ELECTROLYTE, LITHIUM-ION BATTERY, AND APPARATUS CONTAINING SUCH LITHIUM-ION BATTERY
This application provides an electrolyte, a lithium-ion battery, and an apparatus containing the lithium-ion battery. The electrolyte includes a lithium salt, an organic solvent, and an additive. The additive includes a sulfur-containing compound and lithium difluorophosphate, and a reduction potential of the sulfur-containing compound is higher than a reduction potential of lithium difluorophosphate. Because the reduction potential of the sulfur-containing compound is higher than the reduction potential of lithium difluorophosphate, the sulfur-containing compound can form a low-impedance SEI film on a surface of a negative electrode prior to lithium difluorophosphate, allowing more lithium difluorophosphate to form a passivation film with good thermostability on a surface of a positive electrode, so that the lithium-ion battery has good high-temperature storage performance and cycling performance, without suffering performance deterioration such as lithium precipitation.
1 . An electrolyte, comprising:
a lithium salt;
an organic solvent; and
an additive;
wherein
the additive comprises a sulfur-containing compound and lithium difluorophosphate; and
a reduction potential of the sulfur-containing compound is higher than a reduction potential of lithium difluorophosphate.
2 . The electrolyte according to claim 1 , wherein the sulfur-containing compound is selected from one or more of sulfur hexafluoride, sulfuryl fluoride, sulfur dioxide, sulfur trioxide, carbon disulfide, dimethyl sulfide, and methyl ethyl sulfide.
3 . The electrolyte according to claim 1 , wherein mass of the sulfur-containing compound accounts for 0.1% to 8% of total mass of the electrolyte.
4 . The electrolyte according to claim 3 , wherein the mass of the sulfur-containing compound accounts for 0.5% to 5% of the total mass of the electrolyte.
5 . The electrolyte according to claim 1 , wherein mass of lithium difluorophosphate accounts for 0.1% to 5% of the total mass of the electrolyte.
6 . The electrolyte according to claim 5 , wherein the mass of lithium difluorophosphate accounts for 0.1% to 3% of the total mass of the electrolyte.
7 . A lithium-ion battery, comprising:
a positive electrode plate, comprising a positive electrode current collector and a positive electrode membrane disposed on at least one surface of the positive electrode current collector and comprising a positive electrode active material;
a negative electrode plate, comprising a negative electrode current collector and a negative electrode membrane disposed on at least one surface of the negative electrode current collector and that comprising a negative electrode active material;
a separator; and
an electrolyte;
wherein
the electrolyte is the electrolyte according to claim 1 .
8 . The lithium-ion battery according to claim 7 , wherein the positive electrode active material is selected from one or more of a lithium nickel cobalt manganese oxide, a lithium nickel cobalt aluminum oxide, and a compound obtained by adding another transition metal or non-transition metal to the foregoing compounds.
9 . The lithium-ion battery according to claim 7 , wherein the negative electrode active material is selected from one or more of soft carbon, hard carbon, artificial graphite, natural graphite, a silicon-based material, a tin-based material, and lithium titanate.
10 . An apparatus, wherein the apparatus comprises the lithium-ion battery according to claim 7 .