Cathode active material for lithium secondary battery and lithium secondary battery including the same
The cathode active material for a lithium secondary battery according to embodiments of the present invention includes lithium-transition metal composite oxide particles including a plurality of primary particles, and the lithium-transition metal composite oxide particles have a lithium-potassium-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.
1. A cathode active material for a lithium secondary battery comprising:
a lithium-transition metal composite oxide particle including a plurality of primary particles,
wherein the lithium-transition metal composite oxide particle comprises a lithium-potassium-containing portion formed between the primary particles,
wherein the lithium-potassium-containing portion comprises a lithium-potassium-sulfur-containing portion including lithium, potassium and sulfur.
2. The cathode active material for a lithium secondary battery according to claim 1 , wherein the primary particles have a hexagonal close-packed structure.
3. The cathode active material for a lithium secondary battery according to claim 2 , wherein the lithium-transition metal composite oxide particle has no primary particle having a face centered cubic structure.
4. The cathode active material for a lithium secondary battery according to claim 1 , wherein a sulfur content of the lithium-transition metal composite oxide particle measured through a carbon-sulfur (CS) analyzer is 1,100 to 4,500 ppm based on a total weight of the lithium-transition metal composite oxide particle.
5. The cathode active material for a lithium secondary battery according to claim 1 , wherein a potassium concentration of the lithium-potassium-containing portion measured through energy dispersive spectroscopy (EDS) is greater than the potassium concentration in the primary particles measured through the EDS.
6. The cathode active material for a lithium secondary battery according to claim 5 , wherein an average potassium signal value of the lithium-potassium-containing portion measured through the EDS is 1.2 to 4 times greater than the average potassium signal value in the primary particles measured through the EDS.
7. The cathode active material for a lithium secondary battery according to claim 1 , wherein a content of lithium carbonate (Li 2 CO 3 ) remaining on the surface of the lithium-transition metal composite oxide particle is 2,500 ppm or less, and a content of lithium hydroxide (LiOH) remaining on the surface of the lithium-transition metal composite oxide particle is 2,500 ppm or less.
8. A lithium secondary battery comprising:
a cathode comprising a cathode active material layer including the cathode active material for a lithium secondary battery according to claim 1 ; and
an anode disposed to face the cathode.
9. A method of manufacturing a cathode active material for a lithium secondary battery, comprising:
preparing a preliminary lithium-transition metal composite oxide particle;
mixing the preliminary lithium-transition metal composite oxide particle with a potassium compound aqueous solution; and
performing a heat treatment on the mixed preliminary lithium-transition metal composite oxide particle and the potassium compound aqueous solution, to prepare a lithium-transition metal composite oxide particle comprising a plurality of primary particles and a lithium-potassium-containing portion formed between the primary particles
wherein the potassium compound aqueous solution is formed by mixing a solvent with potassium compound powder, and
an input amount of the potassium compound powder is 0.2 to 1.9% by weight based on a total weight of the preliminary lithium-transition metal composite oxide particle,
wherein an input amount of the solvent is 2 to 15% by weight based on the total weight of the preliminary lithium-transition metal composite oxide particle.
10. The method of manufacturing a cathode active material for a lithium secondary battery according to claim 9 , wherein the potassium compound powder is potassium hydrogen sulfate (KHSO 4 ) powder.
11. The method of manufacturing a cathode active material for a lithium secondary battery according to claim 9 , wherein the heat treatment is performed at 200 to 400° C. under an oxygen atmosphere.
12. The method of manufacturing a cathode active material for a lithium secondary battery according to claim 9 , wherein the preliminary lithium-transition metal composite oxide particle is mixed with the potassium compound aqueous solution without water washing treatment.