Separator for electricity storage devices, and electricity storage device
A separator for electricity storage devices, which comprises a porous layer that contains a polyolefin resin and an ionic compound, and which is configured such that: the content of the ionic compound in the porous layer is from 5% by mass to 99% by mass (inclusive); and the degree of whiteness of this separator is more than 98.0.
1. A separator configured for a lithium-ion secondary battery, which has a porous layer comprising a mixture of a polyolefin resin and an ionic compound, wherein a content of the ionic compound in the porous layer is 5% by weight or more and less than 50% by weight in the porous layer and a degree of whiteness of the separator is greater than 98.0, and the degree of whiteness is measured using a colorimeter under a condition that does not include a specular reflection light in a 2° viewing angle, and
wherein a viscosity-average molecular weight of the polyolefin resin comprised in the separator configured for a lithium-ion secondary battery is 300,000 or more and 5,000,000 or less.
2. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein the degree of whiteness is 98.5 or more and 105 or less.
3. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein the polyolefin resin contains polyethylene having a viscosity-average molecular weight of 600,000 or more and 5,000,000 or less.
4. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein a content of metal oxide in the separator configured for a lithium-ion secondary battery is 10% by weight or less.
5. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein the ionic compound has one or more anions selected from the group consisting of a sulfate ion, a nitrate ion, a phosphate ion, and a halide ion.
6. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein the ionic compound has one or more cations selected from the group consisting of an alkali metal ion and an alkaline earth metal ion.
7. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein the ionic compound is barium sulfate.
8. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein an average particle size of the ionic compound is 5 nm or more and 600 nm or less.
9. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein an average pore size of the separator configured for a lithium-ion secondary battery is 10 nm or more and 100 nm or less.
10. The configured for a lithium-ion secondary battery according to claim 1 , wherein an air permeability of the separator configured for a lithium-ion secondary battery is 10 seconds/100 ml or longer and 500 seconds/100 ml or shorter.
11. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein a puncture strength of the separator configured for a lithium-ion secondary battery is 100 gf or more and 600 gf or less.
12. An electricity storage device comprising a positive electrode, a negative electrode, and the separator configured for a lithium-ion secondary battery according to claim 1 .
13. The separator configured for a lithium-ion secondary battery according to claim 1 , wherein, when the thickness of the separator is 20 μm or thinner, the degree of whiteness is measured under the condition with the separator that is folded to the total thickness of 20 μm or more.