Organic electroluminescent device

1. An organic electroluminescent device comprising an anode, a cathode, and an organic layer between the anode and the cathode,

wherein the organic layer comprises one or more light-emitting layers and one or more hole transport layers; at least one of the one or more light-emitting layers comprises one or more dopant compounds and two or more host compounds; a first host compound of the two or more host compounds is represented by the following formula 1; a second host compound is represented by the following formula 2; and at least one of the one or more hole transport layers comprises the compound represented by the following formula 3:

wherein

A 1 and A 2 , each independently, represent a deuterium-substituted or unsubstituted (C6-C18)aryl;

L 1 represents a single bond or a substituted or unsubstituted (C6-C30)arylene;

X 1 to X 16 , each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted 3- to 30-membered heteroaryl containing at least one hetero atom selected from B, N, O, S, Si, and P, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, or a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl;

wherein

Ma represents a substituted or unsubstituted nitrogen-containing 5- to 11-membered heteroaryl;

La represents a substituted or unsubstituted (C6-C30)arylene;

Xa to Xh, each independently, represent hydrogen, deuterium, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted 3- to 30-membered heteroaryl containing at least one heteroatom selected from O and S, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted (C3-C30), mono- or polycyclic, alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen, and sulfur, with the proviso that at least one of Xa to Xh is not hydrogen;

wherein

A 4 and A 5 , each independently, represent a substituted or unsubstituted (C6-C30)aryl;

L 3 represents a single bond or a substituted or unsubstituted (C6-C30)arylene;

Z 1 to Z 9 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted 3- to 30-membered heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino provided that at least one of Z 1 to Z 9 is linked to an adjacent substituent(s) to form a substituted or unsubstituted (C3-C30), mono- or polycyclic, alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen, and sulfur;

n represents an integer of 0;

t represents an integer of 0, 1, or 2; and

the heteroaryl contains at least one hetero atom selected from B, N, O, S, Si, and P.

2. The organic electroluminescent device according to claim 1 , wherein in formula 1, A 1 and A 2 , each independently, represent a deuterium-substituted or unsubstituted (C6-C18)aryl wherein the (C6-C18)aryl is selected from the group consisting of a phenyl, a biphenyl, a terphenyl, a naphthyl, a fluorenyl, a benzofluorenyl, a phenanthrenyl, a anthracenyl, a indenyl, a triphenylenyl, a pyrenyl, a tetracenyl, a perylenyl, a chrysenyl, a phenylnaphthyl, a naphthylphenyl, and a fluoranthenyl.

3. The organic electroluminescent device according to claim 1 , wherein in formula 1, Li represents a single bond, or one selected from the following formulae 9 to 21

wherein

Xi to Xp, each independently, represent hydrogen, deuterium a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, or a substituted or unsubstituted 3- to 30-membered heteroaryl; and represents a bonding site.

4. The organic electroluminescent device according to claim 1 , wherein in formula 2, Ma represents a substituted or unsubstituted monocyclic ring-type heteroaryl selected from the group consisting of a substituted or unsubstituted pyrrolyl, a substituted or unsubstituted imidazolyl, a substituted or unsubstituted pyrazolyl, a substituted or unsubstituted triazinyl, a substituted or unsubstituted tetrazinyl, a substituted or unsubstituted triazolyl, a substituted or unsubstituted tetrazolyl, a substituted or unsubstituted pyridyl, a substituted or unsubstituted pyrazinyl, a substituted or unsubstituted pyrimidinyl, and a substituted or unsubstituted pyridazinyl, or a substituted or unsubstituted fused ring-type heteroaryl selected from the group consisting of a substituted or unsubstituted benzimidazolyl, a substituted or unsubstituted isoindolyl, a substituted or unsubstituted indolyl, a substituted or unsubstituted indazolyl, a substituted or unsubstituted benzothiadiazolyl, a substituted or unsubstituted quinolyl, a substituted or unsubstituted isoquinolyl, a substituted or unsubstituted cinnolinyl, a substituted or unsubstituted quinazolinyl, a substituted or unsubstituted naphthyridinyl, and a substituted or unsubstituted quinoxalinyl.

5. The organic electroluminescent device according to claim 1 , wherein in formula 2, La represents a single bond, or one selected from the following formulae 9 to 21

Wherein

Xi to Xp, each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, or a substituted or unsubstituted 3- to 30-membered heteroaryl; and sulfur; and represents a bonding site.

6. The organic electroluminescent device according to claim 1 , wherein in formula 2, Xa to Xh, each independently, represent hydrogen, a cyano, a (C6-C15)aryl unsubstituted or substituted with a tri(C6-C10)arylsilyl, or a 10- to 20-membered heteroaryl containing at least one heteroatom selected from O and S unsubstituted or substituted with a (C6-C12)aryl; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted benzene, a substituted or unsubstituted indole, a substituted or unsubstituted benzindole, a substituted or unsubstituted indene, a substituted or unsubstituted benzofuran, or a substituted or unsubstituted benzothiophene, with the proviso that at least one of Xa to Xh is not hydrogen.

7. The organic electroluminescent device according to claim 1 , wherein in formula 3, A 4 and A 5 , each independently, represent a substituted or unsubstituted (C6-C30)aryl; L 3 represents a single bond or a substituted or unsubstituted (C6-C18)arylene; Z 1 to Z 9 , each independently, represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted 6- to 30-membered heteroaryl, provided that one to three pairs selected from Z 1 and Z 2 , Z 2 and Z 3 , Z 4 and Z 5 , Z 5 and Z 6 , Z 7 and Z 8 , and Z 8 and Z 9 , as a pair of adjacent substituents, may form a substituted or unsubstituted (C3-C30), mono- or polycyclic aromatic ring, whose carbon atom(s) may be replaced with one to three hetero atoms selected from nitrogen, oxygen, and sulfur; n represents an integer of 0 or 1; and t represents an integer of 1 or 2.

8. The organic electroluminescent device according to claim 1 , wherein in formula 3, A 4 and A 5 , each independently, is selected from the group consisting of a substituted or unsubstituted phenyl, a substituted or unsubstituted biphenyl, a substituted or unsubstituted terphenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted phenanthrenyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted pyrenyl, a substituted or unsubstituted tetracenyl, a substituted or unsubstituted chrysenyl, a substituted or unsubstituted fluorenyl, a substituted or unsubstituted benzofluorenyl, a substituted or unsubstituted fluoranthenyl, a substituted or unsubstituted triphenylenyl, and a substituted or unsubstituted spirobifluorenyl; and t represents an integer of 1 or 2.

9. The organic electroluminescent device according to claim 1 , wherein the compound of formula 1 is selected from the group consisting of:

10. The organic electroluminescent device according to claim 1 , wherein the compound of formula 2 is selected from the group consisting of:

11. The organic electroluminescent device according to claim 1 , wherein the compound of formula 3 is selected from the group consisting of: