Compositions and processes for depositing carbon-doped silicon-containing films
Described herein are compositions for depositing a carbon-doped silicon containing film comprising: a precursor comprising at least one compound selected from the group consisting of: an organoaminosilane having a formula of R 8 N(SiR 9 LH) 2 , wherein R 8 , R 9 , and L are defined herein. Also described herein are methods for depositing a carbon-doped silicon-containing film using the composition wherein the method is one selected from the following: cyclic chemical vapor deposition (CCVD), atomic layer deposition (ALD), plasma enhanced ALD (PEALD) and plasma enhanced CCVD (PECCVD).
1. A method of forming a carbon-doped silicon nitride film via an atomic layer deposition process, the method comprising the steps of:
a. providing a substrate in a reactor;
b. introducing into the reactor a precursor comprising at least one organoaminosilane having a formula of R 8 N(SiR 9 LH) 2 , wherein
R 8 is selected from the group consisting of a C 3 to C 10 linear or branched alkyl group, a C 3 to C 10 cyclic alkyl group, a linear or branched C2 to C 10 alkenyl group, a linear or branched C2 to C 10 alkynyl group, a C 5 to C 10 aromatic group, and a C 3 to C 10 saturated or unsaturated heterocyclic group;
R 9 selected from the group consisting of hydrogen, C 1 to C 10 linear or branched alkyl, a C 3 to C 10 cyclic alkyl group, a linear or branched C2 to C 10 alkenyl group, a linear or branched C 2 to C 10 alkynyl group, a C 5 to C 10 aromatic group, and a C 3 to C 10 saturated or unsaturated heterocyclic group; and
L is selected from the group consisting of Cl, Br, and I;
c. purging the reactor with a purge gas;
d. introducing a nitrogen source into the reactor wherein the nitrogen source is selected from the group consisting of ammonia, hydrazine, monoalkylhydrazine, dialkylhydrazine, nitrogen, nitrogen/hydrogen, ammonia plasma, nitrogen plasma, nitrogen/hydrogen plasma, and mixture thereof; and
e. purging the reactor with a purge gas, wherein steps b through e are repeated until a desired thickness of the film is obtained.
2. A method of forming a carbon-doped silicon oxide film via an atomic layer deposition process, the method comprising the steps of:
a. providing a substrate in a reactor;
b. introducing into the reactor at least one compound selected from the group consisting of:
an organoaminosilane having a formula of R 8 N(SiR 9 LH) 2 , wherein
R 8 is selected from the group consisting of a C 3 to C 10 linear or branched alkyl group, a C 3 to C 10 cyclic alkyl group, a linear or branched C2 to C 10 alkenyl group, a linear or branched C 2 to C 10 alkynyl group, a C 5 to C 10 aromatic group, and a C 3 to C 10 saturated or unsaturated heterocyclic group;
R 9 selected from the group consisting of hydrogen, C 1 to C 10 linear or branched alkyl, a C 3 to C 10 cyclic alkyl group, a linear or branched C 2 to C 10 alkenyl group, a linear or branched C 2 to C 10 alkynyl group, a C 5 to C 10 aromatic group, and a C 3 to C 10 saturated or unsaturated heterocyclic group; and
L is selected from the group consisting of Cl, Br, and I;
c. purging the reactor with a purge gas;
d. introducing an oxygen source into the reactor wherein the oxygen source is selected from the group consisting of water, water plasma, oxygen, peroxide, oxygen plasma, ozone, NO, NO 2 , carbon monoxide, carbon dioxide, and combinations thereof; and
e. purging the reactor with a purge gas, wherein steps b through e are repeated until a desired thickness of the film is obtained.
3. The method of claim 1 wherein R 8 is selected from the group consisting of nPr, iPr, nBu, iBu, sBu, tBu, isomers of pentyl, vinyl, phenyl, and alkyl substituted phenyl.
4. The method of claim 1 wherein R 9 is selected from the group consisting of hydrogen, Me, Et, nPr, iPr, nBu, iBu, sBu, tBu, isomers of pentyl, vinyl, phenyl, and alkyl substituted phenyl.
5. The method of claim 2 wherein R 8 is selected from the group consisting of nPr, iPr, nBu, iBu, sBu, tBu, isomers of pentyl, vinyl, phenyl, and alkyl substituted phenyl.
6. The method of claim 2 wherein R 9 is selected from the group consisting of hydrogen, Me, Et, nPr, iPr, nBu, iBu, sBu, tBu, isomers of pentyl, vinyl, phenyl, and alkyl substituted phenyl.