Electrolyte, lithium-ion battery comprising electrolyte, battery module, battery pack and device
In the embodiments of the present application, an electrolyte, a lithium-ion battery comprising the electrolyte, a battery module, a battery pack, and a device are provided. The electrolyte in the embodiments of the present application comprises an organic solvent, an electrolyte lithium salt dissolved in the organic solvent, and an additive comprising a first additive and a second additive. The first additive is selected from one or more of the compounds represented by formula I, and the second additive is selected from one or more of the compounds represented by formula II. After applying the electrolyte of the present application to a lithium-ion battery, the lithium ion battery has a better cycle performance and storage performance at a high temperature, and lower direct-current impedance at a low temperature, such that the lithium ion battery has both a better high-temperature performance and a better low-temperature performance.
1. An electrolyte, comprising:
an organic solvent;
an electrolyte lithium salt dissolved in the organic solvent; and
an additive comprising a first additive and a second additive,
the first additive being selected from one or more of the following compounds:
the second additive being selected from one or more of the following compounds:
Compound 2-1: Tris(trimethylsilyl)phosphite,
Compound 2-2: Tris(trimethylsilyl)borate,
Compound 2-3: Tris(triethylsilyl)phosphite,
Compound 2-4: Tris(tri-n-propylsilyl)phosphite,
Compound 2-5: Tris(tri-n-butylsilyl)phosphite,
Compound 2-6: Tris(triethylsilyl)borate,
Compound 2-7: Tris(tri-n-propylsilyl)borate,
Compound 2-8: Tris(tri-n-butylsilyl)borate,
Compound 2-9: Tris(trimethylsilyl)phosphate,
Compound 2-10: Tris(triethylsilyl)phosphate,
Compound 2-11: Tris(tri-n-propylsilyl)phosphate,
Compound 2-12: Tris(tri-n-butylsilyl)phosphate, and
wherein the concentration of the first additive in the electrolyte is 0.1wt%-3wt% and the concentration of the second additive in the electrolyte is 0.05wt%-2wt%.
2. The electrolyte according to claim 1 , wherein the electrolyte lithium salt selected from one or more of: LiPF 6 , LiPO 2 F 2 , Li 2 PO 3 F, LiBF 4 , LiSO 3 F, LiTFMSB, LiN(SO 2 F) 2 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiBOB, LiPFO and lithium Tetrafluorophosphate; optionally, the electrolyte lithium salt is selected from one or more of: LiPF 6 , LiBF 4 , LiSO 3 F, LiTFMSB, LiPO 2 F 2 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 F) 2 , LiBOB and LiPFO.
3. The electrolyte according to claim 1 , wherein the concentration of the electrolyte lithium salt in the electrolyte is 0.5M-2M; optionally, the concentration of the electrolyte lithium salt in the electrolyte is 0.8M-1.2M.
4. A lithium-ion battery, comprising a positive electrode, a negative electrode, a separator, and the electrolyte according to claim 1 .
5. A battery module, comprising the lithium-ion battery of claim 4 .
6. A battery pack, comprising the battery module of claim 5 .
7. A device, comprising the lithium-ion battery of claim 4 .