Cellulose composite determination method and apparatus for composite resin
Composite resin containing cellulose is irradiated with infrared light, reflected light from the composite resin irradiated with the light is received, normalization is performed at a peak position maximized in a peak at 2800 cm −1 or more and 3000 cm −1 or less, which is a C—H stretching peak caused by the composite resin, in a reflection or absorption spectrum obtained by the reflected light, and a reflection or absorption spectrum for determination is obtained. The spectrum is used to acquire a ratio value of a spectral intensity (background intensity) at a position of 1000 cm −1 or less according to a determined resin type and different from a wave number at which a peak derived from resin of the determined resin type is expressed, and a ratio of the spectral intensity (background intensity) is used so that a composite of cellulose combined in composite resin can be determined with high accuracy.
1. A cellulose composite determination method for composite resin, comprising:
irradiating composite resin containing cellulose with infrared light;
receiving reflected light from the composite resin irradiated with the infrared light;
determining a resin type of the composite resin from a reflection or absorption spectrum obtained from the reflected light;
using a spectrum obtained by normalization with an intensity at a peak position that becomes a maximum intensity at a peak in a range of a wave number of 2800 cm −1 or more and 3000 cm −1 or less which is a C—H stretching peak caused by the composite resin in the reflection or absorption spectrum obtained by the reflected light to acquire a value of a ratio of a spectral intensity (background intensity) at a position that is 1000 cm −1 or less in the spectrum and is different from a wave number at which a peak derived from resin of the determined resin type is expressed; and
acquiring a value of a ratio of a spectral intensity (background intensity) in advance by a method similar to that for the composite resin using a spectrum of a sample of single resin which is contained in the composite resin and is acquired in advance and comparing the values to determine a composite of cellulose in the composite resin.
2. The cellulose composite determination method for composite resin according to claim 1 , further comprising:
after acquiring, as composite determination information, a value of the peak intensity ratio at a position that is 1000 cm −1 or less and is different from a wave number at which a peak derived from resin of the determined resin type is expressed,
instead of acquiring the value of the ratio of the spectral intensity (that is, the background intensity) in advance by a method similar to that for the composite resin using the spectrum of the sample of single resin which is contained in the composite resin and is acquired in advance and comparing a value of a ratio of a spectral intensity (background intensity) at a position different from a wave number at which a peak derived from resin of them is expressed to determine the composite of cellulose in the composite resin; and
creating a calibration curve relating to a background intensity derived using a sample whose cellulose composite ratio is known in advance; and
performing determination of a composite and a composite ratio based on a level of a correlation degree between the calibration curve and a value of the acquired background intensity.
3. A cellulose composite determination apparatus for composite resin, comprising:
an irradiation unit that irradiates composite resin containing cellulose with infrared light;
a light receiving unit that receives reflected light from the composite resin irradiated with the infrared light;
a resin type determination unit that acquires a reflection or absorption spectrum from the reflected light obtained by the light receiving unit and determines a resin type of the composite resin from the acquired reflection or absorption spectrum;
a composite determination information acquisition unit that uses a spectrum obtained by normalization with an intensity at a peak position that becomes a maximum intensity at a peak in a range of a wave number of 2800 cm −1 or more and 3000 cm −1 or less which is a C—H stretching peak caused by the composite resin in the reflection or absorption spectrum obtained by the reflected light to acquire, as composite determination information, a value of a ratio of a spectral intensity (background intensity) at a position that is 1000 cm −1 or less in the spectrum and is different from a wave number at which a peak derived from resin of the determined resin type is expressed; and
a composite resin determination unit that compares a value of a ratio of a spectral intensity (that is, a background intensity) acquired by the composite determination information acquisition unit and a value of a ratio of a spectral intensity (that is, a background intensity) acquired in advance by a method similar to that for the composite resin using a spectrum of a sample of single resin which is contained in the composite resin and is acquired in advance to determine a composite of cellulose in the composite resin.