Positive electrode plate and related electrochemical energy storage apparatus and device
View Patent ↗This application provides a positive electrode plate, including a positive current collector, a positive active material layer on at least one side of the positive current collector, and a safety layer between the positive active material layer and the positive current collector. The positive active material layer includes a positive active material. The safety layer includes a binding material, a conductive material, and an overcharge-sensitive material. The overcharge-sensitive material is a polymer that includes a monosaccharide structural unit and that includes at least one of a carbonate group and a phosphate group. An average diameter x of the conductive material and a weight-average molecular weight y of the overcharge-sensitive material satisfy Formula 1.
1. A positive electrode plate, comprising a positive current collector, a positive active material layer on at least one side of the positive current collector, and a safety layer between the positive active material layer and the positive current collector,
wherein the positive active material layer comprises a positive active material, and the safety layer comprises a binding material, a conductive material, and an overcharge-sensitive material;
the overcharge-sensitive material is a polymer that comprises a monosaccharide structural unit and that comprises at least one of a carbonate group and a phosphate group;
an average diameter x of the conductive material and a weight-average molecular weight y of the overcharge-sensitive material satisfy Formula 1:
0.001≤ x/y≤ 0.25 Formula 1
wherein, x is in units of nm, and y is in units of 1; and
wherein the weight-average molecular weight of the overcharge-sensitive material satisfies 2,000≤y≤20,000; and
wherein a mass percent of the binding material in relation to a total mass of the safety layer is 30% to 60%;
wherein, in the safety layer, a mass ratio of the overcharge-sensitive material to the conductive material is not less than 2:1;
wherein the average diameter x of the conductive material is measured with an electron microscope and is a mean value of major axis diameters and minor axis diameters.
2. The positive electrode plate according to claim 1 , wherein the average diameter of the conductive material satisfies x≤600 nm.
3. The positive electrode plate according to claim 1 , wherein the overcharge-sensitive materials includes a mixed ester of a sugar carbonate and a sugar phosphate.
4. The positive electrode plate according to claim 1 , wherein the overcharge-sensitive material is one of
a polysaccharide carbonate, or
a mixture of a monosaccharide carbonate and a polysaccharide carbonate.
5. The positive electrode plate according to claim 1 , wherein the conductive material is one of or any combination of a metallic conductive material, a carbon-based conductive material, and a polymer conductive material.
6. The positive electrode plate according to claim 1 , wherein the metallic conductive material is one of or any combination of aluminum, an aluminum alloy, copper, a copper alloy, nickel, a nickel alloy, titanium, and silver; the carbon-based conductive material is one of or any combination of Ketjen black, mesocarbon microbead, activated carbon, graphite, conductive carbon black, acetylene black, carbon fiber, carbon nanotube, and graphene; and the polymer conductive material is one of or any combination of polysulfur nitride, an aliphatic conjugated polymer, an aromatic cyclic conjugated polymer, and an aromatic heterocyclic conjugated polymer.
7. The positive electrode plate according to claim 1 , wherein the conductive material is zero-dimensional conductive particles.
8. The positive electrode plate according to claim 1 , wherein the conductive material is zero-dimensional carbon-based conductive material particles.
9. The positive electrode plate according to claim 1 , wherein the conductive material is zero-dimensional conductive carbon black.
10. The positive electrode plate according to claim 1 , wherein the overcharge-sensitive material degrades when the positive electrode plate is under conditions of a charge voltage α V and a temperature β° C., wherein 4.2≤α≤5.5, and 35≤β≤80.
11. The positive electrode plate according to claim 1 , wherein the binding material is one of or any combination of polyvinylidene difluoride, a vinylidene difluoride-hexafluoropropylene copolymer, polyurethane, polyacrylonitrile, polyimide, epoxy resin, organosilicon resin, an ethylene-vinyl acetate copolymer, styrene butadiene rubber, styrene-acrylic rubber, polyacrylic acid, a polyacrylic acid-acrylate copolymer, and a polyethylene-acrylate copolymer.
12. The positive electrode plate according to claim 1 , wherein the binding material is one of or any combination of polyvinylidene difluoride and a vinylidene difluoride-hexafluoropropylene copolymer.
13. The positive electrode plate according to claim 1 , wherein, in the safety layer,
a mass percent of the overcharge-sensitive material in the total mass of the safety layer is 30% to 50%; and/or
a mass percent of the conductive material in the total mass of the safety layer is 6% to 18%.
14. An electrochemical energy storage apparatus, comprising a positive electrode plate, wherein the positive electrode plate comprises a positive current collector, a positive active material layer on at least one side of the positive current collector, and a safety layer between the positive active material layer and the positive current collector, the positive active material layer comprises a positive active material, and the safety layer comprises a binding material, a conductive material, and an overcharge-sensitive material;
the overcharge-sensitive material is a polymer that comprises a monosaccharide structural unit and that comprises at least one of a carbonate group and a phosphate group;
an average diameter x of the conductive material and a weight-average molecular weight y of the overcharge-sensitive material satisfy Formula 1:
0.001≤ x/y≤ 0.25 Formula 1
wherein, x is in units of nm, and y is in units of 1; and
wherein the weight-average molecular weight of the overcharge-sensitive material satisfies 2,000≤y≤20,000; and
wherein a mass percent of the binding material in relation to a total mass of the safety layer is 30% to 60%;
wherein, in the safety layer, a mass ratio of the overcharge-sensitive material to the conductive material is not less than 2:1;
wherein the average diameter x of the conductive material is measured with an electron microscope and is a mean value of major axis diameters and minor axis diameters.
15. A battery module, wherein the battery module comprises the electrochemical energy storage apparatus according to claim 14 .
16. A battery pack, wherein the battery pack comprises the battery module according to claim 15 .
17. A device, wherein the device comprises the electrochemical energy storage apparatus according to claim 14 , and the device is one or more of an electric vehicle, an electric ship, an electric tool, an electronic device, and an energy storage system.