High strength and high thermal conductivity polyethylene thin film having a bimodal molecular weight
An optically clear, high strength, high modulus, and high thermal conductivity polyethylene thin film may be formed from a crystallizable polymer and an additive configured to interact with the crystallizable polymer to facilitate crystallite alignment and, in some examples, create a higher crystalline content within the polyethylene thin film. The polyethylene thin film may be characterized by a bimodal molecular weight distribution where the molecular weight of the additive may be less than approximately 5% of the molecular weight of the crystallizable polymer. Example crystallizable polymers may include high molecular weight polyethylene, high density polyethylene, and ultra-high molecular weight polyethylene. Example additives may include low molecular weight polyethylene and polyethylene oligomers. The polyethylene thin film may be characterized by a Young's modulus of at least approximately 10 GPa, a tensile strength of at least approximately 0.7 GPa, and a thermal conductivity of at least approximately 5 W/mK.
1. A polyethylene layer, comprising:
a crystalline polymer and an additive, wherein the crystalline polymer has a weight average molecular weight of at least approximately 100,000 g/mol and is oriented either uniaxially or biaxially, and the additive comprises a polyethylene oligomer having a reactive moiety selected from the group consisting of vinyl, acrylate, methacrylate, epoxy, isocyanate, hydroxyl, and amine, and has a weight average molecular weight of less than approximately 4,000 g/mol.
2. The polyethylene layer of claim 1 , wherein the additive comprises one or more of a lubricant and an antioxidant.
3. The polyethylene layer of claim 1 , wherein the additive is characterized by a refractive index ranging from approximately 1.45 to approximately 1.6.
4. The polyethylene layer of claim 1 , wherein the additive comprises from approximately 0.1 wt. % to approximately 90 wt. % of the polyethylene layer.
5. The polyethylene layer of claim 1 , wherein the polyethylene layer is characterized by less than approximately 10% bulk haze.
6. A method comprising:
forming a polyethylene layer by mixing a crystallizable polymer and an additive; and
producing an in-plane strain in the polyethylene layer along a first direction in an amount sufficient to re-orient crystals or align polyethylene chains within the polyethylene layer and form a mechanically anisotropic polyethylene layer, wherein the crystallizable polymer has a weight average molecular weight of at least approximately 100,000 g/mol and is oriented either uniaxially or biaxially, and the additive comprises a polyethylene oligomer having a reactive moiety selected from the group consisting of vinyl, acrylate, methacrylate, epoxy, isocyanate, hydroxyl, and amine, and has a weight average molecular weight of less than approximately 4,000 g/mol.
7. The method of claim 6 , wherein forming the polyethylene layer comprises extruding or casting a mixture containing the crystallizable polyethylene and the additive.
8. The method of claim 6 , wherein producing the in-plane strain comprises applying a uniaxial stress to the polyethylene layer.
9. The method of claim 6 , wherein producing the in-plane strain comprises applying a biaxial stress to the polyethylene layer.
10. The method of claim 6 , further comprising removing the additive from the polyethylene layer.