Pet composition, pet preform, refillable pet bottle and methods for making the same
A polyethylene terephthalate composition (PET), an injection-molded bottle preform made from a PET composition, a refillable PET container blow-molded from the preform, catalyst compositions used for making the PET composition, methods for making the PET composition, methods for injection-molding a PET bottle preform, methods for blow-molding a refillable PET bottle from a preform and methods for improving the rewash stability and recyclability of refillable PET bottles particularly for carbonated soft drinks.
1. A method for forming a refillable bottle preform, comprising:
injection molding a polyester resin composition in a mold to form the refillable bottle preform having a maximum wall thickness of 7.5 mm,
wherein a cavity surface of the mold is at a temperature of from 60 to 90° C.;
wherein the refillable bottle preform formed by the injection molding has a haze of 10% or less according to ASTM D-1003 at a thickness of more than 4.5 mm; and
wherein the polyester resin composition comprises:
(1) a polyester resin comprising polycondensed units of one or more dicarboxylic acids and one or more diols,
wherein the dicarboxylic acid comprises from 90 mol % to 97 mol % percent of terephthalic acid and the diol comprises from 90 mol % to 99 mol % of ethylene glycol;
wherein the polyester resin has an intrinsic viscosity of from 0.81 to 0.85 dl/g and a haze of less than 5% at a thickness of between 4.5 and 6 mm according to ASTM D-1003-B;
wherein the polyester resin further comprises polycondensed units of isophthalic acid in an amount of 3-4 mol % based on the total moles of polycondensed units of dicarboxylic acid in the polyester resin, and cyclohexane dimethanol in an amount of 1 to 3 mol % based on the total moles of polycondensed units of diols in the polyester resin; and
(2) from 125 to 200 ppm of Sb and 2 to 5 ppm of Ti; and
wherein a change in the fill point volume after 5 wash cycles of a 2.5 liter blow molded bottle that is blow molded from the refillable bottle preform is 14 ml or less.
2. The method of claim 1 , wherein the refillable bottle preform has an average wall thickness of greater than 6.5 mm.
3. The method of claim 1 , further comprising:
blow molding the refillable bottle preform to form a blow-molded refillable polyester bottle having a top, a middle portion and a bottom, wherein the top is configured with a thread to accept a threaded closure, and the bottom is configured with a champagne standing ring base to position and stand the bottle upright on a surface.
4. The method of claim 3 , wherein the blow-molded refillable polyester has a change in fill point variability of 15 ml or less after exposure to 25 hot wash cycles, wherein washing is carried out with water at a temperature in a range of from 50° C. to less than 100° C.
5. The method of claim 3 , wherein the blow-molded refillable polyester bottle has a single bottle coefficient of variability of base thickness of less than 10%.