ENVIRONMENTALLY-FRIENDLY COMPOSITIONS AND METHODS FOR EXTRACTING MINERALS AND METALS FROM ORE
The subject invention provides safe, environmentally-friendly, compositions and methods for extracting minerals and/or metals from ore. More specifically, the subject invention provides for bioleaching using a composition comprising one or more biosurfactant-producing microorganisms and/or microbial growth by-products. In specific embodiments, the composition comprises biosurfactant-producing yeasts and/or their growth by-products.
1 . A decadmiation composition comprising a sophorolipid biosurfactant, an acid and, optionally, a pH adjuster, wherein the sophorolipid is a linear sophorolipid or a derivative of a linear sophorolipid; and wherein the acid is selected from acetic acid, citric acid, lactic acid, butyric acid, sorbic acid, benzoic acid, formic acid, fumaric acid, propionic acid, ascorbic acid, glyoxylic acid, malonic acid, pyruvic acid, oxalic acid, uric acid, malic acid, tartaric acid, sulfuric acid, nitric acid, phosphoric acid, hydrochloric acid, boric acid and analogs thereof
2 . The decadmiation composition of claim 1 , wherein the pH adjuster is present in the composition at a concentration that stabilizes the pH of the composition between 2-5.
3 . A method for extracting an impurity from phosphate ore, the method comprising:
(i) obtaining the phosphate ore, said ore comprising phosphate and an impurity;
(ii) contacting a composition comprising a sophorolipid biosurfactant, an acid, and, optionally, a pH adjuster, with the ore for a period of time to yield a mixture comprising a treated phosphate ore and an impurity that has reacted with the composition; and
(iii) separating the reacted impurity and composition from the mixture to obtain a reduced-impurity phosphate-containing material.
4 . The method of claim 3 , wherein the acid is selected from acetic acid, citric acid, lactic acid, butyric acid, sorbic acid, benzoic acid, formic acid, fumaric acid, propionic acid, ascorbic acid, glyoxylic acid, malonic acid, pyruvic acid, oxalic acid, uric acid, malic acid, tartaric acid, sulfuric acid, nitric acid, phosphoric acid, hydrochloric acid, boric acid and analogs thereof.
5 . The method of claim 3 , wherein the pH adjuster is present in the composition at a concentration that stabilizes the pH of the composition between 2-5.
6 . The method of claim 3 , wherein the pH adjuster is sodium hydroxide or potassium hydroxide.
7 . The method of claim 3 , further comprising crushing, grinding or pulverizing the phosphate ore into particles less than 500 nm in size prior to step (ii).
8 . The method of claim 3 , wherein the composition is in liquid form, and wherein step (ii) comprises stirring or shaking the mixture for a time period of 10 minutes to 48 hours, and wherein the reacted impurity and composition of step (iii) is present in the liquid phase and the phosphate ore remains a solid that is decanted and filtered out of the liquid.
9 . The method of claim 3 , wherein step (iii) comprises applying a washing fluid comprising water and, optionally, an organic solvent to the mixture under agitation for a period of time or about 10 to 60 minutes, wherein the washing fluid will comprise the reacted impurity and composition and the phosphate ore remains a solid that is decanted and filtered out of the fluid.
10 . The method of claim 9 , wherein the solvent is an alcohol.
11 . The method of claim 3 , wherein the impurity is selected from cadmium, nickel, arsenic, iron, vanadium, mercury, copper, and lead.
12 . The method of claim 3 , wherein the impurity is cadmium.
13 . A method for extracting an impurity from phosphate ore, the method comprising:
(a) obtaining the phosphate ore, said ore comprising phosphate and an impurity;
(b) preparing a slurry of the phosphate ore in water and maintaining the slurry under agitation;
(c) applying a composition comprising a sophorolipid biosurfactant, an acid, and, optionally, a pH adjuster, to the slurry under agitation for a period of time to yield a mixture comprising a treated phosphate ore and an impurity that has reacted with the composition;
(d) halting the agitation and allowing the mixture to stand for another period of time, thereby causing the formation of a precipitate comprising the treated phosphate ore and an aqueous layer comprising the reacted impurity and composition; and
(e) separating the precipitate from the layer of water to obtain a reduced-impurity phosphate-containing material.
14 . The method of claim 13 , wherein the acid is selected from acetic acid, citric acid, lactic acid, butyric acid, sorbic acid, benzoic acid, formic acid, fumaric acid, propionic acid, ascorbic acid, glyoxylic acid, malonic acid, pyruvic acid, oxalic acid, uric acid, malic acid, tartaric acid, sulfuric acid, nitric acid, phosphoric acid, hydrochloric acid, boric acid and analogs thereof.
15 . The method of claim 13 , wherein the pH adjuster is present in the composition at a concentration that stabilizes the pH of the composition between 2-5.
16 . The method of claim 13 , wherein the pH adjuster is sodium hydroxide or potassium hydroxide.
17 . The method of claim 13 , further comprising crushing, grinding or pulverizing the phosphate ore into particles less than 500 nm in size prior to step (b).
18 . The method of claim 13 , wherein step (e) comprises applying a washing fluid comprising water and, optionally, an organic solvent to the mixture under agitation for a period of time or about 10 to 60 minutes, wherein the washing fluid will comprise the reacted impurity and composition and the phosphate ore remains a solid that is decanted and filtered out of the fluid.
19 . The method of claim 18 , wherein the solvent is an alcohol.
20 . The method of claim 13 , further comprising using the reduced-impurity phosphate-containing material to produce a fertilizer or animal feed supplement.
21 . The method of claim 13 , wherein the impurity is selected from cadmium, nickel, arsenic, iron, vanadium, mercury, copper, and lead.
22 . The method of claim 13 , wherein the impurity is cadmium.