IP Library Granted Patent US 11,613,687
Granted Patent B2
US 11,613,687 · App. 17/529,074 · Granted Mar 28, 2023

High density, low TCT divalent brines and uses thereof

Inventor: Arthur G. Mack (Conroe, TX)
Assignee: TETRA TECHNOLOGIES, INC.
C09K8/035C09K8/03C09K8/62E21B37/06
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Quick Facts
Patent No.
US 11,613,687
App. No.
17/529,074
Granted
Mar 28, 2023
Kind
B2
Abstract

A method of using a suppression factor fluid during a well activity is provided. The method comprising the steps of introducing a suppression factor fluid into a wellbore, the suppression factor fluid comprising an untreated divalent brine, and a suppression sugar alcohol, the suppression sugar alcohol in an amount operable to achieve a suppression factor of at least 0.1, wherein a density upper limitation of the suppression factor fluid is greater than the density upper limitation of the divalent brine; wherein the suppression factor fluid is in the absence of zinc; and completing the well activity in the wellbore, such that the suppression sugar alcohol inhibits crystallization during the well activity.

Claims (10)

1. A method of using a suppression factor fluid during a well activity, the method comprising the steps of:

introducing a suppression factor fluid into a wellbore, the suppression factor fluid comprising:

an untreated divalent brine; and

greater than 5% by weight on a dry weight basis of a suppression sugar alcohol, the suppression sugar alcohol in an amount operable to achieve a suppression factor of at least 1, wherein the suppression sugar alcohol is selected from the group consisting of sorbitol, xylitol, and combinations thereof; and,

a stabilization compound comprising an amine base, the stabilization compound operable to inhibit degradation of the suppression sugar alcohol,

wherein a density upper limitation of the suppression factor fluid is greater than the density upper limitation of the untreated divalent brine,

wherein a density of the suppression factor fluid is on the salt side of a solubility curve of the untreated divalent brine, wherein the suppression factor fluid is thermally stable; and completing the well activity in the wellbore, such that the suppression sugar alcohol inhibits crystallization during the well activity.

2. The method of claim 1 , wherein the untreated divalent brine comprises a divalent salt, where the divalent salt is selected from the group consisting of calcium bromide, calcium chloride, magnesium bromide, magnesium chloride, strontium bromide and combinations thereof.

3. The method of claim 1 , wherein the suppression factor is in the range between 1 and 10.

4. The method of claim 1 , wherein the suppression factor fluid further comprises a polyol, wherein the polyol is selected from the group consisting of glycerol, triglycerol, polypropylene glycol triol, polyether trials, trimethylopropane, trimethylolethane, combinations of the same.

Assignments (3)
SECURITY INTEREST Recorded May 16, 2024
From: TETRA TECHNOLOGIES, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 067435/0204 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jan 12, 2024
From: TETRA TECHNOLOGIES, INC.
To: SILVER POINT FINANCE, LLC
Reel/Frame 066295/0384 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2021
From: MACK, ARTHUR G.
To: TETRA TECHNOLOGIES, INC.
Reel/Frame 058143/0842 →