AQUEOUS BASED POLYMERS FOR SILICON DOMINANT ANODES
Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a water soluble polymer and may comprise one or more of the following materials: pH modifiers, viscosity modifiers, strengthening additives, surfactants and anti-foaming agents. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
1 . A battery electrode, the electrode comprising:
an electrode coating layer on a current collector, the electrode coating layer formed from silicon, an aqueous-based polymer, and one or more additional components; wherein said additional components comprise pH modifiers, viscosity modifiers, strengthening additives, surfactants and anti-foaming agents.
2 . The electrode according to claim 1 , wherein said aqueous-based polymer comprises polyimides, polyamideimides, phenolic resins, polysiloxanes, polyurethanes, polyvinyls, acrylics, polysaccharides, and derivatives thereof.
3 . The electrode according to claim 1 , wherein said aqueous-based polymer is pyrolyzed into carbon during making of the electrode and has a carbon yield upon pyrolysis of greater than about 30%.
4 . The electrode according to claim 1 , wherein said aqueous-based polymer is selected from the group consisting of Polyamideimide; China-innotek; Elantas; Solvay Torlon Al series; Polyimide; Ammonium Lignosulfonate; Kraft Lignin; Phenolic resins; Formaldehyde based Resins; Melamine-formaldehyde based resins; Silane based resins; Silicones; Polyurethanes; Poly(vinyl acetate)/poly(vinyl alcohol) complexes; TOCRYL (acrylic emulsion); Poly(methacrylic acid); Polymethyl methacrylate; ACRONAL water-based acrylic and stryrene-acrylic emulsion polymers; STYROFAN carboxylated styrene-butadiene; Acrylic resins; Poly(acrylic acid); Glycogen; Carbohydrates; Cellulose, Cellulose crystals (including cellulose nano-crystals); HEC (Hydroxy Ethyl Cellulose); CMHEC (Carboxy methyl hydroxy ethyl cellulose); Starch; Pullulan (polysaccharide polymer); Dextran; Chitosan; Helios resins; and Rotaxane.
5 . The electrode according to claim 1 , wherein said one or more additional component comprises one or more pH modifiers.
6 . The electrode according to claim 5 , wherein said pH modifiers are acidic pH modifiers.
7 . The electrode according to claim 5 , wherein said pH modifiers are basic pH modifiers.
8 . The electrode according to claim 1 , wherein said one or more additional component comprises one or more viscosity modifiers.
9 . The electrode according to claim 1 , wherein said one or more additional component comprises one or more strengthening additives.
10 . The electrode according to claim 1 , wherein said one or more additional component comprises one or more surfactants and/or anti-foaming agents.
11 . The electrode according to claim 1 , wherein said additional components when present comprise the amounts of:
less than about 50% pH modifier, less than about 30% strengthening additive, less than about 50% viscosity modifier, less than about 10% surfactant, less than about 10% anti-foaming agent.
12 . The electrode according to claim 1 , comprising the additional components of a pH modifier, viscosity modifier, and a surfactant, wherein the pH modifier is N-methyldiethanolamine, the viscosity modifier is poly(vinyl alcohol) and the surfactant is a non-ionic polymer fluorosurfactant.
13 . The electrode according to claim 1 , wherein the electrode is in electrical and physical contact with an electrolyte, the electrolyte comprising a liquid, solid, or gel.
14 . The electrode according to claim 1 , wherein the battery electrode is in a lithium ion battery.
15 . A method of forming an electrode, the method comprising:
creating an electrode coating layer from an electrode slurry comprising an aqueous solution of a water soluble polymer, silicon powder, and one or more additional components; wherein said additional components comprise pH modifiers, viscosity modifiers, strengthening additives, surfactants and anti-foaming agents;
fabricating a battery electrode by coating the slurry on a current collector; and
pyrolyzing said electrode coating layer.
16 . The method according to claim 15 , wherein said aqueous-based polymer comprises polyimides, polyamideimides, phenolic resins, polysiloxanes, polyurethanes, polyvinyls, acrylics, polysaccharides, and derivatives thereof.
17 . The method according to claim 15 , wherein said pyrolyzing step of said electrode coating layer has a carbon yield upon pyrolysis of greater than about 30%.
18 . The method according to claim 15 , wherein said aqueous-based polymer is selected from the group consisting of Polyamide-imide; China-innotek; Elantas; Solvay Torlon Al series; Polyimide; Ammonium Lignosulfonate; Kraft Lignin; Phenolic resins;
Formaldehyde based Resins; Melamine-formaldehyde based resins; Silane based resins; Silicones; Polyurethanes; Poly(vinyl acetate)/poly(vinyl alcohol) complexes; TOCRYL (acrylic emulsion); Poly(methacrylic acid); Polymethyl methacrylate; ACRONAL water-based acrylic and stryrene-acrylic emulsion polymers; STYROFAN carboxylated styrene-butadiene; Acrylic resins; Poly(acrylic acid); Glycogen; Carbohydrates; Cellulose, Cellulose crystals (including cellulose nano-crystals); HEC (Hydroxy Ethyl Cellulose); CMHEC (Carboxy methyl hydroxy ethyl cellulose); Starch; Pullulan (polysaccharide polymer); Dextran; Chitosan; Helios resins; and Rotaxane.
19 . The method according to claim 15 , wherein said one or more additional component comprises one or more pH modifiers.
20 . The method according to claim 19 , wherein said pH modifiers are acidic pH modifiers.
21 . The method according to claim 19 , wherein said pH modifiers are basic pH modifiers.
22 . The method according to claim 15 , wherein said one or more additional component comprises one or more viscosity modifiers.
23 . The method according to claim 15 , wherein said one or more additional component comprises one or more strengthening additives.
24 . The electrode according to claim 15 , wherein said one or more additional component comprises one or more surfactants and/or anti-foaming agents.
25 . The method according to claim 15 , wherein said additional components when present comprise the amounts of:
less than about 50% pH modifier, less than about 30% strengthening additive, less than about 50% viscosity modifier, less than about 10% surfactant, less than about 10% anti-foaming agent.
26 . The method according to claim 15 , comprising the additional components of a pH modifier, viscosity modifier, and a surfactant, wherein the pH modifier is N-methyldiethanolamine, the viscosity modifier is poly(vinyl alcohol) and the surfactant is a non-ionic polymer fluorosurfactant.
27 . The method according to claim 15 , wherein the electrode is in electrical and physical contact with an electrolyte, the electrolyte comprising a liquid, solid, or gel.
28 . The method according to claim 15 , wherein the battery electrode is in a lithium ion battery.