Polyester film and preperation method thereof
A polyester-based film having excellent scratch resistance, durability, transparency, and visibility and a process for preparing the same. The polyester-based film comprises a base layer and a coating layer on at least one side of the base layer. The light passage according to Relationship 1 is 91% or more, or the total transmittance for light of 380 nm to 780 nm is 92% or more, it has excellent optical properties, durability, visibility, and reliability. Thus, it can be applied to display devices such as smartphones, tablet PCs, and laptops. In addition, in the polyester-based film according to an embodiment, the strain with respect to tensile load satisfies a specific range, whereby it is possible to achieve the flexibility that hardly causes deformation even when a certain load is maintained for a long period of time. Thus, it can be applied to flexible display devices, particularly, foldable display devices.
1. A polyester-based film, which satisfies the following Relationship 2 in a first direction in the plane and the following Relationship 3 in a second direction that is perpendicular to the first direction:
1.3≤| S 1 −S 2 |≤3.1 [Relationship 2]
2.18≤| S 3− S 4|≤5.2, [Relationship 3]
wherein in Relationship 2, S 1 is the final tensile rate (%) after N 1% is maintained for 20 minutes, and S2 is the final tensile rate (%) after N 2% is maintained for 20 minutes, wherein N 1% is the load that stretches the polyester-based film by 1% in the first direction, and N 2% is the load that stretches the polyester-based film by 2% in the first direction,
wherein in Relationship 3, S3 is the final tensile rate (%) after a load that stretches the polyester-based film by 1% in the second direction is maintained for 20 minutes, and S4 is the final tensile rate (%) after a load that stretches the polyester-based film by 2% in the second direction is maintained for 20 minutes, and
wherein the polyester-based film comprises a polyethylene terephthalate resin in an amount of 85% by weight or more.
2. The polyester-based film of claim 1 , which satisfies the following Relationship 4 in a third direction that is 45° to the first direction:
0.5≤| S 5 −S 6 |≤7.2 [Relationship 4]
in Relationship 4, S 5 is the final tensile rate (%) after a load that stretches the polyester-based film by 1% in the third direction is maintained for 20 minutes, and S 6 is the final tensile rate (%) after a load that stretches the polyester-based film by 2% in the third direction is maintained to 20 minutes.
3. The polyester-based film of claim 1 , wherein S 1 is 0.1 to 2.5, S 2 is 1.5 to 4.5, S 3 is 0.8 to 2.4, and S 4 is 2.3 to 7.5.
4. The polyester-based film of claim 1 , wherein S 1 :S 3 is 0.4 to 0.7:1, and S 2 :S 4 is 0.4 to 0.7:1.
5. The polyester-based film of claim 1 , wherein N 1% in the first direction is 10 N to 25 N, N 2% in the first direction is 28 N to 50 N, the load that stretches the polyester-based film by 1% in the second direction is 25 N to 45 N, and the load that stretches the polyester-based film by 2% in the second direction is 50 N to 70 N.
6. A protective film, which comprises a polyester-based film of claim 1 ; and a curable resin layer disposed on one side of the polyester-based film.