
e. one or more catalysts.
16. The method of claim 1 , wherein the liquid solution comprises dimethyl sulfoxide.
17. The method of claim 1 , wherein the fertilizer composition further comprises one or more nitrogen sources selected from the group consisting of i) urea formaldehyde reaction products, ii) urea, formaldehyde and ammonia reaction products, iii) ammonium nitrate, iv) ammonium sulfate, v) manure, vi) monoammonium phosphate, vii) diammonium phosphate, and viii) compost.
18. The method of claim 1 , wherein the liquid solution is anhydrous.
19. A method of making a solid fertilizer composition wherein the solid fertilizer composition comprises a) urea granules and/or urea prills and b) a liquid solution wherein said liquid solution comprises i) one or more biodegradable polymeric and/or oligomeric nitrification inhibitors (BPONIs) and ii) DMSO wherein said one or more biodegradable polymeric and/or oligomeric nitrification inhibitors (BPONIs) are selected from the group consisting of:
wherein R 43 and R 44 , R 45 and R 46 are one or more members independently selected from the group consisting of: H, and —CH 2 OH,
wherein R 47 , R 48 , R 49 R 50 , R 51 and R 52 are one or more members independently selected from the group consisting of: H, and —CH 2 OH,
wherein R 53 , R 54 , R 55 , R 56 , R 57 , R 58 , R 59 and R 60 are one or more members independently selected from the group consisting of: H and —CH 2 OH,
wherein R 61 , R 62 , R 63 , R 64 , R 65 , R 66 , R 67 and R 68 are one or more members independently selected from the group consisting of: H and —CH 2 OH, and x=2-20,
wherein the method comprises coating said urea granules and/or urea prills at a temperature range between 20-80° C. and wherein said one or more BPONIs do not react with said urea granules and/or urea prills.
20. The method of claim 19 , wherein the solid fertilizer composition further comprises one or more members selected from the group consisting of:
a. a colorant that does not contain water and/or an alcohol,
b. one or more members selected from the group consisting of scents and masking agents,
c. one or more surfactants selected from the group consisting of i) nonionic, ii) anionic, iii) cationic, iv) zwitterionic, and v)amphoteric surfactants,
d. one or more buffering agents,
e. one or more flow modifiers, and
f. one or more catalysts.
21. The method of claim 19 , wherein the liquid solution further comprises one or more members selected from the group consisting of a) dicyandiamide and b) one or more additional biodegradable polymeric and/or oligomeric nitrification inhibitors wherein said one or more additional biodegradable polymeric and/or oligomeric nitrification inhibitors comprise one or more dimethylene ether functionalities.
22. The method of claim 19 , wherein the liquid solution is anhydrous.