Fabrication of lithium battery dry electrodes
A solventless method of making a dry electrode for an electrochemical cell is provided. A solventless electrode material mixture includes 85-99% electrode active material and from 0-10% conductive carbon additive. A polymer binder system is present from 1-15%. The polymer binder system includes one or more polymer binders. The electrode material mixture is mixed at a temperature greater than a softening point or a melting point of at least one polymer binder of the polymer binder system. The electrode material mixture is kneaded into an electrode material dough. The electrode material dough is formed into an electrode material sheet. At least a portion of the electrode material sheet is affixed to a metal current collector to form an electrode.
1. A method of preparing a dry electrode layer for a lithium ion battery comprising:
providing a solventless electrode precursor dough to a roller apparatus including electrode active material particles and a binder system including at least one binder, the dough being heated to at a temperature above the melting point of at least one binder of the binder system;
rolling the solventless electrode precursor dough in the roller apparatus, the roller apparatus including a roller and having at least two-axis motion and positioning, including a horizontal axis and a vertical axis;
reducing a thickness of the solventless electrode precursor dough with the roller to create an active material layer;
combining the active material layer with a current collector to create the dry electrode for a lithium ion battery.
2. The method of claim 1 , wherein the roller is heated to a temperature of 100 to 200° C.
3. The method of claim 1 , wherein the dough is supported in the roller apparatus by a heated, non-stick platen.
4. The method of claim 1 , wherein the solventless electrode precursor dough includes 90-99% electrode active material particles, 0-10% conductive carbon additive, and 1-15% binder system.
5. The method of claim 4 , wherein the electrode active material particles and/or conductive carbon additive are chemically modified with a silane coupling agent to effect a dry binding enhancement.
6. The method of claim 1 , wherein the electrode active material particles are positive electrode active material particles selected from one or more of lithium cobalt oxide (LCO), lithium manganese oxide (LMO), lithium iron phosphate (LFP), lithium nickel manganese cobalt oxide, nickel rich lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide (NCA), lithium nickel manganese oxide (LNMO), lithium manganese phosphate (LiMnPO 4 ), lithium cobalt phosphate (LiCoPO 4 ), or lithium vanadium phosphate (LVP).
7. The method of claim 1 , wherein the electrode active material particles are negative electrode active material particles selected from one or more of graphite, hard carbon, soft carbon, silicon-carbon composite, silicon oxide-carbon composite, sulfur-carbon composite, lithium titanium oxide (LTO).
8. The method of claim 1 , wherein the binder system includes one or more of polyvinylidene difluoride (PVDF), poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), polytetrafluoroethylene (PTFE), polyvinylfluoride (PVF), polyethylene (PE), polypropylene (PP), polyethylene oxide (PEO), polyethylene vinyl acetate (PEVA), polyurethane (PU), polypropylene rubber (PPR), ethylene propylene rubber (EPR), styrene butadiene rubber (SBR), styrene-ethylene-butylene-styrene rubber (SEBS), acrylonitrile butadiene styrene rubber (ABS), polyisobutylene (PIB), polyvinyl alcohol (PVA), phenoxy resin, polyethylene terephthalate (PET), nylon, polymethylmethacrylate (PMMA), polyvinyl chloride (PVC), polyphenylene sulfide (PPS), polystyrene (PS), pitch, tar, asphalt, or bitumen.
9. The method of claim 1 , further comprising a conductive carbon additive in an amount of approximately 10% or less wherein the conductive carbon additive is selected from one or more of carbon black, carbon nanotubes, graphene, carbon nanofibers, carbon fibers.
10. The method of claim 1 , wherein a final thickness of the active material layer is 0.05 mm to 2 mm.